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A Conjugated Copolymer Bearing Imidazolium-based Ionic Liquid: Electrochemical Synthesis and Electrochromic Properties

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Abstract

An imidazolium-based ionic liquid (IL) modified triphenylamine derivative, namely 1-(4-((4-(diphenylamino)benzoyl) oxy)butyl)-3-methyl imidazole tetrafluoroborate (TPAC6IL-BF4), was designed and synthesized, and further applied with 3,4-ethylene dioxythiophene (EDOT) to prepare conjugated copolymer P(EDOT:TPAC6IL-BF4) via electrochemical polymerization. The cyclic voltammetry curves show that the copolymer P(EDOT:TPAC6IL-BF4) possesses two pairs of redox peaks, which should be ascribed to the redox behaviors of EDOT and triphenylamine. The ultraviolet-visible (UV-Vis) absorption spectrum of P(EDOT:TPAC6IL-BF4) exhibits one maximum absorption peak at 580 nm and a small shoulder characteristic peak at 385 nm under neutral state which are assigned to π-π* conjugated structure of EDOT and triphenylamine. After being applied at the positive voltage, the copolymer color changes from dark blue to light blue, which is close to the color of poly(3,4-ethylenedioxythiophene) (PEDOT). Surprisingly, the copolymer P(EDOT:TPAC6IL-BF4) shows shorter switching time of 0.37 s, 0.30 s at 580 nm and 0.38 s, 0.45 s at 1100 nm compared with PEDOT. It is more intriguing that the copolymer P(EDOT:TPAC6IL-BF4) exhibits electrochromism even in free supporting electrolyte. The results confirm that the existence of imidazolium-based ionic liquid has an improvement on the ion diffusion properties and the switching time of conjugated polymer, which may provide a potential direction for the preparation of high-performance electrochromic materials.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 51703199 and 51673174) and Natural Science Foundation of Zhejiang Province of China (No. LZ17E030001).

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Authors and Affiliations

  1. International Sci. & Tech. Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, China

    Xiao-Jing Lv, Li-Bin Xu, Liang Qian, Yuan-Yuan Yang, Zhi-Yi Xu, Jin Li & Cheng Zhang

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  1. Xiao-Jing Lv
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  2. Li-Bin Xu
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  4. Yuan-Yuan Yang
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  7. Cheng Zhang
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Correspondence to Cheng Zhang.

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Lv, XJ., Xu, LB., Qian, L. et al. A Conjugated Copolymer Bearing Imidazolium-based Ionic Liquid: Electrochemical Synthesis and Electrochromic Properties. Chin J Polym Sci 39, 537–544 (2021). https://doi.org/10.1007/s10118-021-2525-z

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