Abstract
The contamination of water from industrial pollutants is the most significant concern for environment. Semiconductors have been at forefront of effective elimination of pollutants from waste water, with the tuning of bandgap and improving the photocatalytic activity. This work elaborates the hydrothermal synthesize of highly stable Nickel Oxide (NiO) and Vanadium-doped Nickel Oxide (V-NiO) nanoparticles. The undoped and doped Nickel Oxide nanoparticles were characterized for structural, morphological, thermal and optical properties. X-ray diffraction pattern reveals the V-NiO stabilized in cubic structure. Morphological analysis demonstrates that upon Vanadium doping NiO particles transform from network like structure to spherical nanoparticles. NiO and V-NiO nanoparticles have an average crystallite size of 42 nm and 26 nm which are well matched with particle size calculated from transmission electron micrographs. The photoluminescence study reveals that the Vanadium substitution specifically reduces the rate of recombination in NiO. The V-NiO catalysts exhibited noticeable red shift of absorption spectrum to the visible region in comparison with pure NiO. The functional groups were studied using Fourier Transform Infrared Spectroscopy (FTIR). The photocatalytic study by degradation of Xylenol Orange (XyO) under sunlight irradiation unveils that photocatalytic activity of NiO is enhanced on vanadium doping. Reaction kinetics investigation of XyO degradation revealed that the reaction obeys the pseudo-zero-order model with improved rate constant of 0.115 mol L−1S−1 and 0.225 mol L−1S−1 for NiO and V-NiO, respectively. The retention of high performance and structural stability of photocatalysts after four consecutive degradation cycles implies the reusability of the catalyst. Consequently, the V-NiO with high photocatalytic activity with improved cyclic stability is able to provide as a promising material in the field of environmental remediation.
Similar content being viewed by others
References
Y. Li, F. Chen, R. He, Y. Wang, N. Tang, Semiconductor photocatalysis for water purification, in Chapter 24, nanoscale materials in water purification. (Springer, Berlin, 2019), pp. 689–706
A. Kumar, G. Pandey, A review on the factors affecting the photocatalytic degradation of hazardous materials. Mater. Sci. Eng. Int. J. 3, 106–114 (2017)
F. Opoku, K.K. Govender, C.G.C.E. Van Sittert, P.P. Govender, Recent progress in the development of Semiconductor-based photocatalyst materials for applications in photocatalytic water splitting and degradation of pollutants. Adv. Sustain Syst. 1, 1–24 (2017)
M. Pawar, S. Topcu Sendogdular, P. Gouma, A brief overview of TiO2 photocatalysts for organic dye remediation: case study of reaction mechanisms involved in Ce-TiO2 photocatalysts system. J. Nanometer. (2018). https://doi.org/10.1155/2018/5953609
B. Viswanathan, Photocatalytic degradation of dyes: an overview. Curr. Catal. 7, 1–25 (2018)
S.M. Saleh, Metal oxide nanomaterials as photo-catalyst for dye degradation. Res. Dev. Mater. Sci. 9(2), 1–8 (2019)
R. Nallendran, G. Selvan, A.R. Balu, Photoconductive and photocatalytic properties of CdO-NiO nanocomposite synthesized by a cost-effective chemical method. J. Mater. Sci. Mater. 29, 11384–11393 (2018)
F. Torki, H. Faghihian, Photocatalytic activity of NiS, NiO and coupled NiS-NiO for degradation of pharmaceutical pollutant cephalexin under visible light. RSC Adv. 7, 54651–54661 (2017)
M.R.D. Khaki, M.S. Shafeeyan, A.A.A. Raman, W.M.A.W. Daud, Application of doped photocatalysts for organic pollutant degradation—a review. J. Environ. Manag. 198, 78–94 (2017)
J.M. Goncalves, M.I. da Silva, L. Angnes, K. Araki, Vanadium-containing electro and photocatalysts for the oxygen evolution reaction: a review. J. Mater. Chem. A 8, 2171–2206 (2020)
M.O. Guerrero-Perez, V-containing mixed oxide catalysts for reduction-oxidation based reactions with environmental applications: a short review. Catalysts 8, 1–14 (2018)
G. Nabi, S. Rehman, M.B. Tahir, N. Malik, R. Yousaf, M. Maraj, M. Rizwan, M. Tanveer, Structural, optical and magnetic properties of pure and Vanadium doped NiO microstructures for spintronics applications. J. Supercond. Nov. Magn. 13, 1–6 (2020)
V. Panneerselvam, K.K. Chinnakutti, S.T. Salammal, A.K. Soman, K. Parasuraman, V. Vishwakarma, V. Kanagasabai, Role of Copper/Vanadium on the optoelectronic properties of reactive RF magnetron sputtered NiO thin films. Appl. Nanosci. 6, 1299–1312 (2018)
S.A. Mohammed, L.A. Amouri, E. Yousif, A.A. Ali, F. Mabood, H.F. Abbas, S. Alyaqoobi, Synthesis of NiO:V2O5 nanocomposite and its photocatalytic efficiency for methyl orange degradation. Heliyon 4, 1–12 (2018)
H.H. Lim, B.A. Horri, B. Salamatinia, Synthesis and characterizations of Nickel (II) Oxide sub-micro rods via co-precipitation methods. IOP Conf. Ser. Mater. Sci. Eng. 398, 1–9 (2018)
A.J. Haider, R. Al-Anbari, H.M. Sami, M.J. Haider, Photocatalytic activity of Nickel oxide. J Mater Res Technol. 3, 2802–2808 (2019)
A. Diallo, K. Kaviyarasu, S. Ndiaye, B.M. Mothudi, A. Ishaq, V. Rajendran, M. Maaza, Structural, optical and photocatalytic applications of biosynthesized NiO photocatalysts. Green Chem Lett Rev. 11, 166–175 (2018)
R.A. Raj, M.S. Alsalhi, S. Devanesan, Microwave assisted synthesis of Nickel oxide nanoparticles using coriandrum sativum leaf extract and their structural-magnetic catalytic properties. Materials 10, 1–12 (2017)
D.A. Brewster, Y. Bian, K.E. Knowles, Direct solvothermal synthesis of phase pure colloidal NiO nanocrystals. Chem. Mater. 5, 2004–2013 (2020)
Q. Zhou, Z. Lu, Z. Wei, L. Xu, Y. Gui, W. Chen, Hydrothermal synthesis of hierarchical ultrathin NiO nanoflakes for high performance CH4 sensing. Front. Chem 6, 1–4 (2018)
Y.X. Gan, A.H. Jayatissa, Z. Yu, X. Chen, M. Li, Hydrothermal synthesis of nanomaterials. J. Nanometer. (2020). https://doi.org/10.1155/2020/8917013
N. Duraisamy, K. Kadiah, R. Rajendran, S. Prabhu, R. Ramesh, G. Dhanaraj, Electrochemical and photocatalytic investigation of nickel oxide for energy storage and wastewater treatment. Res. Chem. Intermed. 3, 1–15 (2018)
K. Yogesh Kumar, S. Archana, T.N. Vinuth Raj, B.P. Prasana, M.S. Raghu, H.B. Muralidhara, Superb adsorption capacity of hydrothermally synthesized copper oxide and nickel oxide nanoflakes towards anionic and cationic dyes. J. Sci. Adv. Mater. Devices 2, 183–191 (2017)
R. Wang, L. Wu, B. Chica, L. Gu, G. Xu, Y. Yuan, Ni(dmgH)2 complex coupled with metal-organic frameworks MIL-101(Cr) for photocatalytic H2 evolution under visible light irradiation. J. Materiomics 3, 58–62 (2017)
F. Pellegrino, L. Pellutie, F. Sordello, C. Minero, E. Ortel, V.-D. Hodoroaba, V. Maurino, Influence of agglomeration and aggregation on the photocatalytic activity of TiO2 nanoparticles. Appl. Catal. B. 216, 80–87 (2017)
T. Adinaveen, T. Karnan, S.A.S. Selvakumar, Photo catalytic and optical properties of NiO added Nephelium lappaceum L. peel extract: an attempt to convert waste to a valuable product. Heliyon 5, 1–7 (2019)
P.C.S. Bezerra, R.P. Cavalcante, A. Garcia, H. Wender, M.A.U. Martines, G.A. Casagrande, J. Giménez, P. Marco, S.C. Oliveiraa, A. Machulek Jr., Synthesis, characterization, and photocatalytic activity of pure and N-, B-, or Ag- Doped TiO2. J. Braz. Chem. Soc. 9, 1788–1802 (2017)
P.A. Sheena, K.P. Priyanka, A. Sridevi, T. Varghese, Characterization of NiO/CoPc nanocomposite material synthesized by solvent evaporation route. J. Nanostruct. Chem. 8, 207–215 (2018)
C. Yang, W. Dong, G. Cui, Y. Zhao, X. Shi, X. Xia, B. Tang, W. Wang, Highly-efficient photocatalytic degradation of methylene blue by PoPD-modified TiO2 nanocomposites due to photosensitization-synergetic effect of TiO2 with PoPD. Sci. Rep 7, 1–12 (2017)
A.C. Gandhi, S.Y. Wu, Strong deep level-emission photoluminescence in NiO nanoparticles. Nanomaterials 7, 1–12 (2017)
S. Johnson Jeyakumar, R. Sathish Kumara, M. Jothibas, I. Kartharinal Punithavathy, J. Prince Richard, Temperature effects on the magnetic properties of NiO nanoparticles. Int. J. Adv. Sci. Technol. Eng. Manag. Sci. 9, 8–12 (2017)
R. Manigandan, T. Dhanasekaran, A. Padmanaban, K. Giribabu, R. Suresh, V. Narayanan, Bifunctional hexagonal Ni/NiO nanostructures: influence of the core-shell phase on magnetism, electrochemical sensing of serotonin and catalytic reduction of 4-nitrophenol. Nanoscale Adv. 1, 1531–1540 (2019)
K. Varunkumar, R. Hussain, G. Hegde, A.S. Ethiraj, Efffect of calcination temperature on Cu doped NiO nanoparticles prepared via wet-chemical method: structural, optical and morphological studies. Mater. Sci. Semicond. Process. 66, 149–156 (2017)
M. Ramesh, M.P. Chander Rao, S. Anandan, H. Nagaraja, Adsorption and photocatalytic properties of NiO nanoparticles synthesized via a thermal decomposition process. J. Mater. Res. 5, 601–610 (2018)
F.J. Twagirayezu, Density functional theory study of the effect of Vanadium doping on electronic and optical properties of NiO. Int J Comput Mater. 8, 1–13 (2019)
S. Agrawal, A. Parveen, A. Azam, Microwave assisted synthesis of Co doped NiO nanoparticles and its fluorescence properties. J. Lumin. 184, 250–255 (2017)
O. Sacco, D. Sannino, M. Matarangolo, V. Vaiano, Room temperature synthesis of V-doped TiO2 and its photocatalytic activity in the removal of caffeine under uv irradiation. Materials 911, 1–10 (2019)
H.S. Ali, A.S. Alghamdi, G. Murtaza, H.S. Arif, W. Naeem, G. Farid, S. Sharif, M.G.B. Asiq, S.A. Shabbir, Facile microemulsion synthesis of ‘V’ doped ZnO nanoparticles to analyze the compositional, optical and electronic properties. Materials 821, 1–14 (2019)
W.B. Sultan, M.S. Lassoued, S. Ammar, Thierry Toupance, Vanadium doped SnO2 nanoparticles for photocatalytic degradation of methylene blue. J. Mater. Sci. Mater. Electron. 21, 15826–15834 (2017)
A. Khatri, P.S. Rana, Visible light photocatalysis of methylene blue using cobalt substituted cubic NiO nanoparticles. Bull. Mater. Sci. 141, 1–11 (2019)
H. Abbas, K. Nadeem, A. Hassan, S. Rahman, H. Krenn, Enhanced photocatalytic activity of ferromagnetic Fe-doped NiO nanoparticles. Optik (2019). https://doi.org/10.1016/j.ijleo.2019.163637
Amita, Deepak, Arun, P.S. Rana, Synthesis, characterization and sunlight catalytic performance of Cu doped NiO nanoparticles. AIP Conf. Proc. 2093(0200035), 1–4 (2019)
B. Sarwan, B. Pare, A.D. Acharya, Synthesis of Mn/NiO and Mn/BiOCl nanoparticles for degradation of Nile Blue dye contaminated water under visible light illumination. Particul. Sci. Technol 38, 659–666 (2019)
R.R. Muthuchudarkodi, T.M. MerlinSathyaSuganthi (2017) Green synthesis, Characterizations and photocatalytic applications of cerium doped nickel oxide nanoparticles assisted Byalternantherasessilis. Int. J. Latest Trends Eng. Technol. 164–168
K.R. Basavalingaiah, Udayabhanu, S. Harishkumar, G. Nagaraju, Chikkahanumantharayapa, NiO and Ag@NiO nanomaterials for enhanced photocatalytic and photoluminescence studies: green synthesis using Lycopodium Linn. AJEAT 2, 79–85 (2019)
C.R. Rajith Kumar, Virupaxappa, S. Betageri, G. Nagaraju, G.H. Pujar, B.P. Suma, M.S. Latha, Photocatalytic, nitride sensing and antibacterial studies of facile bio-synthesized nickel oxide nanoparticles. J. Sci. Adv. Mater. Devices 5, 48–55 (2020)
H. Yu, H. Yin, L. Wang, J. Gong, Y. Zheng, Q. Nie, Enhanced degradation of rhodamine B, tetracycline and carbamazepine by construction of a solar driven indirect Z-scheme AgI/Ag/Bi2O2Co3 nano sheets photocatalyst. J. Mater. Sci. Mater. Electron. 30, 17227–17238 (2019)
E.M.M. Putri, M. Rachimoellah, C.S. Rahendaputri, Y. Adisti, Y. Zetra, Photocatalytic degradation of Malachite green using TiO2 and O2/UV. AIP Conf. Proc., 2049, 020092-1-020092-8 (2018)
B. Samai, S. Chall, S.S. Mati, S.C. Bhattacharya, Role of silver nanoclusters in the enhanced photocatalytic activity of cerium oxide nanoparticles. Eur. J. Inorg. Chem. 27, 3224–3231 (2018)
M.A.I. Molla, M. Furukawa, I. Tateishi, H. Katsumata, T. Suzuki, S. Kaneco, Photo catalytic decolorization of dye with self-dye-sensitization under fluorescent light irradiation. Chem. Eng. 8, 1–8 (2017)
M. Shaban, M.R. Abukhadra, S.S. Ibrahim, M.G. Shahien, Photocatalytic degradation and Photo-Fenton oxidation of Congo-red dye pollutants in water using natural chromite response surface optimization. Appl. Water Sci. 7, 4743–4756 (2017)
L. Chen, S.-L. Hsieh, C.-H. Kuo, S. Hsieh, W.-H. Chen, C.-W. Chen, C.-D. Dong, Novel MoS2 quantum dots as a highly efficient visible-light driven photocatalyst in water remediation. RSC Adv. 10, 31794–31799 (2020)
Acknowledgements
The financial support from Anna University in the form of Anna Centenary Research Fellowship (ACRF) from the Center for Research, Anna University Chennai is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Prabhavathy, S., Arivuoli, D. Enhanced photocatalytic activity on Vanadium-doped NiO nanostructures in natural sunlight. J Mater Sci: Mater Electron 32, 1105–1120 (2021). https://doi.org/10.1007/s10854-020-04885-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-04885-4