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Methanol Steam Reforming in a Reactor with a Palladium–Copper Membrane in the Presence of a Nickel–Copper Catalyst

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Abstract

A study of methanol steam reforming (MSR) in the presence of a Ni0.2–Cu0.8/Ce0.3Zr0.7O2-δ catalyst in conventional and membrane reactors has revealed that the hydrogen yield in a reactor with a Pd–Cu membrane is higher than that in a conventional flow reactor. It has been shown that the Pd–Cu alloy membrane exhibits high hydrogen permeability. Methanol steam reforming in the membrane reactor provides the production of high-purity hydrogen, because a stream of pure hydrogen free from any impurities is effluent from the permeate zone. Measurements of the hydrogen permeability of the Pd–Cu alloy foil membrane in the membrane reactor before and after catalysis have been conducted.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the Shared-Use Centers “Analytical Center for the Problems of Deep Oil Refining and Petroleum Chemistry” and “New Petrochemical Processes, Polymer Composites, and Adhesives” at the Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences.

Funding

This work was supported by the Russian Science Foundation, project no. 19-19-00232; the catalyst synthesis and testing were performed under a state task of the Ministry of Education and Science of the Russian Federation at the Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119071, Moscow, Russia

    E. Yu. Mironova, A. A. Lytkina, M. M. Ermilova, N. V. Orekhova, N. A. Zhilyaeva & A. B. Yaroslavtsev

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    N. R. Roshan & V. M. Ievlev

Authors
  1. E. Yu. Mironova
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  2. A. A. Lytkina
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  3. M. M. Ermilova
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  4. N. V. Orekhova
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  5. N. A. Zhilyaeva
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  6. N. R. Roshan
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  7. V. M. Ievlev
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  8. A. B. Yaroslavtsev
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Correspondence to E. Yu. Mironova or A. B. Yaroslavtsev.

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Translated by M. Timoshinina

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Mironova, E.Y., Lytkina, A.A., Ermilova, M.M. et al. Methanol Steam Reforming in a Reactor with a Palladium–Copper Membrane in the Presence of a Nickel–Copper Catalyst. Pet. Chem. 60, 1232–1238 (2020). https://doi.org/10.1134/S0965544120110158

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  • DOI: https://doi.org/10.1134/S0965544120110158

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