The catalytic properties of ZnLaZrSi-oxide systems prepared on the basis of different types of silica (SBA-15, MCM-41, MCM-48, MCF, large-pore silica, Aerosil A-175) in the process of obtaining 1,3-butadiene (BD) from ethanol–aqueous mixtures were studied. It has been determined that the porous structure characteristics are not critical parameters for achieving high selectivity and yield of BD. The activity and selectivity of catalysts depends on the acid–base properties of their surface, which are determined by the type of silica. High values of selectivity for BD are achieved in the presence of catalysts based on KSKG silica (SBD = 65-68%) and SBA-15 (SBD = 63%).
Similar content being viewed by others
References
J. A. Posada, A. D. Patel, A. Roes, et al., Bioresour. Technol., 135, 490-499 (2013), https://doi.org/10.1016/i.biortech.2012.09.058.
J. Pui, H. Li, X. Zhou, et al., Phys. Chem. Chem. Phys., 21, 22351-22358 (2019), https://doi.org/10.1039/c9cp04187g.
R. G. Grim, A. T. To, C. A. Farberow, et al., ACS Catal., 9, 4145-4172 (2019), https://doi.org/10.1021/acscatal.8b03945.
R. Dastillung, B. Fischer , M. Jacquin , and R. Huyghe, “Method for the production of butadiene from ethanol in one low-water- and low-energy-consumption reaction step,” Pat. US 20170267604 Al, Publ. 21.09.2017.
D. Cai, Q. Zhu, C. Chen, et al., J. Taiwan Inst. Chem. Eng., 82, 137-143 (2018), https://doi.org/10.1016/j.jtice.2017.11.002.
G. Pomalaza, M. Capron, V. Ordomsky, and F. Dumeignil, Catalysts, 6, 203 (2016), https://doi.org/10.1016/j.jtice.2017.11.002.
P. I. Kyriienko, S. O. Larina, S. O. Soloviev, et al., Theor. Exp. Chem., 56, 213-242 (2020), https://doi.org/10.1007/s11237-020-09654-2.
G. M. Cabello Gonzalez, P. Concepcionb, A. L. Villanueva Peralesa, et al., Fuel Process. Technol., 193, 263-272 (2019), https://doi.org/10.1016/j.apcata.2018.11.010.
G. Pomalaza, P. Arango, M. Capron, and F. Dumeignil, Catal. Sci. Technol., 10, 4860-4911 (2020), https://doi.org/10.1039/D0CY00784F.
M. D. Jones, C. G. Keir, C. Di Iulio, et al., Catal. Sci. Technol., 1, 267-272 (2011), https://doi.org/10.1039/c0cy00081g.
V. L. Sushkevich, I. I. Ivanova, and E. Taarning, Green Chem., 17, 2552-2559 (2015), https://doi.org/10.1039/C4GC02202E.
V. L. Dagle, M. D. Flake, T. L. Lemmon, et al., Appl. Catal. B Environ., 236, 576-587 (2018), https://doi.org/10.1039/C4GC02202E.
G. Pomalaza, G. Vofo, M. Capron, and F. Dumeignil, Green Chem., 20, 3203-3209 (2018), https://doi.org/10.1039/C8GC01211C.
H.-J. Chae, T.-W. Kim, Y.-K. Moon, et al., Appl. Catal. B Environ., 150-151, 596-604 (2014), https://doi.org/10.1016/j.cej.2014.09.110.
M. Gao, M. Zhang, and H. Jiang, Catal. Surv. Asia, 22, 118-122 (2018), https://doi.org/10.1007/s10563-018-9243-8.
O. V. Larina, N. D. Shcherban, P. I. Kyriienko, et al., ACS Sustain. Chem. Eng., 8, 16600–1661 (2020), https://doi.org/10.1021/acssuschemeng.0c05925.
O. V. Larina, P. I. Kyriienko, and S. O. Soloviev, Theor. Exp. Chem., 51, 252-258 (2015), https://doi.org/10.1007/s10563-018-9243-8.
O. V. Larina, P. I. Kyriienko, D. Y. Balakin, et al., Catal. Sci. Technol., 9, 3964-3978 (2019), https://doi.org/10.1039/C9CY00991D.
L. Silvester, J. F. Lamonier, C. Lamonier, et al., ChemCatChem, 9, 2250-2261 (2017), https://doi.org/10.1002/cctc.201601480.
J. L. Cheong, Y. Shao, S. J. R. Tan, et al., ACS Sustain. Chem. Eng., 4, 4887-4894 (2016), https://doi.org/10.1021/acssuschemeng.6b01193.
M. M. Kurmach, O. V. Larina, P. I. Kyriienko, et al., ChemistrySelect, 3, 8539-8546 (2018), https://doi.org/10.1002/slct.201801971.
O. V. Larina, P. I. Kyriienko, and S. O. Soloviev, Theor. Exp. Chem., 52, 51-56 (2016), https://doi.org/10.1007/s11237-016-9450-1.
T. Miyazawa, Y. Tanabe, I. Nakamura, et al., Catal. Sci. Technol., (2020), doi https://doi.org/10.1039/d0cy01453b.
J. Velasquez Ochoa, C. Bandinelli, O. Vozniuk, et al., Green Chem., 18, 165-1663 (2016), https://doi.org/10.1039/C5GC02194D.
P. I. Kyriienko, O. V. Larina, S. Dzwigaj, et al., Theor. Exp. Chem., 55, 241-247 (2019), https://doi.org/10.1007/s11237-019-09618-1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 56, No. 5, pp. 304-311, September-October, 2020.
Rights and permissions
About this article
Cite this article
Kyriienko, P.I., Larina, O.V., Scherban, N.D. et al. Catalytic Properties of ZnLaZrSi-Oxide Systems in the Process of Obtaining 1,3-Butadiene from Ethanol–Aqueous Mixtures. Theor Exp Chem 56, 329–337 (2020). https://doi.org/10.1007/s11237-020-09662-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-020-09662-2