Abstract
Modified polymer blends demonstrated the desirable properties and performance suitable for various applications. In the present investigation, we prepared the blends of crystalline Polyvinylidene fluoride (PVDF)/ with amorphous Polysulfone (PSF) by a solution technique. We have foreseen the miscibility of the PVDF/PSF polymer system by an optical polarizing microscope. The electrical quality factor (Q) of these polymer blends demonstrated increased quality magnitude with the shift in resonance frequency (\(f_{0}\)) and bandwidth (B.W.) confirmed by an impedance analyzer. The influence of the temperature on the quality factor was studied across the temperature scale (30 to 150 ∘C). This investigation was feasible for the development of a new class of polymer blends deployable for electronics and shielding applications.
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References
Abbas, I.A.: A two-temperature model for evaluation of thermoelastic damping in the vibration of a nanoscale resonators. Mech. Time-Depend. Mater. 20(4), 511–522 (2016). https://doi.org/10.1007/s11043-016-9309-9
Arthisree, D., Joshi, G.M.: Graphene oxide derived high dielectric constant of polymer blends. Mater. Res. Express 5(7), 7 (2018). https://doi.org/10.1088/2053-1591/aad108
Arya, A., Sadiq, M., Sharma, A.L.: Salt concentration and temperature dependent dielectric properties of blend solid polymer electrolyte complexed with NaPF6. Mater. Today Proc. 12, 554–564 (2019). https://doi.org/10.1016/j.matpr.2019.03.098
Aziz, S.B., Abdullah, R.M.: Crystalline and amorphous phase identification from the \(\tan\delta\) relaxation peaks and impedance plots in polymer blend electrolytes based on [CS:AgNt]x:PEO(\(x-1\)) (\(10 \leq \times \leq 50\)). Electrochim. Acta 285, 30–46 (2018). https://doi.org/10.1016/j.electacta.2018.07.233
Barick, B.K., Mishra, K.K., Arora, A.K., Choudhary, R.N.P., Pradhan, D.K.: Impedance and Raman spectroscopic studies of (Na0.5Bi0.5)TiO3. J. Phys. D, Appl. Phys. 44(35), 35 (2011). https://doi.org/10.1088/0022-3727/44/35/355402
Biswas, S., Panja, S.S., Bose, S.: Tailored distribution of nanoparticles in bi-phasic polymeric blends as emerging materials for suppressing electromagnetic radiation: challenges and prospects. J. Mater. Chem. C 6(13), 3120–3142 (2018). https://doi.org/10.1039/c8tc00002f
Buruiana, L.-I., Avram, E., Popa, A., Musteata, V.E., Ioan, S.: Electrical conductivity and optical properties of a new quaternized polysulfone. Polym. Bull. 68(6), 1641–1661 (2012). https://doi.org/10.1007/s00289-011-0659-9
Cheng, Q., Cui, Z., Li, J., Qin, S., Yan, F., Li, J.: Preparation and performance of polymer electrolyte based on poly(vinylidene fluoride)/polysulfone blend membrane via thermally induced phase separation process for lithium ion battery. J. Power Sources 266, 401–413 (2014). https://doi.org/10.1016/j.jpowsour.2014.05.056
Chitsaz Yazdi, F., Jalali, A.: Vibration behavior of a viscoelastic composite microbeam under simultaneous electrostatic and piezoelectric actuation. Mech. Time-Depend. Mater. 19(3), 277–304 (2015). https://doi.org/10.1007/s11043-015-9264-x
Choudhary, S.: Structural, morphological, thermal, dielectric, and electrical properties of alumina nanoparticles filled PVA–PVP blend matrix-based polymer nanocomposites. Polym. Compos. 39(S3), E1788–E1799 (2018). https://doi.org/10.1002/pc.24793
Dhanumalayan, E., Joshi, G.: Quality factor of potassium hexa-titanate oxide ceramic reinforced polymer blends for broad band applications. AIP Conf. Proc. 1992, 030006 (2018). https://doi.org/10.1063/1.5047957
Dhatarwal, P., Sengwa, R.J.: Polymer compositional ratio-dependent morphology, crystallinity, dielectric dispersion, structural dynamics, and electrical conductivity of PVDF/PEO blend films. Macromol. Res. 27(10), 1009–1023 (2019). https://doi.org/10.1007/s13233-019-7142-0
Evaristo Riande, R.D.-C.: Piezoelectric and Pyroelectric Materials. Electrical Properties of Polymers. Dekker/CRC Press, New York/Boca Raton (2004)
Fang, Z-x., Tang, B., Li, E., Zhang, S-r.: High-Q microwave dielectric properties in the Na0.5Sm0.5TiO3 + Cr2O3 ceramics by one synthetic process. J. Alloys Compd. 705, 456–461 (2017). https://doi.org/10.1016/j.jallcom.2017.01.200
Han, C.C., Shi, W., Jin, J.: Morphology and crystallization of crystalline/amorphous polymer blends. In: Encyclopedia of Polymers and Composites, pp. 1–19 (2013). https://doi.org/10.1007/978-3-642-37179-0_25-1
Heinola, J., Silventoinen, P., Latti, K., Kettunen, M., Strom, J.: Determination of dielectric constant and dissipation factor of a printed circuit board material using a microstrip ring resonator structure. In: 15th International Conference on Microwaves, Radar and Wireless Communications, IEEE Cat. No. 04EX824, 17–19 May 2004, vol. 201, pp. 202–205 (2004). https://doi.org/10.1109/MIKON.2004.1356897.
Ioan, S., Buruiana, L.-I., Avram, E., Petreus, O., Musteata, V.E.: Optical, dielectric, and conduction properties of new phosphorus-modified polysulfones. J. Macromol. Sci., Part B 50(8), 1571–1590 (2011). https://doi.org/10.1080/00222348.2010.541848
Jia, Q., Huang, X., Wang, G., Diao, J., Jiang, P.: MoS2 nanosheet superstructures based polymer composites for high-dielectric and electrical energy storage applications. J. Phys. Chem. C 120(19), 10206–10214 (2016). https://doi.org/10.1021/acs.jpcc.6b02968
Joshi, G.M., Deshmukh, K.: Optimized quality factor of graphene oxide-reinforced PVC nanocomposite. J. Electron. Mater. 43(4), 1161–1165 (2014). https://doi.org/10.1007/s11664-014-3010-z
Joy, J., Thomas, S., Shanks, R.: Natural Polymer Blends and Their Composites. Micro- and NanoStructured Polymer Systems Synthesis to Applications. CRC Press, Boca Raton (2015)
Khutia, M., Joshi, G.M., Tambe, P.: Quality factor of Melt blend processed polypropylene/poly (acrylonitrile-butadiene-styrene)/ conducting carbon black blends. Int. J. Plast. Technol. 19(2), 381–387 (2015). https://doi.org/10.1007/s12588-016-9131-x
Kiraci, A., Yurtseven, H.: Temperature dependence of the polarization, dielectric constant, damping constant and the relaxation time close to the ferroelectric-paraelectric phase transition in LiNbO3. Optik 132, 183–191 (2017). https://doi.org/10.1016/j.ijleo.2016.12.020
Koga, E., Yamagishi, Y., Moriwake, H., Kakimoto, K., Ohsato, H.: Large Q factor variation within dense, highly ordered Ba(Zn1/3Ta2/3)O3 system. J. Eur. Ceram. Soc. 26(10), 1961–1964 (2006). https://doi.org/10.1016/j.jeurceramsoc.2005.09.041
Krevelen, D.W., Nijenhuis, K.: Electrical properties. In: Properties of Polymers, pp. 319–354 (2009). https://doi.org/10.1016/B978-0-08-054819-7.00011-X. Chapter 11
Kusumawati, N., Setiarso, P., Muslim, S., Purwidiani, N.: Synergistic ability of PSf and pvdf to develop high-performance PSf/PVDF coated membrane for water treatment. Rasayan J. Chem. 11, 260–279 (2018). https://doi.org/10.7324/RJC.2018.1112018
Lakshmi, N.V., Tambe, P.: EMI shielding effectiveness of graphene decorated with graphene quantum dots and silver nanoparticles reinforced PVDF nanocomposites. Compos. Interfaces 24(9), 861–882 (2017). https://doi.org/10.1080/09276440.2017.1302202
Li, R., Chen, Z., Pei, J.: High dielectric performance of polyamide 66/poly(vinylidene fluoride) flexible blends induced by interfacial copolymer for capacitors. Polymers 8(1), 2 (2015). https://doi.org/10.3390/polym8010002
Li, W.-B., Zhou, D., Pang, L.-X., Dai, Y.-Z., Qi, Z.-M., Wang, Q.-P., Liu, H.-C.: High quality factor microwave dielectric ceramics in the (Mg1/3Nb2/3)O2–ZrO2–TiO2 ternary system. J. Am. Ceram. Soc. 100(9), 3982–3989 (2017). https://doi.org/10.1111/jace.14929
Maricar, M.I., Khalid, A., Cumming, D.S.R., Oxley, C.H.: Improving the quality factor of the coplanar waveguide resonator. Microw. Opt. Technol. Lett. 57(6), 1323–1325 (2015). https://doi.org/10.1002/mop.29082
Martins, M.S., Faria, C.L., Matos, T., Goncalves, L.M., Cabral, J., Silva, A., Jesus, S.M.: Wideband and wide beam polyvinylidene difluoride (PVDF) acoustic transducer for broadband underwater communications. Sensors 19(18), 3991 (2019). https://doi.org/10.3390/s19183991
Michler, G.H.: Semicrystalline polymers. In: Michler, G.H. (ed.) Electron Microscopy of Polymers, pp. 295–327. Springer, Berlin (2008). https://doi.org/10.1007/978-3-540-36352-1_17
Morarescu, R., Pal, P.K., Beneitez, N.T., Missinne, J., Steenberge, G.V., Bienstman, P., Morthier, G.: Fabrication and characterization of high-optical-quality-factor hybrid polymer microring resonators operating at very near infrared wavelengths. IEEE Photonics J. 8(2), 1–9 (2016). https://doi.org/10.1109/JPHOT.2016.2544641
Mutiso, R., Winey, K.: Electrical properties of polymer nanocomposites containing rod-like nanofillers. Prog. Polym. Sci. 40, 63–84 (2014). https://doi.org/10.1016/j.progpolymsci.2014.06.002
Nangia, R., Shukla, N., Sharma, A.: Frequency and temperature-dependent impedance spectroscopy of PVA/PEG polymer blend film. High Perform. Polym. 30, 095400831877483 (2018). https://doi.org/10.1177/0954008318774837
Nayak, L., Rahaman, M., Khastgir, D., Chaki, T.K.: Thermal and electrical properties of carbon nanotubes based polysulfone nanocomposites. Polym. Bull. 67(6), 1029 (2011). https://doi.org/10.1007/s00289-011-0479-y
Nguyen, H.T.V., Ngo, T.H.A., Do, K.D., Nguyen, M.N., Dang, N.T.T., Nguyen, T.T.H., Vien, V., Vu, T.A.: Preparation and characterization of a hydrophilic polysulfone membrane using graphene oxide. J. Chem. 2019, 3164373 (2019). https://doi.org/10.1155/2019/3164373
Niu, Y., Yang, L., Wang, H., Wang, Z.: Criteria of process optimization in binary polymer blends with both phase separation and crystallization. Macromolecules 42, 7623–7626 (2009). https://doi.org/10.1021/ma901543c
Pozar, D.M.: Microwave Engineering, 4th edn. Wiley, New York (2011).
Radwan, A.G.: Resonance and quality factor of the \(RL_{\alpha} C_{\alpha}\) fractional circuit. IEEE J. Emerg. Sel. Top. Circuits Syst. 3(3), 377–385 (2013). https://doi.org/10.1109/JETCAS.2013.2272838
Ramanathan, M., Darling, S.: Optical microscopy (polarized, interference, and phase-contrast microscopy) and confocal microscopy. In: Characterization of Polymer Blends: Miscibility, Morphology and Interfaces, pp. 523–550 (2015). https://doi.org/10.1002/9783527645602.ch16
Rujun, B., Hernandez, G.A., Yang, C., Sellers, J.A., Ellis, C.D., Tuckerman, D.B., Hamilton, M.C.: Cryogenic microwave characterization of Kapton polyimide using superconducting resonators. In: 2016 IEEE MTT-S International Microwave Symposium (IMS), 22-27 May 2016, pp. 1–4 (2016). https://doi.org/10.1109/MWSYM.2016.7539977.
Rusu, M., Airinei, A., Butuc, E., Rusu, G.G., Baban, C., Rusu, G.I.: On the electrical properties of some modified polysulfones in thin films. J. Macromol. Sci., Part B 37(1), 73–82 (1998). https://doi.org/10.1080/00222349808220456
Saini, P., Aror, M.: Microwave absorption and EMI shielding behavior of nanocomposites based on intrinsically conducting polymers, graphene and carbon nanotubes. In: New Polymers for Special Applications (2012). https://doi.org/10.5772/48779
Sánchez-Valdes, S., Ramos-De Valle, L.F., Manero, O.: Polymer blends. In: Handbook of Polymer Synthesis, Characterization, and Processing, pp. 505–517 (2013). https://doi.org/10.1002/9781118480793.ch27
Sastri, V.: Materials used in medical devices. In: Plastics in Medical Devices, pp. 19–31 (2014). https://doi.org/10.1016/b978-0-8155-2027-6.10003-0
Saxena, P., Gaur, M.S.: Electrical conduction mechanism of polyvinylidenefluoride (PVDF) – polysulfone (PSF) blend film. J. Electrost. 67(6), 844–849 (2009). https://doi.org/10.1016/j.elstat.2009.07.004
Scobbo, J., Goettler, L.: Applications of polymer alloys and blends. In: Polymer Blends Handbook, p. 951. Springer, Berlin (2003). ISBN 978-1-4020-1114-6. https://doi.org/10.1007/0-306-48244-4_13.
Sebastian, M.T.: Measurement of microwave dielectric properties and factors affecting them. In: Sebastian, M.T. (ed.) Dielectric Materials for Wireless Communication, pp. 11–47. Elsevier, Amsterdam (2008). Chapter Two. https://doi.org/10.1016/B978-0-08-045330-9.00002-9
Shantanu Dixit, E.D., Anandraj, J., Pandey, M., Joshi, G.M., Madhusudhana Rao, N., Kaleemulla, S., Shirale, D.J., Teresa, M.: Cuberes: resonance frequency, bandwidth and quality factor of varying grades of poly (tetrafluroethylene) films. Mech. Mater. Sci. Eng. 10 (2017). https://doi.org/10.2412/mmse.29.22.320
Sharma, P., Kanchan, D.K.: A comparison of effect of PEG and EC plasticizers on relaxation dynamics of PEO–PMMA–AgNO3 polymer blends. Ionics 19(9), 1285–1290 (2013). https://doi.org/10.1007/s11581-013-0851-z
Sharma, B.K., Khare, N., Dhawan, S.K., Gupta, H.C.: Dielectric properties of nano-ZnO-polyaniline composite in the microwave frequency range. J. Alloys Compd. 477(1–2), 370–373 (2009). https://doi.org/10.1016/j.jallcom.2008.10.004
Shrivas, S., Patel, S., Dubey, R.K., Keller, J.M.: Polarization behaviour of polyvinylidenefluoride-polysulfone (PVDF: PSF) blends under high field and high temperature condition. AIP Conf. Proc.. (2018). https://doi.org/10.1063/1.5032690
Tang, B., Zhang, X., Fang, Z., Liu, Q., Zhang, S.: Preparation and characterization of (Co0.3Zn0.7) (Ti1-xSnx)Nb2O8 microwave dielectric ceramics. Mater. Sci.-Pol. 35, 405–411 (2017). https://doi.org/10.1515/msp-2017-0042
Yadav, V.S., Sahu, D.K., Singh, Y., Kumar, M., Dhubkarya, D.C.: Frequency and temperature dependence of dielectric properties of pure poly vinylidene fluoride (PVDF) thin films. AIP Conf. Proc. 1285(1), 267–278 (2010). https://doi.org/10.1063/1.3510553
Yang, L., Ji, H., Qiu, J., Zhu, K., Shao, B.: Effect of temperature on the crystalline phase and dielectric and ferroelectric properties of poly(vinylidene fluoride) film. J. Intell. Mater. Syst. Struct. 25(7), 858–864 (2013). https://doi.org/10.1177/1045389x13510217
Yang, L., Liu, L., Wang, Z.: Preparation of PVDF/GO SiO2 hybrid microfiltration membrane towards enhanced perm-selectivity and anti-fouling property. J. Chin. Inst. Chem. Eng. 78, 500–509 (2017). https://doi.org/10.1016/j.jtice.2017.06.018
Yu, L., Dean, K., Li, L.: Polymer blends and composites from renewable resources. Prog. Polym. Sci. 31, 576–602 (2006). https://doi.org/10.1016/j.progpolymsci.2006.03.002
Zhang, J., Zuo, R., Song, J., Xu, Y., Shi, M.: Low-loss and low-temperature firable Li2Mg3SnO6-Ba3(VO4)2 microwave dielectric ceramics for LTCC applications. Ceram. Int. 44(2), 2606–2610 (2018). https://doi.org/10.1016/j.ceramint.2017.10.195
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The authors are thankful to the Institute of Chemical Technology Mumbai for providing OPM facility and Vellore institute of technology, Vellore (India) for providing the electrical characterization facility.
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Humbe, S.S., Joshi, G.M., Deshmukh, R.R. et al. Improved under damped oscillator properties of polymer blends for electronic applications. Mech Time-Depend Mater 26, 119–132 (2022). https://doi.org/10.1007/s11043-020-09478-6
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DOI: https://doi.org/10.1007/s11043-020-09478-6