Skip to main content
SpringerLink
Log in

The Reaction of (1,3,4-Oxadiazole-Thiolato) Mercury(II) with Triphenyl Phosphine

  • STRUCTURE OF ORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The reaction of 5-phenyl-1,3,4-oxadiazole-2-thiol with mercury(II) acetate in ethanol led to the isolation of the complex [Hg(L)2] (1). Further reaction of 1 with a twofold molar excess of triphenylphosphine led to the isolation of [Hg(L)2(PPh3)2] (2). The complex 2 was characterized by infrared, ultraviolet–visible and nuclear magnetic resonance spectroscopy techniques, as well as by X-ray diffraction analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. B. Kumar, A. Kumar, A. K. Beheraand, and V. Raj, J. Cell. Sci. Ther. 7, 1 (2016).

    Google Scholar 

  2. B. A. H. Alsafee, Swed. J. Sci. Res. 1, 11 (2014).

    Google Scholar 

  3. J. Boström, A. Hogner, A. Llinàs, et al., J. Med. Chem. 5, 1817 (2012).

    Article  Google Scholar 

  4. Nagaraj, K. C. Chaluvaraju, M. S. Niranjan, and S. Kiran, Int. J. Pharm. Sci. 3, 9 (2011).

    Google Scholar 

  5. B. N. Goswami, J. C. S. Kataky, J. N. Baruah, and S. C. Nath, J. Heterocycl. Chem. 1, 205 (1984).

    Article  Google Scholar 

  6. A. Kiss-Szikszaia, T. Patonay, and J. Jekőb, ARKIVOC 3, 40 (2001).

    Google Scholar 

  7. A. Hasan, N. F. Thomas, and S. Gapil, Molecules 2, 1297 (2011).

    Article  Google Scholar 

  8. M. T. Omar, Arch. Pharm. Res. 6, 602 (1997).

    Article  Google Scholar 

  9. M. Matsumuto, Y. Kawamura, Y. Yasuda, et al., J. Antibiot. 10, 1465 (1989).

    Article  Google Scholar 

  10. M. M. Dutta, B. N. Goswam, and J. C. S. Kataky, J. Heterocycl. Chem. 3, 793 (1986).

    Article  Google Scholar 

  11. T. M. C. Tan, Y. Chen, K. H. Kong, et al., Antiviral Res. 1, 7 (2006).

    Article  Google Scholar 

  12. S. Wagle, A. V. Adhikari, and N. S. Kumari, Indian J. Chem. B 3, 439 (2008).

    Google Scholar 

  13. N. K. Singh, M. K. Bharty, R. Dulare, and R. J Butcher, Polyhedron 12, 2443 (2009).

    Article  Google Scholar 

  14. F. Bentiss, M. Lagrenee, H. Vezin, et al., Polyhedron 23, 1903 (2004).

    Article  Google Scholar 

  15. M. Amir and K. Shikha, Eur. J. Med. Chem. 39, 535 (2004).

    Article  Google Scholar 

  16. P. Tripathi, A. Pal, V. Jancik, et al., Polyhedron 26, 2597 (2007).

    Article  Google Scholar 

  17. O. H. Amin, L. J. Al-Hayaly, S. A. Al-Jibori, and T. A. Al-Allaf, Polyhedron 23, 2013 (2004).

    Article  Google Scholar 

  18. H. X. Xu, J. P. Ma, R. Q. Huang, and Y. B. Dong, Acta Crystallogr. E 61, m2462 (2005).

    Article  Google Scholar 

  19. Y. T. Wang and G. M. Tang, Inorg. Chem. Commun. 10, 53 (2007).

    Article  Google Scholar 

  20. M. Du, Z. H. Zhang, X. J. Zhao, and Q. Xu, Inorg. Chem. 45, 5785 (2006).

    Article  Google Scholar 

  21. Bruker, APEX2, SADABS, SAINT (Bruker AXS Inc., Madison, Wisconsin, USA, 201).

  22. G. M. Sheldrick, Acta Crystallogr. A 64,112 (2008).

    Article  ADS  Google Scholar 

  23. C. B. Hubschle, G. M. Sheldrick, and B. Dittrich, J. Appl. Crystallogr. 44, 1281 (2011).

    Article  Google Scholar 

  24. N. Singh and R. S. Kumar, Inorg. Chem. Commun. 4, 454 (2001).

    Article  Google Scholar 

  25. A. S. Al-Jibori and S. S. A. Al-Zaubai, Transition Met. Chem. 32, 281 (2007).

    Google Scholar 

  26. J. C. Pessoa, M. T. Duarte, R. D. Gillard, et al., J. Chem. Soc. Dalton Trans. 23, 4015 (1998).

    Article  Google Scholar 

  27. A. S. M. Al-Janabi, G. A. Al-Soumadaiy, and B. A. Khear-Allah, Orient J. Chem. 27,1465 (2011).

    Google Scholar 

  28. T. A. K. Al-Allaf, H. Schmidt, K. Merzweiler, et al., J. Organomet. Chem. 678, 48 (2003).

    Article  Google Scholar 

  29. H. Nöth, W. Beck, and K. Burger, Eur. J. Inorg. Chem. 1998, 93 (1998).

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors thank the Chemistry Department, the College of Education and the Salahaddin University for their assistance in accomplishment of this work.

Author information

Authors and Affiliations

  1. Department of Chemistry, College of Education, Salahaddin University-Erbil, Erbil, Iraq

    H. A. Mohamad

  2. Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

    T. I. A. Gerber & E. C. Hosten

Authors
  1. H. A. Mohamad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. I. A. Gerber
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. C. Hosten
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. A. Mohamad.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mohamad, H.A., Gerber, T.I. & Hosten, E.C. The Reaction of (1,3,4-Oxadiazole-Thiolato) Mercury(II) with Triphenyl Phosphine. Crystallogr. Rep. 65, 1117–1120 (2020). https://doi.org/10.1134/S1063774520070123

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774520070123

Search

Navigation