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Dissociation of Phenylacetylene and Its Derivatives by Electron Impact

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Abstract

Phenylacetylene and its chemically active isomer pentalene play an important role in the formation and destruction of polyaromatic hydrocarbons—the main components of the soot microparticles formed during the combustion of fossil fuel, which are the most dangerous anthropogenic aerosol air pollutants for human health. The probable mechanisms of the decay of phenylacetylene and its isomers upon ionization by electron impact are considered. It is shown that the loss of electrons during ionization changes the aromatic/antiaromatic properties of phenylacetylene and its isomers to the opposite properties.

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Funding

This study was carried out in the framework of State Assignment of the Ministry of Science and Higher Education of the Russian Federation (registration number AAAA-A19-119010990034-5).

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Authors and Affiliations

  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    Yu. A. Dyakov, S. O. Adamson, G. V. Golubkov, I. I. Morozov, O. A. Olkhov, V. L. Shapovalov, D. V. Shestakov & M. G. Golubkov

  2. National Taipei University of Nursing and Health Science, Taipei, Taiwan

    A. A. Puzankov

  3. National Research Center “Kurchatov Institute”, Moscow, Russia

    G. V. Golubkov

Authors
  1. Yu. A. Dyakov
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  2. A. A. Puzankov
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  3. S. O. Adamson
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  4. G. V. Golubkov
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  5. I. I. Morozov
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  6. O. A. Olkhov
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  7. V. L. Shapovalov
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  8. D. V. Shestakov
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  9. M. G. Golubkov
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Correspondence to Yu. A. Dyakov.

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Dyakov, Y.A., Puzankov, A.A., Adamson, S.O. et al. Dissociation of Phenylacetylene and Its Derivatives by Electron Impact. Russ. J. Phys. Chem. B 14, 728–732 (2020). https://doi.org/10.1134/S1990793120050188

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  • DOI: https://doi.org/10.1134/S1990793120050188

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