Abstract
In this paper, we study the energetic capabilities of four N-dinitro- and N-trinitromethyl derivatives of nitroazoles described in the literature as potential components of composite solid propellants. Using the thermodynamic calculations, some of the considered compounds are shown to have good potential for the creation of solid propellants with improved energy characteristics based on them. The quantitative dependences of the energetic parameters of the fuel on the properties of the studied oxidizer, the aluminum fraction in the composition, and the type and the content of binder are established.
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Funding
This study was supported by the Institute of Problems of Chemical Physics, Russian Academy of Sciences (IPCP RAS) (topic no. 0089-2014-0019 “Creation of high-energy materials and technologies for developed and advanced systems”), the Presidium of the Russian Academy of Sciences “Development of solid fuels and combustibles for gas generators of ramjet engines of hypersonic aircraft and research of heat and mass transfer and combustion in gas generators” as part of program 56 “Fundamentals of breakthrough technologies in the interests of national security.”
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Zyuzin, I.N., Gudkova, I.Y. & Lempert, D.B. Energetic Capabilities of N-Dinitro- and N-Trinitromethyl Derivatives of Nitroazoles as Composite Solid Propellant Components. Russ. J. Phys. Chem. B 14, 804–813 (2020). https://doi.org/10.1134/S1990793120050140
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DOI: https://doi.org/10.1134/S1990793120050140