Skip to main content
SpringerLink
Log in

Hydrogen Peroxide Decomposition Catalyzed by Iron Hydroxide Supported on Cellulose

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

Colloidal particles of iron hydroxide produced by the hydrolysis of an iron(III) chloride solution in hot water catalyze the consumption of hydrogen peroxide and initiate the oxidative decomposition of impurities present in technical cellulose. This causes the bleaching of cellulose, and its degree depends on the concentrations of reagents and conditions of the process. The main products of the parallel oxidative destruction of cellulose itself are formic and other carboxylic acids. The regularities and features of the processes are analyzed; the kinetic parameters of the peroxide decomposition and acid formation are determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Nanocatalysis: Synthesis and Application, Ed. by V. Polshettiwar and T. N. Y. Asefa (Wiley, New York, 2013).

    Google Scholar 

  2. A. I. Kryukov, A. L. Stroyuk, S. Ya. Kuchmii, and V. D. Pokhodenko, Nanophotocatalysis (Akademperiodika, Kiev, 2013) [in Russian].

    Google Scholar 

  3. I. V. Kumpanenko, A. V. Roshchin, N. A. Ivanova, E. I. Zelenina, T. C. Volchenko, and E. O. Panin, Russ. J. Phys. Chem. B 12, 58 (2018).

    Article  CAS  Google Scholar 

  4. I. V. Moskalenko, I. V. Tikhonov, E. M. Pliss, M. A. Fomich, V. V. Shmanai, and A. I. Rusakov, Russ. J. Phys. Chem. B 12, 987 (2018).

    Article  CAS  Google Scholar 

  5. I. V. Tikhonov, E. M. Pliss, L. I. Borodin, and V. D. Sen’, Russ. J. Phys. Chem. B 11, 400 (2017).

    Article  CAS  Google Scholar 

  6. I. V. Tikhonov, I. V. Moskalenko, E. M. Pliss, M. A. Fomich, A. V. Bekish and V. V. Shmanai, Russ. J. Phys. Chem. B 11, 395 (2017).

    Article  CAS  Google Scholar 

  7. G. Zelmanov and R. Semit, Water Res. 42, 492 (2008).

    Article  CAS  Google Scholar 

  8. H. Michel, Angew. Chem., Int. Ed. Engl. 51, 2516 (2012).

    Article  CAS  Google Scholar 

  9. A. E. Kuznetsov and N. B. Gradova, Scientific Foundations of Ecobiotechnology (Mir, Moscow, 2006) [in Russian].

  10. L. M. Pisarenko, V. I. Lesin, and O. T. Kasaikina, Russ. Chem. Bull. 63, 688 (2014).

    Article  CAS  Google Scholar 

  11. V. I. Lesin, L. M. Pisarenko, and O. T. Kasaikina, RF Patent No. 2425715, Byull. Izobret., No. 22, 14 (2011).

  12. V. I. Lesin, L. M. Pisarenko, and O. T. Kasaikina, Colloid. J. 74, 85 (2012).

    Article  CAS  Google Scholar 

  13. O. T. Kasaikina, L. M. Pisarenko, and V. I. Lesin, Colloid. J. 74, 483 (2012).

    Article  CAS  Google Scholar 

  14. O. T. Kasaikina, L. M. Pisarenko, and I. V. Zinov’ev, RF Patent No. 2488445, Byull. Izobret., No. 21 (2013).

  15. O. T. Kasaikina, L. M. Pisarenko, and I. V. Zinov’ev, RF Patent No. 2515319, Byull. Izobret., No. 13 (2014).

  16. O. T. Kasaikina, V. I. Lesin, and L. M. Pisarenko, Catal. Sustain. Energy, No. 1, 21 (2014).

    Google Scholar 

  17. L. M. Pisarenko, O. T. Kasaikina, I. V. Zinov’ev, et al., in Proceedings of the 4th International Ecological Conference on Problems of Reclamation of Household Waste, Industry and Agricultural Production (Kuban.Gos. Agro Univ., Krasnodar, 2015), Part 1, p. 419.

  18. S. S. Voyutskii, Colloid Chemistry (Khimiya, Moscow, 1964) [in Russian].

    Google Scholar 

  19. L. M. Pisarenko, Russ. Chem. Bull. 67, 1026 (2018).

    Article  CAS  Google Scholar 

  20. V. B. Ivanov, E. V. Solina, O. V. Staroverova, E. I. Popova, O. L. Lazareva and O. A. Belova, Russ. J. Phys. Chem. B 11, 978 (2017).

    Article  CAS  Google Scholar 

  21. V. B. Ivanov, V. V. Bitt, E. V. Solina, and A. V. Samo-ryadov, Polymers (Basel) 11, 1579 (2019).

    Article  CAS  Google Scholar 

  22. A. Y. Kuptsov and G. N. Zhizhin, Handbook of Fourier Transform Raman and Infrared Spectra of Polymers, Vol. 45 of Physical Sciences Data (Elsevier, Amsterdam, 1998).

Download references

ACKNOWLEDGMENTS

The authors thank N.B. Polyanskii (Institute of Biochemical Physics, Russian Academy of Sciences) for assisting in the analysis of Fe(III) and O.V. Staroverova for measuring and analyzing the IR spectra.

Funding

The work was performed in accordance with state contract no. 0082-18-006 (no. AAAA-A18-118020890097-1).

Author information

Authors and Affiliations

  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 117977, Moscow, Russia

    L. M. Pisarenko, O. T. Kasaikina & V. B. Ivanov

Authors
  1. L. M. Pisarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. T. Kasaikina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. B. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. B. Ivanov.

Additional information

Translated by L. Chernikova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pisarenko, L.M., Kasaikina, O.T. & Ivanov, V.B. Hydrogen Peroxide Decomposition Catalyzed by Iron Hydroxide Supported on Cellulose. Russ. J. Phys. Chem. B 14, 773–780 (2020). https://doi.org/10.1134/S1990793120050097

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793120050097

Keywords:

Search

Navigation