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Effect of Chemical Modification of the Tetrapyrrole Macrocycle Structure on the Spectral, Acid–Base, and Complexing Properties of tert-Butyl-Substituted Porphyrazines

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Abstract

The effect of chemical modification of the tetrapyrrole macrocycle structure on the spectral, acid–base, and complexing properties of tetrakis[5,6-bis(4-tert-butylphenyl)pyrazino]porphyrazine, tetra(4-tert-butyl)phthalocyanine, and octakis(4-tert-butylphenyl)porphyrazine in acetonitrile at 298–318 K has been studied by 1H NMR, electronic spectroscopy, and mass spectrometry. The obtained results can be used in the design of macrocyclic tetrapyrrole functional materials with desired physicochemical properties.

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ACKNOWLEDGMENTS

This study was performed using the equipment of the Upper Volga Regional Center for Physicochemical Studies.

Funding

This study was performed under financial support by the Russian Foundation for Basic Research (project no. 19-73-20079, spectral studies) and by the state research program (project no. FZZW-2020-0008, synthesis of porphyrazines).

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153040, Ivanovo, Russia

    Yu. B. Ivanova, T. V. Lyubimova & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    A. S. Semeikin & T. V. Lyubimova

Authors
  1. Yu. B. Ivanova
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  2. A. S. Semeikin
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  3. T. V. Lyubimova
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  4. N. Zh. Mamardashvili
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Correspondence to Yu. B. Ivanova.

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Ivanova, Y.B., Semeikin, A.S., Lyubimova, T.V. et al. Effect of Chemical Modification of the Tetrapyrrole Macrocycle Structure on the Spectral, Acid–Base, and Complexing Properties of tert-Butyl-Substituted Porphyrazines. Russ J Org Chem 56, 1691–1695 (2020). https://doi.org/10.1134/S1070428020100036

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