Abstract
In this work, the effect of Cu addition on the microstructure and corrosion passivation behavior of Sn alloyed ferritic stainless steel in 3.5 wt.% NaCl solution at 30 °C was investigated by optical microscope (OM), scanning electron microscope (SEM), energy-dispersion spectrum (EDS), potentiodynamic polarization curve and x-ray photoelectron spectroscopy (XPS). The results indicate that Cu addition has certain effect on grain refinement of ferritic stainless steel. Meanwhile, Cu addition has little influence on the cathodic corrosion process of ferritic stainless steel in 3.5 wt.% NaCl solution but shows beneficial effect on enhancing both the corrosion resistance of steel substrate and its passivation behavior. It has been found that the deposition of Cu particles at the bottom of corrosion pits is responsible for the better corrosion resistance and passivation behavior of ferritic stainless steel. Moreover, there is synergistic effect between Sn and Cu on enhancing the corrosion resistance of ferric stainless steel matrix and improving its passivation behavior in NaCl solution.
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X. Zhang, Y. Zhang, Y.D. Wu, S.S. Ao, and Z. Luo, Effects of Melting-Mixing Ratio on the Interfacial Microstructure and Tensile Properties of Austenitic–Ferritic Stainless Steel Joints, J. Mater. Res. Technol., 2019, 8(3), p 2649–2661
X.G. Ma, J.W. Zhao, W. Du, X. Zhang, L.Z. Jiang, and Z.Y. Jiang, Quantification of Texture-Induced Ridging in Ferritic Stainless Steels 430 and 430LR During Tensile Deformation, J. Mater. Res. Technol., 2019, 8(2), p 2041–2051
N. Fujita, K. Ohmura, and A. Yamamoto, Changes of Microstructures and High Temperature Properties During High Temperature Service of Niobium Added Ferritic Stainless Steels, Mater. Sci. Eng., A, 2003, 351, p 272–281
J.S. Peltz, L.M. Antonini, S.R. Kunst, G.A. Ludwig, L.T. Fuhr, and C.F. Malfattiet, Effect of Application of the Shot Peening Process in the Corrosion Resistance of the AISI, 430 Ferritic Stainless Steel, Mater. Sci. Forum, 2014, 775–776, p 365–369
H. Luo, H.Z. Su, B.S. Li, and G.B. Ying, Electrochemical and Passive Behavior of Tin Alloyed Ferritic Stainless Steel in Concrete Environment, Appl. Surf. Sci., 2018, 439, p 232–239
J. Shu, H.Y. Bi, X. Li, and Z. Xu, The Effect of Copper and Molybdenum on Pitting Corrosion and Stress Corrosion Cracking Behavior of Ultra-Pure Ferritic Stainless Steels, Corros. Sci., 2012, 57, p 89–98
B. Liu, X. Mu, Y. Yang, L. Hao, X.Y. Ding, J.H. Dong, Z. Zhang, H.X. Hou, and W. Ke, Effect of Tin Addition on Corrosion Behavior of a Low-Alloy Steel in Simulated Costal-Industrial Atmosphere, J. Mater. Sci. Technol., 2019, 35, p 1228–1239
W.F. Wang, Effect of Tin Addition on the Microstructure Development and Corrosion Resistance of Sintered 304L Stainless Steels, J. Mater. Eng. Perform., 1999, 8(6), p 649–652
X.H. Hao, J.H. Dong, X. Mu, J. Wei, C.G. Wang, and W. Ke, Influence of Sn and Mo on Corrosion Behavior of Ferrite-Pearlite Steel in the Simulated Bottom Plate Environment of Cargo Oil Tank, J. Mater. Sci. Technol., 2019, 35, p 799–811
H.X. Li, H. Yu, T. Zhou, B.L. Yin, S.J. Yin, and Y.L. Zhang, Effect of Tin on the Corrosion Behavior of Sea-Water Corrosion-Resisting Steel, Mater. Des., 2015, 84(5), p 1–9
T. Kamimura, K. Kashima, K. Sugae, H. Miyuki, and T. Kudo, The Role of Chloride Ion on the Atmospheric Corrosion of Steel and Corrosion Resistance of Sn-Bearing Steel, Corros. Sci., 2012, 62, p 34–41
N.D. Nam, M.J. Kim, Y.W. Jang, and J.G. Kim, Effect of Tin on the Corrosion Behavior of Low-Alloy Steel in an Acid Chloride Solution, Corros. Sci., 2010, 52, p 14–20
N.D. Greene, C.R. Bishop, and M. Stern, Corrosion and Electrochemical Behavior of Chromium-Noble Metal Alloys, J. Electrochem. Soc., 1961, 108(9), p 836–841
T. Ujiro, S. Satoh, R.W. Staehle, and W.H. Smyrl, Effect of Alloying Cu on the Corrosion Resistance of Stainless Steels in Chloride Media, Corros. Sci., 2001, 43(11), p 2185–2200
A. Pardo, M.C. Merino, M. Carboneras, F. Viejo, R. Arrabal, and J. Munoz, Influence of Cu and Sn Content in the Corrosion of AISI, 304 and 316 Stainless Steels in H2SO4, Corros. Sci., 2006, 48(5), p 1075–1092
X.J. Zhang and Z.Y. Liu, Synergy Effects of Cu and Sn on Pitting Corrosion Resistance of Ultra-Purified Medium Chromium Ferritic Stainless Steel, IOP Conf. Ser.: Mater. Sci. Eng., 2017, 182(1), p 012032
M. Sun, M. Luo, C. Lu, T.W. Liu, Y.P. Wu, L.Z. Jiang, and J. Li, Effect of Alloying Tin on the Corrosion Characteristics of Austenitic Stainless Steel in Sulfuric Acid and Sodium Chloride Solutions, Acta Metall. Sin. Engl. Lett., 2015, 28(9), p 1089–1096
A. Pardo, M.C. Merino, M. Carboneras, A.E. Coy, and R. Arrabal, Pitting Corrosion Behaviour of Austenitic Stainless Steels–Combining Effects of Mn and Mo Additions, Corros. Sci., 2008, 50(6), p 1796–1806
Y. Li, G. Yang, Z.H. Jiang, C.Y. Chen, S. Sun, and P.F. Du, Effects of Ce on the Microstructure and Properties of 27Cr-3.8 Mo-2Ni Super-Ferritic Stainless Steels, Ironmak. Steelmak., 2018, 47(1), p 67–76
D. Ye, J. Li, W. Jiang, J. Su, and K.Y. Zhao, Effect of Cu Addition on Microstructure and Mechanical Properties of 15% Cr Super Martensitic Stainless Steel, Mater. Des., 2012, 41, p 16–22
G.T. Burstein, P.C. Pistorius, and S.P. Mattin, The Nucleation and Growth of Corrosion Pits on Stainless Steel, Corros. Sci., 1993, 35(1–4), p 57–62
H. Su, X.B. Luo, C.F. Yang, F. Chai, and H. Li, Effects of Cu on Corrosion Resistance of Low Alloyed Steels in Acid Chloride Media, J. Iron. Steel Res. Int., 2014, 21(6), p 619–624
A.V. Naumkin, A. Kraut-Vass, and S.W. Gaarenstroom, NIST X-ray Photoelectron Spectroscopy Database, Cedric J. Powell, 2012, https://doi.org/10.18434/T4T88K
C.T. Liu and J.K. Wu, Influence of pH on the Passivation Behavior of 254SMO Stainless Steel in 3.5% NaCl Solution, Corros. Sci., 2007, 49(5), p 2198–2209
J. Liu, T. Zhang, G.Z. Meng, Y.W. Shao, and F.H. Wang, Effect of Pitting Nucleation on Critical Pitting Temperature of 316L Stainless Steel by Nitric Acid Passivation, Corros. Sci., 2015, 91, p 232–244
P. Ghods, O.B. Isgor, J.R. Brown, F. Bensebaa, and D. Kingston, XPS Depth Profiling Study on the Passive Oxide Film of Carbon Steel in Saturated Calcium Hydroxide Solution and the Effect of Chloride on the Film Properties, Appl. Surf. Sci., 2011, 257(10), p 4669–4677
T.J. Mesquita, E. Chauveau, M. Mantel, and R.P. Nogueira, A XPS Study of the Mo Effect on Passivation Behaviors for Highly Controlled Stainless Steels in Neutral and Alkaline Conditions, Appl. Surf. Sci., 2013, 270, p 90–97
K. Volgmann, F. Voigts, and W. Maus-Friedrichs, The Interaction of Oxygen Molecules with Iron Films Studied with MIES, UPS and XPS, Surf. Sci., 2010, 604(11–12), p 906–913
H. Luo, X.G. Li, C.F. Dong, K. Xiao, and X.Q. Cheng, Influence of UV Light on Passive Behavior of the 304 Stainless Steel in Acid Solution, J. Phys. Chem. Solids, 2013, 74(5), p 691–697
Z.Y. Ai, J.Y. Jiang, W. Sun, D. Song, H. Ma, J.C. Zhang, and D.Q. Wang, Passive Behaviour of Alloy Corrosion-Resistant Steel Cr10Mo1 in Simulating Concrete Pore Solutions with Different pH, Appl. Surf. Sci., 2016, 389, p 1126–1136
A.P. Grosvenor, B.A. Kobe, M.C. Biesinger, and N.S. Mclntyre, Investigation of Multiplet Splitting of Fe 2p XPS Spectra and Bonding in Iron Compounds, Surf. Interface Anal., 2004, 36(12), p 1564–1574
L.A.S. Ries, M.D.C. Belo, M.G.S. Ferreira, and L. Muller, Chemical Composition and Electronic Structure of Passive Films Formed on Alloy 600 in Acidic Solution, Corros. Sci., 2008, 50(3), p 676–686
A. Lazauskas, V. Grigaliūnas, A. Guobienė, M. Andrulevičius, and J. Baltrusaitis, Atomic Force Microscopy and X-Ray Photoelectron Spectroscopy Evaluation of Adhesion and Nanostructure of Thin Cr Films, Thin Solid Films, 2012, 520(19), p 6328–6333
Y. Han, J. Mei, Q.J. Peng, E.H. Han, and W. Ke, Effect of Electropolishing on Corrosion of Nuclear Grade 316L Stainless Steel in Deaerated High Temperature Water, Corros. Sci., 2016, 112, p 625–634
C.O.A. Olsson and D. Landolt, Passive Films on Stainless Steels-Chemistry, Structure and Growth, Electrochim. Acta, 2003, 48(9), p 1093–1104
R.O. Ansell, T. Dickinson, A.F. Povey, and P.M.A. Sherwood, X-Ray Photoelectron Spectroscopic Studies of Tin Electrodes After Polarization in Sodium Hydroxide Solution, J. Electrochem. Soc., 1977, 124(9), p 1360–1364
J. Huang, X. Wu, and E.H. Han, Electrochemical Properties and Growth Mechanism of Passive Films on Alloy 690 in High-Temperature Alkaline Environments, Corros. Sci., 2010, 52(10), p 3444–3452
G. Okamoto, Passive Film of 18-8 Stainless Steel Structure and Its Function, Corros. Sci., 1973, 13(6), p 471–489
M.N. Wang, C. Qiao, X.L. Jiang, L. Hao, and X.H. Liu, Microstructure Induced Galvanic Corrosion Evolution of SAC305 Solder Alloys in Simulated Marine Atmosphere, J. Mater. Sci. Technol., 2020, 51, p 40–53
C. Qiao, L.F. Shen, L. Hao, X. Mu, J.H. Dong, W. Ke, J. Liu, and B. Liu, Corrosion Kinetics and Patina Evolution of Galvanized Steel in a Simulated Coastal-Industrial Atmosphere, J. Mater. Sci. Technol., 2019, 35, p 2345–2356
C.I. House and G.H. Kelsall, Potential-pH Diagrams for the Sn/H2O-Cl System, Electrochim. Acta, 1984, 29(10), p 1459–1464
C. Qiao, M.N. Wang, L. Hao, X.L. Jiang, X.H. Liu, Ch Thee, and X.Z. An, In-Situ EIS Study on the Initial Corrosion Evolution Behavior of SAC305 Solder Alloy Covered with NaCl Solution, J. Alloys Compd., 2021, 852, p 156953
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The authors acknowledge the financial support by National Natural Science Foundation of China (51674071).
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Li, Y., Yao, C., Li, H. et al. Effect of Cu Addition on the Microstructure and Passivation Behavior of Sn Alloyed Ferritic Stainless Steel in NaCl Solution. J. of Materi Eng and Perform 29, 8422–8430 (2020). https://doi.org/10.1007/s11665-020-05303-w
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DOI: https://doi.org/10.1007/s11665-020-05303-w