Abstract
The effect of addition of graphene nanoplatelets (GnPs) on the mechanical behavior of unidirectional S-glass fiber based composites fabricated through the hand layup technique, followed by hot compression moulding were investigated. The GnPs with varying concentrations were introduced into the composites in two different ways, i.e., (1) GnPs in matrix; (2) GnPs on the fiber surface (GnPs coated fibers fabric). The influence of method of incorporation of GnPs in the composites were evaluated from the mechanical properties, i.e., tensile, fiber pull-out and drop weight impact tests. The composite containing 0.5 wt.% GnPs on fiber surface showed the highest tensile strength with an improvement of 212% and the composite containing 0.5 wt.% GnPs in matrix showed higher energy absorption with 52% over the pristine composite. The influence of 0.5 wt.% GnPs added on the fiber surface improved the interfacial shear strength by 136% over pristine due to the enhancement of adhesion at the fiber/matrix interface.
Similar content being viewed by others
References
N.A. Siddiqui, M.L. Sham, B.Z. Tang, A. Munir, and J.K. Kim, Tensile Strength of Glass Fibres with Carbon Nanotube-Epoxy Nanocomposite Coating, Compos. Part A Appl. Sci. Manuf., 2009, 40(10), p 1606–1614. https://doi.org/10.1016/j.compositesa.2009.07.005
A. Bianco, H.M. Cheng, T. Enoki, Y. Gogotsi, R.H. Hurt, N. Koratkar, T. Kyotani, M. Monthioux, C.R. Park, J.M.D. Tascon, J. Zhang, A. Bianco, H.M. Cheng, T. Enoki, Y. Gogotsi, and R.H. Hurt, All in the Graphene Family—A Recommended Nomenclature for Two-Dimensional Carbon Materials, Carbon N. Y., 2013, 65, p 1–6
S.G. Prolongo, A. Jiménez-Suárez, R. Moriche, and A. Ureña, Graphene Nanoplatelets Thickness and Lateral Size Influence on the Morphology and Behavior of Epoxy Composites, Eur. Polym. J., 2014, 53, p 292–301
T. Kuilla, S. Bhadra, D. Yao, N.H. Kim, S. Bose, and J.H. Lee, Recent Advances in Graphene Based Polymer Composites, Prog. Polym. Sci., 2010, 35(11), p 1350–1375. https://doi.org/10.1016/j.progpolymsci.2010.07.005
A.K. Geim, K.S. Novoselov, A.K. Geim, and K.S. Novolesov, The Rise of Graphene, Nat. Mater., 2007, 6(3), p 183–191
L.M. Viculis, J.J. Mack, O.M. Mayer, H.T. Hahn, and R.B. Kaner, Intercalation and Exfoliation Routes to Graphite Nanoplatelets, J. Mater. Chem., 2005, 15(9), p 974–978
M.A. Rafiee, J. Rafiee, Z. Wang, H. Song, Z. Yu, and N. Koratkar, Enhanced Mechanical Properties of Nanocomposites at Low Graphene Content, ACS Nano, 2009, 3(12), p 3884–3890. https://doi.org/10.1021/nn9010472
R. Moriche, S.G. Prolongo, M. Sánchez, A. Jiménez-Suárez, M.J. Sayagués, and A. Ureña, Morphological Changes on Graphene Nanoplatelets Induced during Dispersion into an Epoxy Resin by Different Methods, Compos. Part B Eng., 2015, 72, p 199–205. https://doi.org/10.1016/j.compositesb.2014.12.012
G.V. Seretis, G. Kouzilos, D.E. Manolakos, and C.G. Provatidis, On the Graphene Nanoplatelets Reinforcement of Hand Lay-up Glass Fabric/Epoxy Laminated Composites, Compos. Part B Eng., 2017, 118, p 26–32. https://doi.org/10.1016/j.compositesb.2017.03.015
B. Ahmadi-Moghadam and F. Taheri, Influence of Graphene Nanoplatelets on Modes I, II, and III, Interlaminar Fracture Toughness of Fiber-Reinforced Polymer Composites, Eng. Fract. Mech., 2015, 143, p 97–107. https://doi.org/10.1016/j.engfracmech.2015.06.026
J. Jia, X. Du, C. Chen, X. Sun, Y.W. Mai, and J.K. Kim, 3D Network Graphene Interlayer for Excellent Interlaminar Toughness and Strength in Fiber Reinforced Composites, Carbon N. Y., 2015, 95, p 978–986. https://doi.org/10.1016/j.carbon.2015.09.001
N.T. Kamar, M.M. Hossain, A. Khomenko, M. Haq, L.T. Drzal, and A. Loos, Interlaminar Reinforcement of Glass Fiber/Epoxy Composites with Graphene Nanoplatelets, Compos. Part A Appl. Sci. Manuf., 2015, 70, p 82–92. https://doi.org/10.1016/j.compositesa.2014.12.010
G. Lubineau and A. Rahaman, A Review of Strategies for Improving the Degradation Properties of Laminated Continuous-Fiber/Epoxy Composites with Carbon-Based Nanoreinforcements, Carbon, 2012, https://doi.org/10.1016/j.carbon.2012.01.059
A. Warrier, A. Godara, O. Rochez, L. Mezzo, F. Luizi, L. Gorbatikh, S.V. Lomov, A.W. VanVuure, and I. Verpoest, The Effect of Adding Carbon Nanotubes to Glass/Epoxy Composites in the Fibre Sizing and/or the Matrix, Compos. Part A Appl. Sci. Manuf., 2010, 41(4), p 532–538. https://doi.org/10.1016/j.compositesa.2010.01.001
A. Godara, L. Gorbatikh, G. Kalinka, A. Warrier, O. Rochez, L. Mezzo, F. Luizi, A.W. van Vuure, S.V. Lomov, and I. Verpoest, Interfacial Shear Strength of a Glass Fiber/Epoxy Bonding in Composites Modified with Carbon Nanotubes, Compos. Sci. Technol., 2010, 70(9), p 1346–1352. https://doi.org/10.1016/j.compscitech.2010.04.010
U. Zaheer, A.A. Khurram, and T. Subhani, A Treatise on Multiscale Glass Fiber Epoxy Matrix Composites Containing Graphene Nanoplatelets, Adv. Compos. Hybrid Mater., 2018, 1(4), p 705–721. https://doi.org/10.1007/s42114-018-0057-y
G.V. Seretis, I.D. Theodorakopoulos, D.E. Manolakos, and C.G. Provatidis, Effect of Sonication on the Mechanical Response of Graphene Nanoplatelets/Glass Fabric/Epoxy Laminated Nanocomposites, Compos. Part B Eng., 2018, 147, p 33–41. https://doi.org/10.1016/j.compositesb.2018.04.034
S. Dolati, A. Fereidoon, and A. Sabet, Hail Impact Damage Behaviors of Glass Fiber Reinforced Epoxy Filled with Nanoclay, J. Compos. Mater., 2014, 48(10), p 1241–1249. https://doi.org/10.1177/0021998313484950
W. Rasband, “Image J,” U. S. National Institutes of Health, Bethesda, Maryland, USA, 2018, imagej.nih.gov/ij/.
S.-S.S. Du Sen, F. Li, H.M.H.-M. Xiao, Y.-Q.Y.Q. Li, N. Hu, and S.-Y.S.Y. Fu, Tensile and Flexural Properties of Graphene Oxide Coated-Short Glass Fiber Reinforced Polyethersulfone Composites, Compos. Part B Eng., 2016, 99, p 407–415. https://doi.org/10.1016/j.compositesb.2016.06.023
D. Pedrazzoli, A. Pegoretti, and K. Kalaitzidou, Synergistic Effect of Graphite Nanoplatelets and Glass Fibers in Polypropylene Composites, J. Appl. Polym. Sci., 2015, 132(12), p 1–8
G. Belingardi and R. Vadori, Low Velocity Impact Tests of Laminate Glass-Fiber-Epoxy Matrix Composite Material Plates, 2002, 27, p 213–229. https://doi.org/10.1016/S0734-743X(01)00040-9
M.J. Emerson, V.A. Dahl, K. Conradsen, L.P. Mikkelsen, and A.B. Dahl, A Multimodal Data-Set of a Unidirectional Glass Fibre Reinforced Polymer Composite, Data Br., 2018, 18, p 1388–1393. https://doi.org/10.1016/j.dib.2018.04.039
S. Keck and M. Fulland, Effect of Fibre Volume Fraction and Fibre Direction on Crack Paths in Unidirectional Flax Fibre-Reinforced Epoxy Composites under Static Loading, Theor. Appl. Fract. Mech., 2019, 101, p 162–168. https://doi.org/10.1016/j.tafmec.2019.01.028
V.V. Dubrovsky, V.A. Shapovalov, V.N. Aderikha, and S.S. Pesetskii, Effect of Hybrid Filling with Short Glass Fibers and Expanded Graphite on Structure, Rheological and Mechanical Properties of Poly(Ethylene Terephthalate), Mater. Today Commun., 2018, 17, p 15–23. https://doi.org/10.1016/j.mtcomm.2018.08.002
A. Bourmaud, J. Mérotte, D. Siniscalco, M. Le Gall, V. Gager, A. Le Duigou, F. Pierre, K. Behlouli, O. Arnould, J. Beaugrand, and C. Baley, Main Criteria of Sustainable Natural Fibre for Efficient Unidirectional Biocomposites, Compos. Part A Appl. Sci. Manuf., 2019, 124, p 105504
G.V. Seretis, G.N. Kouzilos, D.E. Manolakos, and C.G. Provatidis, Multi-Objective Optimization of Post-Curing Process for GNPs Reinforced Glass Fabric/Epoxy Nanocomposite Laminae, Polym. Compos., 2018, 39(S4), p E2483–E2489. https://doi.org/10.1002/pc.24777
H. Mahmood, L. Vanzetti, M. Bersani, and A. Pegoretti, Mechanical Properties and Strain Monitoring of Glass-Epoxy Composites with Graphene-Coated Fibers, Compos. Part A Appl. Sci. Manuf., 2018, 107, p 112–123. https://doi.org/10.1016/j.compositesa.2017.12.023
M. Rafiee, F. Nitzsche, and M.R. Labrosse, Fabrication and Experimental Evaluation of Vibration and Damping in Multiscale Graphene/Fiberglass/Epoxy Composites, J. Compos. Mater., 2019, 53(15), p 2105–2118
S. Menbari, A. Ashori, H. Rahmani, and R. Bahrami, Viscoelastic Response and Interlaminar Delamination Resistance of Epoxy/Glass Fiber/Functionalized Graphene Oxide Multi-Scale Composites, Polym. Test., 2016, 54, p 186–195. https://doi.org/10.1016/j.polymertesting.2016.07.016
ASTM, Standard Test Method for Measuring the Damage Resistance of a Fiber-Renforced Polymer Matrix Composite to a Drop-Weight Impact, ASTM Stand., 2012, https://doi.org/10.1520/d7136_d7136m-15
Acknowledgement
The authors acknowledge the technical support for testing drop weight impact test from the Department of Aerospace Engineering, Madras Institute of Technology, Anna University, Chennai, Tamil Nadu, India.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Veerakumar, V.G.S., Shanmugavel, B.P., Paskaramoorthy, R. et al. The Influence of Graphene Nanoplatelets on the Tensile and Impact Behavior of Glass-Fiber-Reinforced Polymer Composites. J. of Materi Eng and Perform 30, 596–609 (2021). https://doi.org/10.1007/s11665-020-05335-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-020-05335-2