SCHEDULED MAINTENANCE
Advances in polycyclization cascades in natural product synthesis
Yubo
Jiang, 
†ab
Edward A.
Anderson
*a
†ab
Edward A.
Anderson
*a
Abstract
Cascade reactions (also known as domino reactions) are arguably the most powerful means to achieve the construction of multiple ring systems in a single step. In this Tutorial Review, highlights in cascade polycyclizations applied to natural product syntheses over the last five years are discussed, including pericyclic, ionic, metal-catalyzed, organocatalytic, and radical processes. Significant developments in each of these fields that have advanced the state-of-the-art are a particular focus, including photochemical and electrochemical methods, novel biomimetic routes, and enantioselective cascades.
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