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Nanoscale engineering of catalytic materials for sustainable technologies

Abstract

Nanostructured materials of diverse architecture are ubiquitous in industrial catalysis. They offer exciting prospects to tackle various sustainability challenges faced by society. Since the introduction of the concept a century ago, researchers aspire to control the chemical identity, local environment and electronic properties of active sites on catalytic surfaces to optimize their reactivity in given applications. Nowadays, numerous strategies exist to tailor these characteristics with varying levels of atomic precision. Making headway relies upon the existence of analytical approaches able to resolve relevant structural features and remains challenging due to the inherent complexity even of the simplest heterogeneous catalysts, and to dynamic effects often occurring under reaction conditions. Computational methods play a complementary and ever-increasing role in pushing forward the design. Here, we examine how nanoscale engineering can enhance the selectivity and stability of catalysts. We highlight breakthroughs towards their commercialization and identify directions to guide future research and innovation.

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Fig. 1: Nanostructuring metal-based catalysts.
Fig. 2: Surface and interface engineering of catalysts for enhanced selectivity.
Fig. 3: Solving long-standing catalyst stability challenges through nanostructuring.
Fig. 4: Challenges in the design and implementation of nanostructured catalysts for sustainable technologies.

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Acknowledgements

N.Z. acknowledges the support from the National Key R&D Program of China, Ministry of Science and Technology of China (2017YFA0207302), the National Natural Science Foundation of China (21890752, 21731005) and the Tencent Foundation through the XPLORER PRIZE.

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Mitchell, S., Qin, R., Zheng, N. et al. Nanoscale engineering of catalytic materials for sustainable technologies. Nat. Nanotechnol. 16, 129–139 (2021). https://doi.org/10.1038/s41565-020-00799-8

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