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Influence of the Working Media of Fuel Cells on the Structure and Physicomechanical Characteristics of Ceramics of the ZrO2–Y2O3–NiO System

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We study the properties of ZrO2 –Y2O3 –NiO ceramics obtained by using the technologies of sintering of powders and tape casting in the intact state and after one-time reduction both in pure hydrogen and in Ar–5% H2 and N2 –10% H2 –5% CO2 mixtures. It is demonstrated that, by using the technology of tape casting, it is possible to obtain materials for anodes-substrates of solid-oxide fuel cells with smaller grains and a more uniform structure, which improves their strength characteristics. It is shown that, in the hydrogen-containing medium containing carbon dioxide (N2 –10% H2 –5% CO2 ), the strength of 8YSZ–Ni cermet decreases as its electric conductivity increases as compared with the material reduced in the Ar–5% H2 mixture.

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References

  1. F. M. Sapountzi, S. Brosda, K. M. Papazisi, S. P. Balomenou, and D. Tsiplakides, “Electrochemical performance of La0.75Sr0.25Cr0.9M0.1O3 perovskites as SOFC anodes in CO/CO2 mixtures,” J. Appl. Electrochem., 42, 727–735 (2012).

    Article  CAS  Google Scholar 

  2. A. Hagen, A. Winiwarter, H. Langnickel, and G. Johnson, “SOFC operation with real biogas,” Fuel Cells, 17 (6), 854–861 (2017).

    Article  CAS  Google Scholar 

  3. J. Fergus, R. Hui, X. Li, D. Wilkinson, and J. Zhang (editors), Solid Oxide Fuel Cells. Materials Properties and Performance, CRC Press, Boca Raton (2019).

    Google Scholar 

  4. B. Sarruf, J. Hong, R. Steinberger-Wilckens, and P. De Miranda, “CeO2–Co3O4 –CuO anode for direct utilization of methane or ethanol in solid oxide fuel cells,” Int. J. Hydr. Energy, 43, 6340–6351 (2018).

    Article  CAS  Google Scholar 

  5. B. Vasyliv, V. Podhurska, and O. Ostash, “Preconditioning of the YSZ–NiO fuel cell anode in hydrogenous atmospheres containing water vapor,” Nanoscale Res. Lett., 12, 265 (2017); DOI: https://doi.org/10.1186/s11671-017-2038-4.

    Article  CAS  Google Scholar 

  6. B. D. Vasyliv, V. Ya. Podhurska, O. P. Ostash, and V. V. Vira, “Effect of a hydrogen sulfide-containing atmosphere on the physical and mechanical properties of solid oxide fuel cell materials,” in: O. Fesenko and L. Yarsenko (editors), Nanocomposites, Nanostructures, and Their Applications, Springer, Berlin (2018), pp. 475–485.

  7. B. D. Vasyliv, V. Ya. Podhurs’ka, O. P. Ostash, O. D. Vasyl’ev, and E. M. Brodnikovs’kyi, “Influence of reducing and oxidizing media on the physicomechanical properties of ScCeSZ–NiO and YSZ–NiO ceramics,” Fiz.-Khim. Mekh. Mater., 49, No. 2, 5–13 (2013); English translation: Mater. Sci., 49, No. 6, 135–144 (2013).

  8. A. S. Thorel, “Tape casting ceramics for high temperature fuel cell applications,” in: W. Wunderlich (editor), Ceramic Materials, Tokai University, Tokyo (2010), pp. 49–67.

  9. J. Chao, M. Yachun, Z. Naiqing, and S. Kening, “Fabrication and characterization of Ni–ScZ gradient anodes/SSZ electrolyte for anode-supported SOFCs by tape casting and co-sintering technique,” Int. J. Hydr. Energy, 40, 8433–8441 (2015).

    Article  CAS  Google Scholar 

  10. M. Letilly, O. Joubert, M.-T. Caldes, and A. Le Gal La Salle, “Tape casting fabrication, co-sintering and optimization of anode/electrolyte assemblies for SOFC based on BIT07-Ni/BIT07,” Int. J. Hydr. Energy, 37, 4346–4355 (2012).

    Article  CAS  Google Scholar 

  11. I. Polishko, S. Ivanchenko, R. Horda, Y. Brodnikovskyi, N. Lysunenko, and L. Kovalenko, “Tape casted SOFC based on Ukrainian 8YSZ powder,” Materials Today: Proceed., 6, 237–241 (2019).

    CAS  Google Scholar 

  12. GOST 2409–2014. Refractory Materials. Method for the Determination of the Apparent Density, Open and Total Porosities, and Water Absorption [in Russian], Standartinform, Moscow (2014).

  13. L. J. Van der Pauw, “A method of measuring specific resistivity and Hall effect of discs of arbitrary shape,” Philips Res. Reports, 13, 1–9 (1958).

    Google Scholar 

  14. V. Podhurska, B. Vasyliv, O. Ostash, Y. Brodnikovskyi, and O. Vasylyev, “Influence of treatment temperature on microstructure and properties of YSZ–NiO anode materials,” Nanoscale Res. Lett., 11, 93 (2016); DOI: https://doi.org/10.1186/s11671-016-1306-z.

    Article  CAS  Google Scholar 

  15. R. M. C. Clemmer and S. F. Corbin, “The influence of pore and Ni morphology on the electrical conductivity of porous Ni/YSZ composite anodes for use in solid oxide fuel cell applications,” Solid State Ionics, 180, 721–730 (2009).

    Article  CAS  Google Scholar 

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Correspondence to O. P. Ostash.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 56, No. 1, pp. 21–26, January–February, 2020.

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Vasyliv, B.D., Podhurska, V.Y., Ostash, O.P. et al. Influence of the Working Media of Fuel Cells on the Structure and Physicomechanical Characteristics of Ceramics of the ZrO2–Y2O3–NiO System. Mater Sci 56, 15–21 (2020). https://doi.org/10.1007/s11003-020-00391-4

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  • DOI: https://doi.org/10.1007/s11003-020-00391-4

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