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Synthesis and Crystal Structure of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and (1,1'-Biphenyl)-2,2'-dicarboxylate Ligands

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Abstract

Zinc coordination polymer with V-shaped ligands, {[Zn(L1) ⋅ (bpda)] ⋅ H2O}n, (1) (L1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H2bpda = (1,1'-biphenyl)-2,2'-dicarboxylic acid) was synthesized under solvothermal condition. The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by infrared spectra and elemental analyses. In 1, the Zn(II) ion is four-coordinated by two nitrogen atoms of two distinct L1 ligands and two oxygen atoms of two bpda2– to form a distorted tetrahedron. Complex 1 displays a 2D four-connected framework with a (65 × 8) topology along c direction.

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Funding

This work was financially supported by the Natural Science Foundation of Jiangsu Province of China (BK20171404), Shan Dong Industrial Tecchnology Research Institute (Y95P021P05), the Priority Academic Program of Applied Chemistry (XK-2019057), and Applied Research Projects of Yuncheng University (CY-2018019).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, P. R. China

    G.-F. Wang

  2. Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, 215163, Suzhou, China

    Y.-Z. Liu

  3. Jinan Guoke Medical Technology Development Co.Ltd., 250100, Jinan, China

    Y.-Z. Liu

Authors
  1. G.-F. Wang
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  2. Y.-Z. Liu
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Correspondence to G.-F. Wang or Y.-Z. Liu.

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Wang, GF., Liu, YZ. Synthesis and Crystal Structure of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and (1,1'-Biphenyl)-2,2'-dicarboxylate Ligands. Crystallogr. Rep. 65, 871–874 (2020). https://doi.org/10.1134/S1063774520060371

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  • DOI: https://doi.org/10.1134/S1063774520060371

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