Skip to main content
Log in

Effect of the Variation of Film Thickness on the Properties of Multilayered Si-Doped Diamond-Like Carbon Films Deposited on SUS 304, Al and Cu Substrates

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

Multilayered Si-doped DLC film with thicknesses of 5.5, 10.1, 21.8 and 28.3 μm was deposited on stainless steel, aluminum alloy and copper alloy substrates by plasma-enhanced chemical vapor deposition. The mechanical and tribological properties of multilayered Si-doped DLC films deposited on three different substrates were evaluated in this study. The hardness of the multilayered Si-doped DLC film of different substrates is related to the substrate material and internal stress. In a scratch test, the adhesion of the multilayered Si-doped DLC film increased with the film thickness. The multilayered Si-doped DLC film with a thickness of 28.3 μm on stainless steel substrate has the highest adhesion of 31 N. The adhesion of the multilayered Si-doped DLC film with different thicknesses on the copper alloy is relatively poor. The ball-on-disk friction test results show that the multilayered Si-doped DLC film with thicknesses of 5.5 and 10.1 μm is prone to shear deformation and exhibit high friction coefficient. The uneven stress distribution and surface deformation of the multilayered Si-doped film deposited on the aluminum alloy and the copper alloy cause the fluctuation and rise of the friction coefficient. The wear resistance of multilayered Si-doped DLC films on different substrates is related to stress shielding and adhesion strength.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

References

  1. H. Maruno and A. Nishimoto, Adhesion and Durability of Multi-interlayered Diamond-like Carbon Films Deposited on Aluminum Alloy, Surf. Coat. Tech., 2018, 354, p 134–144.

    CAS  Google Scholar 

  2. S.D.A. Lawes, M.E. Fitzpatrick, and S.V. Hainsworth, Evaluation of the Tribological Properties of DLC for Engine Applications, J. Phys. D Appl Phys, 2007, 40, p 5427–5437.

    CAS  Google Scholar 

  3. S.R. Polaki, N. Kumar, N.G. Krishna, K. Madapu, M. Kamruddin, S. Dash, and A.K. Tyagi, Microwave Plasma Induced Surface Modification of Diamond-Like Carbon Films, Surf. Topogr. Metrol. Prop., 2017, 5, p 045005.

    Google Scholar 

  4. J. Robertson, Diamond-like Amorphous Carbon, Mat. Sci. Eng. R, 2002, 37, p 129–281.

    Google Scholar 

  5. M. Goto, Preparations and Tribological Properties of Soft-metal/DLC Composite Coatings by RF Magnetron Sputter Using Composite Targets, Int. J. Mech. Mater. Des., 2017, 14, p 313–327.

    Google Scholar 

  6. B.C. Yeldose and B. Ramamoorthy, Characterization of DC Magnetron Sputtered Diamond-Like Carbon (DLC) Nano Coating, Int. J. Adv. Manuf. Technol., 2007, 38, p 705–717.

    Google Scholar 

  7. S. Grigoriev, M. Volosova, S. Fyodorov, M. Lyakhovetskiy, and A. Seleznev, DLC-coating Application to Improve the Durability of Ceramic Tools, J. Mater. Eng. Perform., 2019, 28, p 4415–4426.

    CAS  Google Scholar 

  8. Y. Sun, X.Y. Huang, and H. Wang, Influence of Hydrogen Content on Optical and Mechanical Performances of Diamond-Like Carbon Films on Glass Substrate, J. Mater. Eng. Perform., 2016, 25, p 1570–1577.

    CAS  Google Scholar 

  9. M. Odén, J. Almer, and G. Håkansson, The Effects of Bias Voltage and Annealing on the Microstructure and Residual Stress of Arc-Evaporated Cr-N Coatings, Surf. Coat. Tech., 1999, 120–121, p 272–276.

    Google Scholar 

  10. A. Leyland and A. Matthews, Thick TiTiN Multilayered Coatings for Abrasive and Erosive Wear Resistance, Surf. Coat. Tech., 1994, 70, p 19–25.

    CAS  Google Scholar 

  11. Y. Ye, S. Jia, D. Zhang, W. Liu, and H. Zhao, A Study for Anticorrosion and Tribological Behaviors of Thin/Thick Diamond-Like Carbon Films in Seawater, Surf. Topogr. Metrol. Prop., 2018, 6, p 014004.

    Google Scholar 

  12. Q. Wei, A.K. Sharma, J. Sankar, and J. Narayan, Mechanical Properties of Diamond-Like Carbon Composite Thin Films Prepared by Pulsed Laser Deposition, Compos. Part B, 1999, 30, p 675–684.

    Google Scholar 

  13. S. Logothetidis, M. Gioti, C. Charitidis, P. Patsalas, J. Arvanitidis, and J. Stoemenos, Stability, Enhancement of Elastic Properties and Structure of Multilayered Amorphous Carbon Films, Appl. Surf. Sci., 1999, 138–139, p 244–249.

    Google Scholar 

  14. P. Wang, X. Wang, T. Xu, W.M. Liu, and J. Zhang, Comparing Internal Stress in Diamond-Like Carbon Films with Different Structure, Thin Solid Films, 2007, 515, p 6899–6903.

    CAS  Google Scholar 

  15. S. Neuville and A. Matthews, A Perspective on the Optimisation of Hard Carbon and Related Coatings for Engineering Applications, Thin Solid Films, 2007, 515, p 6619–6653.

    CAS  Google Scholar 

  16. A. Leyland and A. Matthews, On the Significance of the H-E Ratio in Wear Control: A Nanocomposite Coating Approach to Optimised Tribological Behavior, Wear, 2000, 246, p 1–11.

    CAS  Google Scholar 

  17. L.L. Liu, Z.Z. Wu, X.K. An, S. Xiao, S.H. Cui, H. Lin, R.K.Y. Fu, X.B. Tian, R.H. Wei, P.K. Chu, and F. Pan, Excellent Adhered Thick Diamond-Like Carbon Coatings by Optimizing Hetero-Interfaces with Sequential Highly Energetic Cr and C Ion Treatment, J. Alloy. Compd., 2018, 735, p 155–162.

    CAS  Google Scholar 

  18. J. Sun, Z. Fu, W. Zhang, C. Wang, W. Yue, S. Lin, and M. Dai, Friction and Wear of Cr-Doped DLC Films Under Different Lubrication Conditions, Vacuum, 2013, 94, p 1–5.

    CAS  Google Scholar 

  19. E.D. Rejowski, M.C.L. de Oliveira, R.A. Antunes, and M.F. Pillis, Structural Characterization and Corrosion Stability of a Si-Doped DLC Coating Applied on Cylinder Liner, J. Mater. Eng. Perform., 2014, 23, p 3926–3933.

    CAS  Google Scholar 

  20. S. Viswanathan, L. Mohan, P. Bera, V.P. Kumar, H.C. Barshilia, and C. Anandan, Corrosion and Wear Behaviors of Cr-Doped Diamond-Like Carbon Coatings, J. Mater. Eng. Perform., 2017, 26, p 3633–3647.

    CAS  Google Scholar 

  21. E.Z. Carvalho, B.J. Kooi, and JTh.M. De Hosson, Stress Analysis and Microstructure of PVD Monolayer TiN and Multilayer TiN/(Ti, Al)N Coatings, Thin Solid Films, 2003, 429, p 179–189.

    CAS  Google Scholar 

  22. M. Lorenz, V. Lazenka, P. Schwinkendorf, F. Bern, M. Ziese, H. Modarresi, and A. Volodin, Multiferroic BaTiO3–BiFeO3 Composite Thin Films and Multilayers: Strain Engineering and Magnetoelectric Coupling, J. Phys. D Appl Phys, 2014, 47, p 135303.

    Google Scholar 

  23. Y.Q. Wei, X.Y. Zong, Z.Q. Jiang, and X.B. Tian, Characterization and Mechanical Properties of TiN/TiAlN Multilayer Coatings with Different Modulation Periods, Int. J. Adv. Manuf. Technol., 2017, 96, p 1677–1683.

    Google Scholar 

  24. T. Takeshita, Y. Kurata, and S. Hasegawa, Bonding Properties of Glow-Discharge Polycrystalline and Amorphous Si-C Films Studied by X-Ray Diffraction and X-Ray Photoelectron Spectroscopy, J. Appl. Phys., 1992, 71, p 5395–5400.

    CAS  Google Scholar 

  25. T.F. Zhang, Z.X. Wan, J.C. Ding, S.H. Zhang, Q.M. Wang, and K.H. Kim, Microstructure and High-Temperature Tribological Properties of Si-Doped Hydrogenated Diamond-like Carbon Films, Appl. Surf. Sci., 2018, 435, p 963–973.

    CAS  Google Scholar 

  26. M.J. Cui, J.B. Pu, J. Liang, L.P. Wang, G.A. Zhang, and Q.J. Xue, Corrosion and Tribocorrosion Performance of Multilayer Diamond-Like Carbon Film in NaCl Solution, RSC Adv., 2015, 5, p 104829–104840.

    CAS  Google Scholar 

  27. J.J. Wang, J.B. Pu, G.A. Zhang, and L.P. Wang, Interface Architecture for Superthick Carbon-Based Films Toward Low Internal Stress and Ultrahigh Load-Bearing Capacity, ACS Appl. Mater. Interface, 2013, 5, p 5015–5024.

    CAS  Google Scholar 

  28. D. César, R. Tello, E. Broitman, F.J. Flores-Ruiz, O. Jiménez, and M. Flores, Mechanical Properties and Tribological Behavior at Micro and Macro-Scale of WC/WCN/W Hierarchical Multilayer Coatings, Tribol. Int., 2016, 101, p 194–203.

    Google Scholar 

  29. J.J. Wang, J.B. Pu, G.A. Zhang, and L.P. Wang, Tailoring the Structure and Property of Silicon-Doped Diamond-Like Carbon Films by Controlling the Silicon Content, Surf. Coat. Tech., 2013, 235, p 326–332.

    CAS  Google Scholar 

  30. J.B. Pu, J.J. Wang, D.Q. He, and S. Wan, Corrosion and Tribocorrosion Behaviour of Super-Thick Diamond-Like Carbon Films Deposited on Stainless Steel in NaCl Solution, Surf. Interface Anal., 2016, 48, p 360–367.

    CAS  Google Scholar 

  31. Y.Y. Lin, Z.F. Zhou, and K.Y. Li, Improved Wear Resistance at High Contact Stresses of Hydrogen-Free Diamond-Like Carbon Coatings by Carbon/Carbon Multilayer Architecture, Appl. Surf. Sci., 2017, 477, p 137–146.

    Google Scholar 

  32. A. Modabberasl, P. Kameli, M. Ranjbar, H. Salamati, and R. Ashiri, Fabrication of DLC Thin Films with Improved Diamond-Like Carbon Character by the Application of External Magnetic Field, Carbon, 2015, 94, p 485–493.

    CAS  Google Scholar 

  33. A.C. Ferrari and J. Robertson, Interpretation of Raman Spectra of Disordered and Amorphous Carbon, Phys. Rev. B, 2000, 61, p 14095.

    CAS  Google Scholar 

  34. R. Paul, S.N. Das, S. Dalui, R.N. Gayen, R.K. Roy, R. Bhar, and A.K. Pal, Synthesis of DLC Films with Different sp2/Sp3ratios and Their Hydrophobic Behaviour, J. Phys. D Appl Phys, 2008, 41, p 055309.

    Google Scholar 

  35. R. Cruz, J. Rao, T. Rose, K. Lawson, and J.R. Nicholls, DLC–Ceramic Multilayers for Automotive Applications, Diam. Relat. Mater., 2006, 15, p 2055–2060.

    CAS  Google Scholar 

  36. Z. Li, Y. Wang, X. Cheng, Z. Zeng, J. Li, X. Lu, L. Wang, and Q. Xue, Continuously Growing Ultrathick CrN Coating to Achieve High Load-Bearing Capacity and Good Tribological Property, ACS Appl, Mater. Interface., 2018, 10, p 2965–2975.

    CAS  Google Scholar 

  37. J. Musil and M. Jirout, Toughness of Hard Nanostructured Ceramic Thin Films, Surf. Coat. Tech., 2007, 201, p 5148–5152.

    CAS  Google Scholar 

  38. N. Konkhunthot, P. Photongkam, and P. Wongpanya, Improvement of Thermal Stability, Adhesion Strength and Corrosion Performance of Diamond-like Carbon Films with Titanium Doping, Appl. Surf. Sci., 2019, 469, p 471–486.

    CAS  Google Scholar 

  39. X.Z. Ding, B.K. Tay, S.P. Lau, P. Zhang, and X.T. Zeng, Structural and Mechanical Properties of Ti-Containing Diamond-Like Carbon Films Deposited by Filtered Cathodic Vacuum Arc, Thin Solid Films, 2002, 408, p 183–187.

    CAS  Google Scholar 

  40. J. Zhang, X. Yu, X.A. Zhao, and L. Zhang, Influences of Interfacial Carbonization on the Structure and Mechanical Properties of Multilayered Cr-Containing Diamond-Like Carbon Films, J. Phys. Chem. C, 2017, 121, p 6781–6787.

    CAS  Google Scholar 

  41. J.J. Wang, J.B. Pu, G.A. Zhang, and L.P. Wang, Architecture of Superthick Diamond-Like Carbon Films with Excellent High Temperature Wear Resistance, Tribol. Int., 2015, 81, p 129–138.

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by National Key R&D Program of China (No. 2018YFB0703801) and the National Natural Science Foundation of China (Nos. 51775535, 11972344).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yunfeng Wang or Guangan Zhang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, A., Chen, Q., Wu, G. et al. Effect of the Variation of Film Thickness on the Properties of Multilayered Si-Doped Diamond-Like Carbon Films Deposited on SUS 304, Al and Cu Substrates. J. of Materi Eng and Perform 29, 8473–8483 (2020). https://doi.org/10.1007/s11665-020-05310-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-020-05310-x

Keywords

Navigation