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Evidence for superhydrous primitive arc magmas from mafic enclaves at Shiveluch volcano, Kamchatka

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Abstract

Mafic enclaves preserve a record of deep differentiation of primitive magmas in arc settings. We analyze the petrology and geochemistry of mafic enclaves from Shiveluch volcano in the Kamchatka peninsula to determine the differentiation histories of primitive magmas and to estimate their pressures, temperatures, and water contents. Amphibole inclusions in high forsterite olivine suggest that the primitive melt was superhydrous (i.e., > 8 wt% H2O) and was fractionating amphibole and olivine early on its liquid line of descent. We find that the hydrous primitive melt had liquidus temperatures of 1062 ± 48 °C and crystallized high Mg# amphibole at depths of 23.6–28.8 km and water contents of 10–14 wt% H2O. The major and trace element whole-rock chemistry of enclaves and of published analyses of andesites suggest that they are related through fractionation of amphibole-bearing assemblages. Quantitative models fractionating olivine, clinopyroxene, and amphibole reproduce geochemical trends defined by enclaves and andesites in variation diagrams. These models estimate 0.2–12.2% amphibole fractionated from the melt to reproduce the full range of enclave compositions, which overlaps with estimates of the amount of amphibole fractionated from parental melts based on whole-rock dysprosium contents. This contribution extends the published model of shallow processes at Shiveluch to greater depths. It provides evidence that primitive magmas feeding arc volcanoes may be more hydrous than estimated from other methods, and that amphibole is an important early fractionating phase on the liquid line of descent of superhydrous, primitive mantle-derived melts.

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Code availability

Matlab codes used for quantitative fractionation modeling and compositional correction of enclaves is available on request.

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Acknowledgements

The authors acknowledge support from Washington University in Saint Louis for funding field and lab work associated with this project. AEG and MG acknowledge the McDonnell Center for the Space Sciences for funding. PR acknowledges support from National Science Foundation EAR Grants #1426820 and #1719687. Fieldwork for NVG was supported by Grant #15-05-06440 from the Russian Foundation for Basic Research. MJK acknowledges support from National Science Foundation EAR Grant #1654683. We thank Paul Carpenter for help with electron probe microanalysis. This manuscript benefitted from helpful conversations with Rita Parai, Doug Wiens, David Fike, and Kelsey Prissel. M. Portnyagin and P. Ulmer are thanked for their helpful reviews of this manuscript, and O. Müntener is thanked for editorial handling and review.

Funding

Funding from Washington University in Saint Louis is acknowledged for completion of this project. AEG and MG also acknowledge the McDonnell Center for Space Sciences for funding. MJK acknowledges support from NSF EAR Grant #1654683. Fieldwork for NVG was supported by Grant #15-05-06440 from the Russian Foundation for Basic Research. PR acknowledges support from NSF EAR Grants #1426820 and #1719687.

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Authors and Affiliations

  1. Department of Earth and Planetary Sciences, Washington University in St. Louis, St. Louis, MO, USA

    Andrea E. Goltz, Michael J. Krawczynski & Maxim Gavrilenko

  2. Department of Geological Sciences and Engineering, University of Nevada, Reno, Reno, NV, USA

    Maxim Gavrilenko & Philipp Ruprecht

  3. Skolkovo Institute of Science and Technology, Moscow, Russia

    Maxim Gavrilenko

  4. Vernadsky Institute of Geochemistry and Analytical Chemistry, Moscow, Russia

    Maxim Gavrilenko

  5. Institute of Volcanology and Seismology, Russian Acadamy of Science, Petropavlovsk-Kamchatsky, Russia

    Natalia V. Gorbach

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  1. Andrea E. Goltz
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  2. Michael J. Krawczynski
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  3. Maxim Gavrilenko
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  4. Natalia V. Gorbach
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  5. Philipp Ruprecht
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Correspondence to Andrea E. Goltz.

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Communicated by Othmar Müntener.

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Goltz, A.E., Krawczynski, M.J., Gavrilenko, M. et al. Evidence for superhydrous primitive arc magmas from mafic enclaves at Shiveluch volcano, Kamchatka. Contrib Mineral Petrol 175, 115 (2020). https://doi.org/10.1007/s00410-020-01746-5

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