Skip to main content
SpringerLink
Log in

Phase Equilibria in BaS–In2S3 System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

A confined region of solid solution exists in BaS−In2S3 system of eutectic type with incongruent melting compounds of BaIn2S4 and Ba2In2S5 composition based on the α modification of In2S3. Compounds BaIn2S4 and Ba2In2S5 melt incongruently at 1330 and 1497 K, crystallize in rhombic syngony with unit cell parameters а = 2.181 nm, b = 2.165 nm, с = 1.311 nm (space group Fddd) and а = 1.317 nm, b = 1.272 nm, с = 1.178 nm (space group Pbca), respectively. Microhardness H = 2470 MPa for BaIn2S4 and 2250 MPa for Ba2In2S5. Coordinates of BaIn2S4–In2S3 eutectics is 76 mol % In2S3, Tm = 1190 K. Solubility of BaS in α-In2S3 at 1070 K reaches 2 mol % BaS. Solubility of BaS in α-In2S3 decreases with temperature and becomes 1 mol % BaS at 870 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. K. J. Hong, T. S. Jeong, and C. J. Youn, J. Cryst. Growth 433, 13 (2016). https://doi.org/10.1016/j.jcrysgro.2015.09.027

    Article  CAS  Google Scholar 

  2. N. A. Moldovyan, Inorg. Mater. 23, 670 (1992).

    Google Scholar 

  3. A. V. Kertman, Russ. J. Inorg. Chem. 62, 1240 (2017). https://doi.org/10.1134/S003602361709008X

    Article  CAS  Google Scholar 

  4. A. V. Kertman, I. I. Nosov, and O. V. Andreev, Russ. J. Inorg. Chem. 47, 126 (2002).

    Google Scholar 

  5. A. V. Kertman Russ. J. Inorg. Chem. 64, 130 (2019). https://doi.org/10.1134/S0036023619010133

    Article  CAS  Google Scholar 

  6. C. Hidaka, M. Goto, M. Kubo, and T. Takizawa, J. Cryst. Growth 275, e439 (2005). https://doi.org/10.1016/j.jcrysgro.2004.11.016

    Article  CAS  Google Scholar 

  7. Y. Chi, Sh.-P. Guo, and H.-G. Xue, RSC Adv. 7, 5039 (2017). https://doi.org/10.1039/c6ra25283d

  8. B. Eisenmann and A. Hofmann, Z. Anorg. Allg. Chem. 580, 151 (1990).

    Article  CAS  Google Scholar 

  9. W. Gao, K. Wu, K. Lai, et al., Z. Anorg. Allg. Chem. 641, 1329 (2015). https://doi.org/10.1002/zaac.201500113

    Article  CAS  Google Scholar 

  10. A. V. Kertman and N. V. Shal’neva, Russ. J. Inorg. Chem. 61, 109 (2016). https://doi.org/10.1134/S0036023616010101

    Article  CAS  Google Scholar 

  11. M. X. Stubbs, Y. A. Schule, A. Y. Tornpson, et al., J. Am. Chem. Soc. 74, 1441 (1952).

    Article  CAS  Google Scholar 

  12. Z. S. Medvedeva, Chalcogenides of Subgroup III B Elements of the Periodic System (Nauka, Moscow, 1968) [in Russian].

    Google Scholar 

  13. G. A. Steigmann, H. H. Sutherland, and J. Goodyear, Acta Crystallogr. 19, 967 (1965).

    Article  CAS  Google Scholar 

  14. A. V. Naumov, A. V. Sergeeva, and V.N. Semenov, Inorg. Mater. 53, 560 (2017). https://doi.org/10.1134/S0020168517060127

    Article  CAS  Google Scholar 

  15. A. V. Kosyakov, A. Yu. Zavrazhnov, and A. V. Naumov, Inorg. Mater. 46, 343 (2010).

    Article  CAS  Google Scholar 

  16. A. V. Naumov, A. V. Sergeeva, and V. N. Semenov, Inorg. Mater. 51, 1205 (2015). https://doi.org/10.1134/S0020168515110060

    Article  CAS  Google Scholar 

  17. A. Yu. Zavrazhnov, A. V. Naumov, P. V. Anorov, et al., Inorg. Mater. 42, 1294 (2006).

    Article  CAS  Google Scholar 

  18. A. V. Kosyakov, A. Yu. Zavrazhnov, A. V. Naumov, and A. V. Sergeeva, Vestnik VGU. Seriya: Khimiya, Biologiya, Farmatsiya, No. 2, 28 (2009).

    Google Scholar 

  19. P. Pistor, J. M. Merino Alvarez, M. Leon, et al., Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 72, 410 (2016). https://doi.org/10.1107/S2052520616007058

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  20. T. Li, S. Zhang, S. Meng, et al., Royal Soc. Chem. 7, 6457 (2017). https://doi.org/10.1039/c6ra28560k

    Article  CAS  Google Scholar 

  21. P. E. Rodrigues-Hernandez, K. E. Nieto-Zepeda, A. Guillen-Cervantes, et al., Chalcogenide Letters 14, 331 (2017).

    Google Scholar 

  22. K. Jeong and K. Hong, J. Korean Cryst. Growth Cryst. Technol. 25, 183 (2015). https://doi.org/10.6111/JKCGCT.2015.25.5.173

    Article  Google Scholar 

  23. R. D. Shannon, Acta Crystallogr. A 32, 751 (1976).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tyumen State University, 625003, Tyumen, Russia

    A. V. Kertman & A. V. Ruseikina

Authors
  1. A. V. Kertman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Ruseikina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Kertman.

Ethics declarations

The authors declare no conflict of interest.

Additional information

Translated by I. Kudryavtsev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kertman, A.V., Ruseikina, A.V. Phase Equilibria in BaS–In2S3 System. Russ. J. Inorg. Chem. 65, 1756–1761 (2020). https://doi.org/10.1134/S003602362011008X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602362011008X

Keywords:

Search

Navigation