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Physicochemical Analysis of the FeSe–Ga2Se3–In2Se3 System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

Phase equilibria in the FeSe–Ga2Se3–In2Se3 system were studied by differential thermal analysis and X-ray powder diffraction analysis. A number of polythermal sections, the isothermal section at 1000 K, and the projection of the liquidus surface of the phase diagram were constructed. It was determined that this system is quasi-ternary, and that the liquidus surface comprises the fields of primary crystallization of six phases. The types and coordinates of invariant and monovariant equilibria were found. Wide regions of solid solutions based on binary and ternary compounds (FeGa2Se4, FeIn2Se4) were revealed, being of interest as magnetic materials.

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Funding

This work was performed within the framework of the scientific program of the International Laboratory of Promising Materials for Spintronics and Quantum Computing, which was established based on the Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan, and the Donostia International Physics Center, Donostia–San Sebastián, Gipuzkoa, Spain. This work was supported in part by the Science Development Foundation under the President of the Republic of Azerbaijan (grant no. EİF/MQM/Elm-Tehsil-1-2016-1(26)-71/01/4-M-33).

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Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, AZ-1143, Baku, Azerbaijan

    F. M. Mamedov, D. M. Babanly, D. B. Tagiev & M. B. Babanly

  2. Azerbaijan State University of Oil and Industry, AZ-1010, Baku, Azerbaijan

    D. M. Babanly

  3. Institute of Physics, National Academy of Sciences of Azerbaijan, AZ-1143, Baku, Azerbaijan

    I. R. Amiraslanov

  4. Baku State University, AZ-1148, Baku, Azerbaijan

    M. B. Babanly

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  1. F. M. Mamedov
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Correspondence to F. M. Mamedov.

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Translated by V. Glyanchenko

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Mamedov, F.M., Babanly, D.M., Amiraslanov, I.R. et al. Physicochemical Analysis of the FeSe–Ga2Se3–In2Se3 System. Russ. J. Inorg. Chem. 65, 1747–1755 (2020). https://doi.org/10.1134/S0036023620110121

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