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Synthesis, Molecular, and Crystal Structure of Tris(2-carbamoylmethoxyphenyl)phosphine Oxide

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Abstract

New tripodal ligand, tris(2-carbamoylmethoxyphenyl)phosphine oxide, has been synthesized via the alkylation of tris(2-hydroxyphenyl)phosphine oxide with chloroacetamide. The ligand structure has been studied by means of IR and NMR (1H, 31P) spectroscopy as well as X-ray diffraction.

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Funding

This study was financially supported by the Russian Science Foundation (project no. 20-13-00329). Spectral experiments were performed using the equipment of the Center for Molecular Structure Studies, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences. Elemental analysis was performed in the Laboratory of Microanalysis, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.

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Correspondence to I. Yu. Kudryavtsev.

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Baulina, T.V., Kudryavtsev, I.Y., Artem’ev, A.V. et al. Synthesis, Molecular, and Crystal Structure of Tris(2-carbamoylmethoxyphenyl)phosphine Oxide. Russ J Gen Chem 90, 1840–1844 (2020). https://doi.org/10.1134/S1070363220100059

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