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Tris(2-methoxy-5-chlorophenyl)antimony: Synthesis and Oxidative Addition Reactions

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Abstract

The reaction of 2-methoxy-5-chlorophenyllithium with SbCl3 (3 : 1) in diethyl ether has afforded tris(2-methoxy-5-chlorophenyl)antimony, which has been crystallized from benzene as solvate. Treatment of the solvate with bromine in chloroform has led to the formation of tris(2-methoxy-5-chlorophenyl)antimony dibromide, which has been isolated from benzene as solvate as well. The product of a similar reaction with chlorine, tris(2-methoxy-5-chlorophenyl)antimony dichloride, has been also obtained via oxidation of tris(2-methoxy-5-chlorophenyl)antimony with copper dichloride in acetone. The structural features of the obtained compounds have been established by means of single-crystal X-ray diffraction analysis.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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  1. V. V. Sharutin
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Sharutin, V.V., Sharutina, O.K. Tris(2-methoxy-5-chlorophenyl)antimony: Synthesis and Oxidative Addition Reactions. Russ J Gen Chem 90, 1901–1905 (2020). https://doi.org/10.1134/S1070363220100138

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  • DOI: https://doi.org/10.1134/S1070363220100138

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