Abstract
Based on a numerical experiment, it is proven that the Dubinin theory of micropore filling can be extended to adsorption equilibria at supercritical temperatures. The temperature dependences of the main parameters of the theory are refined.
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REFERENCES
Dubinin, M.M., in Progress in Surface and Membrane Science, New York: Academic Press, 1975, vol. 9, p. 1.
Fomenkov, P.E., Gumerov, M.R., and Tolmachev, A.M., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, no. 4, p. 565.
Tolmachev, A.M., Kuznetsova, T.A., Kruchenkov, N.G., and Fomenkov, P.E., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 4, p. 487.
Tolmachev, A.M., Godovikov, I.A., and Kuznetsova, T.A., Prot. Met. Phys. Chem. Surf., 2012, vol. 48, no. 2, p. 165.
Tolmachev, A.M., Firsov, D.A., Kryuchenkova, N.G., and Kuznetsova, T.A., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, no. 3, p. 420.
Tolmachev, A.M., Langmuir, 1991, no. 7, p. 1400.
Nikolaev, K.M. and Dubinin, M.M., Izv. Akad. Nauk SSSR,Otd. Khim. Nauk, 1958, vol. 7, no. 10, p. 65.
Tolmachev, A.M., Godovikov, I.A., Kuznetsova, T.A., Kryuchenkova, N.G., and Firsov, D.A. http://www. adsbank.chem.msu.ru.
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In memory of Academician M.M. Dubinin
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Tolmachev, A.M., Kuznetsova, T.A., Fomenkov, P.E. et al. The Theory of Volume Filling Micropores at Temperatures above Those Critical for Absorbances. Prot Met Phys Chem Surf 56, 879–881 (2020). https://doi.org/10.1134/S2070205120050251
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DOI: https://doi.org/10.1134/S2070205120050251