Abstract
In this study, a mixture of 93% Ni–7% Mg and 97% Ni–3% Mg powders were produced by the TM method and the diffusion kinetics, surface properties of borided nickel–magnesium alloy at different temperatures and times were investigated. The samples were sintered at 530°C. The boriding process was performed Ekabor II boron powder in atmospheric furnace environment at 900, 950 and 1000°C temperatures for 1.5, 3.0 and 4.5 h. The phases in the boride layer were found by means of CuKα radiation in XRD. XRD analysis of NiB, Ni2B and Ni3B phases were obtained. The hardness of borides layer formed on surface after boriding of the 93% Ni–7% Mg and 97% Ni–3% Mg alloys substrate ranged from 1518 to 1964 HV0.05, whereas value of the unborided nickel was 112–136 HV0.05. The boron activation energy was estimated as equal to 136.506 and 158.843 kJ/mol for the borided 93% Ni–7% Mg and 97% Ni–3% Mg alloys, respectively.
Similar content being viewed by others
REFERENCES
Oztürk, F. and Kaçar, I., Nigde Univ.J. Eng. Sci., 2012, vol. 1, pp. 12–20.
Zhu, S.M., Mordike, B.L., and Nie, J.F., Mater. Sci. Eng., A, 2006, vols. 483–484, pp. 583–586.
Kazeem, O.S. and Esther, T.A., Mater. Today: Proc., 2018, vol. 5, pp. 18468–18474.
Duygulu, O., Kaya, R.A., Oktay, G., and Kaya, A.A., Mater. Sci. Forum, 2007, vols. 546–549, pp. 421–424.
Hazeli, K., Askari, H., Cuadra, J., Streller, F., Carpick, R.W., Zbib, H.M., and Kontsos, A., Int. J. Plast., 2015, vol. 68, pp. 55–76.
Sathish, S., Anandakrishnan, V., and Manoj, G., Mater. Today, 2019 (in press). Sathish, S., Anandakrishnan, V., and Manoj, G., Mater. Today: Proc., 2020, vol. 21, pp. 492–496.
Hu, R., Su, Y., and Liu, H., J. Alloys Compd., 2016, vol. 658, pp. 555–560.
Shao, Z., Cai, Z., Hu, R., and Wei, S., Surf. Coat. Technol., 2014, vol. 249, pp. 42–47.
Majumdar, J.D. and Manna, I., Scr. Mater., 2010, vol. 62, pp. 579–581.
Keddam, M. and Kulka, M., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, pp. 282–290.
Kulka, M., Makuch, N., and Pertek, A., Opt. Laser Technol., 2013, vol. 45, pp. 308–318.
Vitry, V. and Bonin, L., Surf. Coat. Technol., 2017, vol. 311, pp. 166–171.
Yapici, A., Aydin, S.E., Koc, V., Kanca, E., and Yildiz, M., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, pp. 341–351.
Vitry, V., Kanta, A.F., and Delaunois, F., Surf. Coat. Technol., 2011, vol. 206, pp. 1879–1885.
Gunes, I., Keddam, M., Chegroune, R., and Ozcatal, M., Bull. Mater. Sci., 2015, vol. 38, no. 4, pp. 1113–1118.
Gunes, I., J. Mater. Sci. Technol., 2013, vol. 29, pp. 662–668.
He, X., Xiao, H., Ozaydin, M.F., Balzuweit, K., and Liang, H., Surf. Coat. Technol., 2015, vol. 263, pp. 21–26.
Gunes, I., Ulker, S., and Taktak, S., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, pp. 567–573.
Makuch, N. and Kulka, M., Appl. Surf. Sci., 2014, vol. 314, pp. 1007–1018.
Campos-Silva, I., Contla-Pacheco, A.D., Figueroa-López, U., Martínez-Trinidad, J., Garduño-Alva, A., and Ortega-Avilés, M., Surf. Coat. Technol., 2019, vol. 378, p. 124862.
Makuch, N., Kulka, M., Dziarski, P., and Taktak, S., Surf. Coat. Technol., 2019, vol. 367, pp. 187–202.
Kulka, M., Dziarski, P., Makuch, N., Piasecki, A., and Miklaszewski, A., Appl. Surf. Sci., 2013, vol. 284, pp. 757–771.
Dong, M., Bao-luo, S., Chao, Y., and Xin, Z., Vacuum, 2009, vol. 83, no. 12, pp. 1481–1484.
De-wei, D., Chun-guang, W., Qian-qian, L., and Ting-ting, N., Trans. Nonferrous Met. Soc. China, 2015, vol. 25, pp. 437−443.
Campos-Silva, I., Contla-Pacheco, A.D., Ruiz-Rios, A., Martínez-Trinidad, J., Rodríguez-Castro, G., Meneses-Amador, A., and Wong-Angel, W.D., Surf. Coat. Technol., 2018, vol. 349, pp. 917–927.
Calik, A., Ucar, N., Delikanli, K., Carkci, M., and Karakas, S., Indian J. Eng. Mater. Sci., 2017, vol. 24, no. 5, pp. 362–368.
Kahvecioglu, O., Sista, V., Eryilmaz, O.L., Erdemir, A., and Timur, S., Thin Solid Films, 2011, vol. 520, p. 1575.
Torun, O., Surf. Coat. Technol., 2008, vol. 202, no. 15, pp. 3549–3554.
Funding
This study was supported by Afyon Kocatepe University BAPK 17.MYO.05. Many thanks to the Scientific Research Projects Commission for their support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ismail Yildiz, Çelik, A.G. & Gunes, I. Characterization and Diffusion Kinetics of borided Ni–Mg Alloys. Prot Met Phys Chem Surf 56, 1015–1022 (2020). https://doi.org/10.1134/S2070205120050287
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205120050287