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m-Cresol Chemisorption on a Porous Iron-Containing Sorbent Prepared from the Carbon Residue after Lignin Processing: I. Pore Structure and Adsorption Ability of the Sorbent

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Abstract

The pore structure of the new adsorbent prepared from carbon-containing residues after catalytic carbon dioxide reforming of lignin of wood origin and the features of m-cresol chemisorption on this adsorbent were studied. The main step of the pore structure formation is treatment of the iron-containing carbon residue with carbon dioxide in a plasma catalytic mode, stimulated by microwave radiation. Iron-containing clusters were formed on the surface of the initial lignin and were used as a catalyst in the first step of its processing. The sorbent has a developed porous structure. The total pore volume is 0.65 cm3/g, with the micropore volume of 0.18 cm3/g and mesopore volume of 0.42 cm3/g. The adsorbent is characterized by unimodal distribution of adsorption pores with respect to effective radii with the diameter of 3.8 nm. The m-cresol adsorption dynamics was studied in situ by IR spectroscopy. The adsorption involves chemical transformation of cresol with the formation of Ph–O–C bonds between the phenyl ring of cresol and terminal (carbon or oxygen) atoms of the adsorbent.

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REFERENCES

  1. Kuznetsov, B.N., Chesnokov, N.V., Ivanov, I.P., Veprikova, E.V., and Ivanchenko, N.M., J. Sib. Fed. Univ., Chemistry, 2015, vol. 2, no. 8, pp. 232–255.

    Article  Google Scholar 

  2. Kuznetsov, B.N., Chesnokov, N.V., Ivanov, I.P., Veprikova, E.V., and Ivanchenko, N.M., Solid Fuel Chem., 2016, vol. 50, no. 1, pp. 23–30.

    Article  CAS  Google Scholar 

  3. Haq, I., Mazumder, P., and Kalamdhad, A.S., Bioresource Technol., 2020, pp. 123636–123647.

  4. Rabinovich, M.L., Fedoryak, O., Dobele, G., Andersone, A., Gawdzik, B., Lindström, M.E., and Sevastyanova, O., Renew. Sustain. Energy Rev., 2016, vol. 57, pp. 1008–1024.

    Article  CAS  Google Scholar 

  5. Ayyachamy, M., Cliffe, F.E., Coyne, J.M., Collier, J., and Tuohy, M.G., Biomass Conv. Bioref., 2013, no. 3, pp. 255–269.

    Article  Google Scholar 

  6. Suhas, S., Carrott, P.J.M., and Carrott, M.M.L.R., Bioresource Technol., 2007, vol. 98, pp. 2301–2312.

    Article  CAS  Google Scholar 

  7. Fu, K., Yue, Q., and Gao, B., Chem. Eng. J., 2013, vol. 228, no. 15, pp. 1074–1082.

    Article  CAS  Google Scholar 

  8. Jawaid, M., Tahir, P.M., and Saba, N., Lignocellulosic Fibre and Biomass-Based Composite Materials: Processing, Properties and Applications, Woodhead, 2017.

  9. Alkhatib, A.J. and Al Zailaey, K., Eur. Sci. J., 2015, vol. 11, no. 3, pp. 50–56.

    Google Scholar 

  10. Tsodikov, M.V., Nikolaev, S.A., Chistyakov, A.V., Bukhtenko, O.V., and Fomkin, A.A., Micropor. Mesopor. Mater., 2020, vol. 298, pp. 110089–110096.

    Article  CAS  Google Scholar 

  11. Tsodikov, M.V., Ellert, O.G., Nikolaev, S.A., Arapova, O.V., Bukhtenko, O.V., Maksimov, Yu.V., Kirdyankin, D.I., and Vasil’kov, A.Yu., J. Nanoparticle Res., 2018, vol. 20, no. 3, pp. 86–101.

    Article  Google Scholar 

  12. Hillebrand, W.F., Lundell, G.E.F., Bright, H.A. and Hoffman, J.I., Applied Inorganic Analysis, New York: Wiley, 1953, 2nd ed.

  13. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area and Porosity, London: Academic, 1982.

  14. Elliot, S., The Physics and Chemistry of Solids, New York: Wiley, 1998.

  15. Barrett, E.P., Joyner, L.G., and Halenda, P.P., J. Am. Chem. Soc., 1951, vol. 73, pp. 373–380.

    Article  CAS  Google Scholar 

  16. Dubinin, M.M. and Plavnik, G.M., Carbon, 1968, vol. 6, pp. 183–192.

    Article  CAS  Google Scholar 

  17. Feldman, L.C. and Mayer, J.W., Fundamentals of Surface and Thin Film Analysis, Amsterdam: Elsevier, 1986.

  18. Arapova, O.V., Bondarenko, G.N., Chistyakov, A.V., and Tsodikov, M.V., Russ. J. Phys. Chem. A, 2017, vol. 91, no. 9, pp. 1717–1729.

    Article  CAS  Google Scholar 

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Funding

The study was performed within the framework of government assignment for the Topchiev Institute of Petrochemical Synthesis, theme no. 47.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    G. N. Bondarenko, A. S. Kolbeshin, A. V. Chistyakov & M. V. Tsodikov

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    E. Yu. Liberman

  3. OOO Sorbis Group, 119361, Moscow, Russia

    V. I. Pasevin

Authors
  1. G. N. Bondarenko
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  2. A. S. Kolbeshin
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  3. E. Yu. Liberman
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  4. A. V. Chistyakov
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  5. V. I. Pasevin
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  6. M. V. Tsodikov
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Correspondence to M. V. Tsodikov.

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Bondarenko, G.N., Kolbeshin, A.S., Liberman, E.Y. et al. m-Cresol Chemisorption on a Porous Iron-Containing Sorbent Prepared from the Carbon Residue after Lignin Processing: I. Pore Structure and Adsorption Ability of the Sorbent. Pet. Chem. 61, 81–87 (2021). https://doi.org/10.1134/S0965544121010096

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  • DOI: https://doi.org/10.1134/S0965544121010096

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