Abstract
Ag2O/GO/TiO2 composite nanoparticles were synthesized via a two-stage route including wet chemical and sol-gel techniques. The phase regarding the composition and morphology of composite nanoparticles was characterized using X-ray diffraction (XRD), Fourier transfer infrared (FT-IR) spectroscopy, and field emission scanning electron microscopy (FESEM). The structural studies revealed the successful formation of 300-nm Ag2O/GO/TiO2 composite spheres self-assembled to 35-nm particle aggregates. UV-Vis diffuse reflectance spectroscopy (DRS) was utilized to investigate optical properties. The results indicated an absorption edge in the UV region with a band-gap equivalent to 3.2 eV for Ag2O/GO/TiO2 composite nanoparticles. The morphological features of the sample were investigated with a Zeiss (EM10C, Germany) transmission electron microscope (TEM) operating at 100 kV.
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Fujishima, A., Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature. 238, 37 (1972)
Subramanian, V., Wolf, E., Kamat, P.V.: Semiconductor- metal composite nanostructures. To what extent do metal nanoparticles improve the photocatalytic activity of TiO2 films? J. Phys. Chem. B. 105, 11439–11446 (2001)
S.U.M. Khan, M. Al-Shahry, W.B. Ingler, Efficient photochemical water splitting by a chemically modified n-TiO2, Science (80-. ). 297 (2002) 2243–2245
Yu, J.C., Yu, J., Ho, W., Jiang, Z., Zhang, L.: Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater. 14, 3808–3816 (2002)
R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, Y. Taga, Visible-light photocatalysis in nitrogen-doped titanium oxides, Science (80-. ). 293 (2001) 269–271
Sakthivel, S., Kisch, H.: Photocatalytic and photoelectrochemical properties of nitrogen-doped titanium dioxide. ChemPhysChem. 4, 487–490 (2003)
Burda, C., Lou, Y., Chen, X., Samia, A.C.S., Stout, J., Gole, J.L.: Enhanced nitrogen doping in TiO2 nanoparticles. Nano Lett. 3, 1049–1051 (2003)
Saleh, R., Taufik, A., Prakoso, S.P.: Fabrication of Ag2O/TiO2 composites on nanographene platelets for the removal of organic pollutants: influence of oxidants and inorganic anions. Appl Surf Sci. 480, 697–708 (2019)
Chenchana, A., Nemamcha, A., Moumeni, H., Rodríguez, J.M.D., Araña, J., Navío, J.A., Díaz, O.G., Melián, E.P.: Photodegradation of 2, 4-dichlorophenoxyacetic acid over TiO2 (B)/anatase nanobelts and Au-TiO2 (B)/anatase nanobelts. Appl Surf Sci. 467, 1076–1087 (2019)
Viana, M.M., Soares, V.F., Mohallem, N.D.S.: Synthesis, and characterization of TiO2 nanoparticles. Ceram Int. 36, 2047–2053 (2010)
Mathew, S., Kumar Prasad, A., Benoy, T., Rakesh, P.P., Hari, M., Libish, T.M., Radhakrishnan, P., Nampoori, V.P.N., Vallabhan, C.P.G.: UV-visible photoluminescence of TiO 2 nanoparticles prepared by hydrothermal method. J Fluoresc. 22, 1563–1569 (2012)
Guang, M., Xia, Y., Wang, D., Zeng, X.-F., Wang, J.-X., Chen, J.-F.: Controllable synthesis of transparent dispersions of monodisperse anatase-TiO2 nanoparticles and nanorods. Mater Chem Phys. 224, 100–106 (2019)
Nagaraj, G., Irudayaraj, A., Josephine, R.L.: Tuning the optical band gap of pure TiO2 via the photon-induced method. Optik (Stuttg). 179, 889–894 (2019)
Abisharani, J.M., Devikala, S., Kumar, R.D., Arthanareeswari, M., Kamaraj, P.: Green synthesis of TiO2 nanoparticles using Cucurbita pepo seeds extract. Mater Today Proc. 14, 302–307 (2019)
Abazovi, N.D., Omor, M.I., Anin, M.D.D., Jovanovi, D.J., Ahrenkiel, S.P., Nedeljkovi, J.M.: Photoluminescence of anatase and rutile TiO2 particles. J. Phys. Chem. B. 110, 25366–25370 (2006)
Ren, L., Li, Y., Mao, M., Lan, L., Lao, X., Zhao, X.: Significant improvement in photocatalytic activity by forming homojunction between anatase TiO2 nanosheets and anatase TiO2 nanoparticles. Appl Surf Sci. (2019)
Lv, K., Fang, S., Si, L., Xia, Y., Ho, W., Li, M.: Fabrication of TiO2 nanorod assembly grafted rGO (rGO@ TiO2-NR) hybridized flake-like photocatalyst. Appl Surf Sci. 391, 218–227 (2017)
Qiu, P., Sun, X., Lai, Y., Gao, P., Chen, C., Ge, L.: N-doped TiO2@ TiO2 visible light active film with stable and efficient photocathodic protection performance. J Electroanal Chem. 844, 91–98 (2019)
Sadanandam, G., Valluri, D.K., Scurrell, M.S.: Highly stabilized Ag2O-loaded nano TiO2 for hydrogen production from glycerol: water mixtures under solar light irradiation. Int J Hydrog Energy. 42, 807–820 (2017)
Yang, X., Wang, Y., Wang, Z., Lv, X., Jia, H., Kong, J., Yu, M.: Preparation of CdS/TiO2 nanotube arrays and the enhanced photocatalytic property. Ceram Int. 42, 7192–7202 (2016)
Bandara, J., Hadapangoda, C.C., Jayasekera, W.G.: TiO2/MgO composite photocatalyst: the role of MgO in photoinduced charge carrier separation. Appl Catal B Environ. 50, 83–88 (2004)
Toloman, D., Pana, O., Stefan, M., Popa, A., Leostean, C., Macavei, S., Silipas, D., Perhaita, I., Lazar, M.D., Barbu-Tudoran, L.: Photocatalytic activity of SnO 2 -TiO 2 composite nanoparticles modified with PVP. J Colloid Interface Sci. 542, 296–307 (2019). https://doi.org/10.1016/j.jcis.2019.02.026
Upadhyay, G.K., Rajput, J.K., Pathak, T.K., Kumar, V., Purohit, L.P.: Synthesis of ZnO: TiO2 nanocomposites for photocatalyst application in visible light. Vacuum. 160, 154–163 (2019)
Tahir, M.B., Farman, S., Rafique, M., Shakil, M., Khan, M.I., Ijaz, M., Mubeen, I., Ashraf, M., Nadeem Riaz, K.: Photocatalytic performance of hybrid WO3/TiO2 nanomaterials for the degradation of methylene blue under visible light irradiation. Int J Environ Anal Chem. 1–13 (2019)
El-Sayed, S.M., Amer, M.A., Meaz, T.M., Deghiedy, N.M., El-Shershaby, H.A.: Investigational analysis on irradiated MgO-TiO2 binary oxide. Mater Res Express. 5, 56508 (2018)
Varkey, A.J., Fort, A.F.: Some optical properties of silver peroxide (AgO) and silver oxide (Ag2O) films produced by chemical-bath deposition. Sol Energy Mater Sol Cells. 29, 253–259 (1993)
Kudryashov, D.A., Grushevskaya, S.N., Vvedenskii, A.V.: Determining some structure-sensitive characteristics of nano-sized anodic Ag (I) oxide from photopotential spectroscopy. Prot. Met. 43, 591–599 (2007)
Fang, F., Li, Q., Shang, J.K.: Enhanced visible-light absorption from Ag2O nanoparticles in nitrogen-doped TiO2 thin films. Surf Coatings Technol. 205, 2919–2923 (2011). https://doi.org/10.1016/j.surfcoat.2010.10.068
Endo-Kimura, M., Janczarek, M., Bielan, Z., Zhang, D., Wang, K., Markowska-Szczupak, A., Kowalska, E.: Photocatalytic and antimicrobial properties of Ag2O/TiO2 heterojunction. ChemEngineering. 3, 3 (2019). https://doi.org/10.3390/chemengineering3010003
Hou, Y., Pu, S., Shi, Q., Mandal, S., Ma, H., Xue, S., Cai, G., Bai, Y.: Ultrasonic impregnation assisted in-situ photoreduction deposition synthesis of Ag/TiO2/rGO ternary composites with synergistic enhanced photocatalytic activity. J Taiwan Inst Chem Eng. 104, 139–150 (2019). https://doi.org/10.1016/j.jtice.2019.08.023
Liu, X., Wang, Z., Wu, Y., Liang, Z., Guo, Y., Xue, Y., Tian, J., Cui, H.: Integrating the Z-scheme heterojunction into a novel Ag 2 O@rGO@reduced TiO 2 photocatalyst: broadened light absorption and accelerated charge separation co-mediated highly efficient UV/visible/NIR light photocatalysis. J Colloid Interface Sci. 538, 689–698 (2019). https://doi.org/10.1016/j.jcis.2018.12.070
Sullivan, K.T., Wu, C., Piekiel, N.W., Gaskell, K., Zachariah, M.R.: Synthesis, and reactivity of nano-Ag2O as an oxidizer for energetic systems yielding antimicrobial products. Combust Flame. 160, 438–446 (2013). https://doi.org/10.1016/j.combustflame.2012.09.011
Xiao, L., Youji, L., Feitai, C., Peng, X., Ming, L.: Facile synthesis of mesoporous titanium dioxide doped by Ag-coated graphene with enhanced visible-light photocatalytic performance for methylene blue degradation. RSC Adv. 7, 25314–25324 (2017). https://doi.org/10.1039/c7ra02198d
Olya, M.E., Vafaee, M., Jahangiri, M.: Modeling of acid dye decolorization by TiO2–Ag2O nano-photocatalytic process using response surface methodology modeling of acid dye decolorization by TiO2–Ag2O nano-photocatalyts. J Saudi Chem Soc. 21, 633–642 (2017). https://doi.org/10.1016/j.jscs.2015.07.006
Franco Jr., A., H.: V Pessoni, optical band-gap and dielectric behavior in Ho-doped ZnO nanoparticles. Mater Lett. 180, 305–308 (2016)
Kumar, V., Singh, R.G., Purohit, L.P., Singh, F.: Effect of swift heavy ion on structural and optical properties of undoped and doped nanocrystalline zinc oxide films. Adv Mat Lett. 4, 423–427 (2013)
Hosseini, M., Haghighatzadeh, A., Mazinani, B.: Enhanced third-order optical susceptibility in heterogeneous wurtzite ZnO/anatase TiO2 core/shell nanostructures via controlled TiO2 shell thickness. Opt Mater (Amst). 92, 1–10 (2019)
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This work was partially supported by the Ahvaz Branch of Islamic Azad University and the authors would like to thank the Research Council for their generous support of this work.
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Bayati, F., Mohammadi, M.K., Yengejeh, R.J. et al. Ag2O/GO/TiO2 composite nanoparticles: synthesis, characterization, and optical studies. J Aust Ceram Soc 57, 287–293 (2021). https://doi.org/10.1007/s41779-020-00528-3
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DOI: https://doi.org/10.1007/s41779-020-00528-3