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Syntheses, Structures and Luminescence Sensing Properties of Two Cd(II) MOFs Constructed from Mixed Ligands

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Abstract

Hydrothermally reaction of Cd(NO3)2·4H2O, pimelic acid (H2Pim) mixed with two N-containing ligands of 1,2-bis(2-methyl-imidazol-1-ylmethyl)benzene (1,2-mbix) or 1,3-bis(2-methyl-imidazol-1-ylmethyl)benzene (1,3-mbix) gave rise to two new Cd(II) MOFs, [Cd(Pim)(1,2-mbix)] (1) and [Cd(Pim)(1,3-mbix)]·H2O (2). Both MOFs were structurally characterized by IR and UV–Vis spectra, single-crystal and powder X-ray diffraction, thermogravimetric analyses. MOF 1 shows a fourfold interpenetrating dia network. Differently, MOF 2 shows a 2D → 3D interdigitated architecture base on the 63 hcb layer when 1,2-mbix was replaced by 1,3-mbix. The luminescent properties of 1 and 2 have been investigated. Furthermore, the luminescent quenching experiments suggest both MOFs exhibit good selectivity and sensitivity to detect Fe3+ and Cr2O72− in water.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21601105), and the Scientific Research Foundation of Qufu Normal University (No. 6106).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, China

    Fang-Hua Zhao, Jian-Hui Han, Yu-Wen Lin & Zhong-Lin Li

  2. College of Chemistry and Chemical Engineering, Qilu Normal University, Jinan, 250200, China

    Shao-Shuang Zou

  3. Key Laboratory of Functional Polymer Materials of Ministry of Education, College of Chemistry, Nankai University, Tianjin, 300071, China

    Tao Liu

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  1. Fang-Hua Zhao
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Zhao, FH., Han, JH., Lin, YW. et al. Syntheses, Structures and Luminescence Sensing Properties of Two Cd(II) MOFs Constructed from Mixed Ligands. J Clust Sci 32, 1711–1721 (2021). https://doi.org/10.1007/s10876-020-01931-3

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  • DOI: https://doi.org/10.1007/s10876-020-01931-3

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