Abstract
Recently geopolymer technology possesses not only great efficiency in immobilizing heavy metal wastes but also produces valuable materials that can be applied in building sectors. The aim of this study is to examine the capability of geopolymers in the immobilization and entrapping of heavy metals bearing materials. The study will focus on the evaluation of optimum ratio of heavy metal that can affect and densify the produced composite. The studied mortar’s binder was made from blast furnace slag, while the used fine aggregates were air-cooled slag < 1 mm. However, the used activator was 8% sodium hydroxide. The studied heavy metals’ bearing materials were barium sulfate, lead phosphate, lead slag and electric arc furnace dust used as partial replacement of blast furnace slag. The physico-mechanical characterization of each set of samples was conducted using XRD, FTIR, SEM, compressive strength and bulk density. Results demonstrated that barium sulfate can be efficiently used up to 2%, lead phosphate up to 1%, lead slag up to 5% and electric arc furnace dust up to 10%.
Similar content being viewed by others
References
Kontopoulos, A.; Komnitsas, K. K.; Xenidis, A.: Environmental characterization of the lead smelter slags in Lavrion. In: Proceedings of the IMM Minerals Metals and the Environment II Conference, Prague, (1996)
Glasser, F.P.: Fundamental aspects of cement solidification and stabilization. J. Hazard. Mater. 52(2–3), 151–170 (1997)
Malviya, R.; Chaudhary, R.: Factors affecting hazardous waste solidification/stabilization, a review. J. Hazard. Mater. B137, 267–276 (2006)
Duxson, P.; Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo, A.; van Deventer, J.S.J.: Geopolymer technology, the current state of the art. J. Mater. Sci. 42(9), 2917–2933 (2007)
Provis, J.L.; Lukey, G.C.; van Deventer, J.S.J.: Do geopolymers actually contain nano crystalline zeolites a reexamination of existing results. Chem. Mater. 17(12), 3075–3085 (2005)
Shi, C.; Krivenko, P.V.; Roy, D.M.: Alkali-Activated Cements and Concretes, p. 376. Taylor & Francis, Abingdon (2006)
Van Deventer, J.S.J.; Provis, J.L.; Duxson, P.; Lukey, G.C.: Reaction mechanisms in the geopolymeric conversion of inorganic waste to useful products. J. Hazard. Mater. A139(3), 506–513 (2007)
Milestone, N.B.: Reactions in cement encapsulated nuclear wastes, need for toolbox of different cement types. Adv. Appl. Ceram. 105(1), 13–20 (2006)
Deja, J.: Immobilization of Cr6+, Cd2+, Zn2+ and Pb2+ in alkali-activated slag binders. Cement Concrete Res. 32(12), 1971–1979 (2002)
Van Jaarsveld, J.G.S.; van Deventer, J.S.J.: The effect of metal contaminants on the formation and properties of waste-based geopolymers. Cement Concrete Res. 29(8), 1189–1200 (1999)
Palomo, A.; Palacios, M.: Alkali-activated cementitious materials: alternative matrices for the immobilization of hazardous wastes, Part II. Stabilization of chromium and lead. Cement Concrete Res. 33(2), 289–295 (2003)
Duxson, P.; Provis, J.L.; Lukey, G.C.; Mallicoat, S.W.; Kriven, W.M.; van Deventer, J.S.J.: Understanding the relationship between geopolymer composition, microstructure and mechanical properties. Colloids Surf. APhysicochem. Eng. Asp. 269(1–3), 47–58 (2005)
Duxson, P.; Mallicoat, S.W.; Lukey, G.C.; Kriven, W.M.; van Deventer, J.S.J.: The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers. Colloids Surf. A Physicochem. Eng. Asp. 292(1), 8–20 (2007)
Van Jaarsveld, J.G.S.: Ph.D. Thesis, University of Melbourne, Australia, (2000); 381
Lloyd, R.R.: Ph.D. Thesis, University of Melbourne, Australia, to be submitted
Lee, W.K.W.; van Deventer, J.S.J.: The effect of ionic contaminants on the early-age properties of alkali-activated fly ash-based cements. Cement Concrete Res. 32(4), 577–584 (2002)
Khater, H.M.: Hybrid slag geopolymer composites with durable characteristics activated by cement kiln dust. Constr. Build. Mater. 228, 116708 (2019). https://doi.org/10.1016/j.conbuildmat.2019.116708
Lizcano, M.; Kim, H.S.; Basu, S.; Radovic, M.: Mechanical properties of sodium and potassium activated metakaolin-based geopolymers. J. Mater. Sci. 47, 2607–2616 (2012)
Fernández-Jiménez, A.; Zibouche, F.; Boudissa, N.; García-Lodeiro, I.; Abadlia, M.T.; Palomo, A.: Metakaolin-slag-clinker blends. The role of Na+ or K+ as alkaline activators of theses ternary blends. J. Am. Ceram. Soc. 96(6), 1991–1998 (2013)
Hounsia, A.D.; Nanab, G.; Djétélia, G.; Blanchart, P.; Alowanoua, D.; Kpeloua, P.; Napoa, K.; Tchangbédjia, G.; Praisler, M.: How does Na, K alkali metal concentration change the early age structural characteristic of kaolin-based geopolymers. Ceram. Int. 40, 8953–8962 (2014)
Leong, H.Y.; Ong, D.E.L.; Sanjayan, J.G.; Nazari, A.: The effect of different Na2O and K2O ratios of alkali activator on compressive strength of fly ash based-geopolymer. Constr. Build. Mater. 106, 500–511 (2016)
Zhang, F.; Zhanga, L.; Liua, M.; Mub, C.; Lianga, Y.N.; Huc, X.: Role of alkali cation in compressive strength of metakaolin based geopolymers. Ceram. Int. 43, 3811–3817 (2017)
Hu, N.; Bernsmeier, D.; Grathoff, G.H.; Warr, L.N.: The influence of alkali activator type, curing temperature and gibbsite on the geopolymerization of an interstratified illite-smectite rich clay from Fried land. Appl. Clay Sci. 135, 386–393 (2017)
Steins, P.; Poulesquen, A.; Frizon, F.; Diat, O.; Jestin, J.; Causse, J.; Lambertina, D.; Rossignol, S.: Effect of aging and alkali activator on the porous structure of a geopolymer. J. Appl. Crystallogr. 47, 316–324 (2014)
Lemougna, P.N.; Melo, U.F.C.; Delplancke, M.P.; Rahier, H.: Influence of the activating solution composition on the stability and thermo-mechanical properties of inorganic polymers (geopolymers) from volcanic ash. Constr. Build. Mater. 48, 278–286 (2013)
Chequer, C.D.; Frizon, F.: Impact of sulfate and nitrate incorporation on potassium and sodium-based geopolymers: geopolymerization and materials properties. J. Mater. Sci. 46, 5657–5664 (2011)
Palomo, A.; Grutzeck, M.W.; Blanco, M.T.: Alkali-activated fly ashes: a cement for the future. Cem. Concr. Res. 29, 1323–1329 (1999)
Wang, S.; Li, L.; Zhu, Z.H.: Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater. J. Hazard. Mater. B139, 254–259 (2007)
Al-Zboon, K.; Al-Harahsheh, M.S.; Hani, F.B.: Fly ash-based geopolymer for Pb removal from aqueous solution. J. Hazard. Mater. 188, 414–421 (2011)
López, F.J.; Sugita, S.; Tagaya, M.; Kobayashi, T.: Metakaolin-based geopolymers for targeted adsorbents to heavy metal ion separation. J. Mater. Sci. Chem. Eng. 2, 16–27 (2014)
Al-Harahsheh, M.S.; Al Zboon, K.; Al-Makhadmeh, L.; Hararah, M.; Mahasneh, M.: Fly ash based geopolymer for heavy metal removal: a case study on copper removal. J. Environ. Chem. Eng. 3, 1669–1677 (2015)
Ge, Y.; Cui, X.; Kong, Y.; Li, Z.; He, Y.; Zhou, Q.: Porous geopolymeric spheres for removal of Cu(II) from aqueous solution: synthesis and evaluation. J. Hazard. Mater. 283, 244–251 (2015)
Javadian, H.; Ghorbani, F.; Tayebi, H.; Asl, S.H.: Study of the adsorption of Cd (II)from aqueous solution using zeolite-based geopolymer synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies. Arabian J. Chem. 8, 837–849 (2015)
Luukkonen, T.; Runtti, H.; Niskanen, M.; Tolonen, E.; Sarkkinen, M.; Kemppainen, K.; Rämö, J.; Lassi, U.: Simultaneous removal of Ni(II) As(III), and Sb(III) from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers. J. Environ. Manage. 166, 579–588 (2016)
Ge, Y.; Cui, X.; Liao, C.; Li, Z.: Facile fabrication of green geopolymer/alginate hybrid spheres for efficient removal of Cu(II) in water: batch and column studies. Chem. Eng. J. 311, 126–134 (2017)
Kara, I.; Yilmazer, D.; Akar, S.T.: Metakaolin based geopolymer as an effective adsorbent for adsorption of zinc(II) and nickel(II) ions from aqueous solutions. Appl. Clay Sci. 139, 54–63 (2017)
Wan, Q.; Rao, F.; Song, S.; Leon-Patino, C. A.; Ma, Y.; Yin, W.: Consolidation of mine tailings through geopolymerization at ambient temperature, J. Am. Ceram. Soc. 1–11 (2018)
Ke, X.; Bernal, S.A.; Ye, N.; Provis, J. L.; Yang, J.: One-part geopolymers based on thermally treated red Mud/NaOH Blends. J. Am. Ceram. Soc. 1–7 (2014)
ASTM C109M: Standard Test Method for Compressive Strength of Hydraulic Cement Mortars, Annual Book of ASTM Standards; ASTM International: West Conshohocken, PA, USA, (2016)
Standards, Egyptian: Concrete Building Units Used in Non-Load and Load Bearing Walls, p. 1292. Egyptian Organization for Standardization, Cairo (1992)
Ugheoke, B.I.; Onche, E.O.; Namessan, O.N.; Asikpo, G.A.: Property Optimization of Kaolin—Rice Husk Insulating Fire—Bricks. Leonardo Electronic J. Pract. Technol. 9, 167–178 (2006)
de Vargas, A.S.; DalMolin, D.C.; Masuero, Â.B.; Vilela, A.C.; Castro-Gomes, J.; de Gutierrez, R.M.: Strength development of alkali-activated fly ash produced with combined NAOH and CA(OH)2 activators. Cement Concrete Compos. 53, 341–349 (2014)
Panias, D.; Giannopoulou, I.P.; Perraki, T.: Effect of synthesis parameters on the mechanical properties of fly ash-based geopolymers, Colloids and Surfaces A: physico-chem. Eng. Aspects 301, 246–254 (2007)
Kalinkin, A.M.; Kalinkina, E.V.; Politov, A.A.; Makarov, V.N.; Boldyrev, V.V.: Mechanochemical interaction of Ca silicate and aluminosilicate minerals with carbon dioxide. J. Mater. Sci. 39, 5393–5398 (2004)
Temuujin, J.; Van Riessen, A.; Williams, R.: Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes. J. Hazard. Mater. J. Hazard. Mater. 167(1–3), 82–88 (2009)
Weitzel, B.; Hansen, M. R.; Kowald, T. L.; Müller, T.; Spiess, H. W.; Trettin, H. F. R.: Influence of Multiwalled Carbon Nanotubes on the Microstructure of CSH-Phases. In: Proceeding of 13th Congress on the Chemistry of Cement, 3-8 July (2011), Madrid, Spain
Alarcon-Ruiz, L.; Platret, G.; Massieu, E.; Ehrlacher, A.: The use of thermal analysis in assessing the effect of temperature on a cement paste. Cem. Concr. Res. 35(3), 609–613 (2005)
Buchwald, A.; Tatarin, R.; Stephan, D.: Reaction progress of alkaline-activated metakaolin-ground granulated blast furnace slag blends. J. Mater. Sci. 44, 5609–5617 (2009)
Bernal, S.A.; Provis, J.L.; Rose, V.; Mejía de Gutiérrez, R.: Evolution of binder structure in sodium silicate-activated lag metakaolin blends. Cem. Concr. Compos. 33(1), 46–54 (2011)
Engelhardt, G.; Felsche, J.; Sieger, P.: The hydrosodalite system Na6+x[SiAlO4]6(OH)x.nH2O: formation, phase composition, and de- and rehydration studied by 1H, 23Na, and 29Si MAS-NMR spectroscopy in tandem with thermal analysis, X-ray diffraction, and IR spectroscopy. J. Am. Chem. Soc. 114, 1173–1182 (1992)
Barall, E.M.; Rogers, L.B.: Differential thermal analysis of the decomposition of sodium bicarbonate and its simple double salts. J. Inorg. Nucl. Chem. 28, 41 (1966). https://doi.org/10.1016/0022-1902(66)80226-9
Vu, T.H.; Gowripalan, N.: Mechanism of heavy metal immobilization using geopolymerization techniques- a review. J. Adv. Concr. Technol. 18, 124–135 (2018)
Davidovits, J.: Properties of geopolymer cements. In: 1st International Conference of Alkaline Cements and Concretes, (1994), pp. 131-149- Kiev, Ukraine
Zheng, L.; Wang, W.; Shi, Y.: The effects of alkaline dosage and Si/Al ratio on immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer. Chemosphere 79, 665–671 (2010)
Grutzeck, M.W.; Siemer, D.D.: Zeolites synthesized from class F fly ash and sodium aluminate slurry. J. Am. Ceram. Soc. 80(9), 2449–2453 (1997)
Khater, H.M.: Influence of electric arc furnace slag on characterisation of the produced geopolymer composites, építôanyag. J. Silicate Based Compos. Mater. 67(3), 82–88 (2015)
Khater, H.M.: Effect of Nano silica on microstructure formation of low cost geopolymer binder. J. Nanocompos. (Taylor and Francis) 2(2), 84–97 (2016). https://doi.org/10.1080/20550324.2016.1203515
Khater, H.M.; Nagar, El; Abdeen, M.: Combination between organic polymer and geopolymer for production of eco-friendly metakaolin composite. Int. J. Australian Ceramic Soc. (2019). https://doi.org/10.1007/s41779-019-00371-1
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khater, H.M., Ghareib, M. Utilization of alkaline Aluminosilicate activation in heavy metals immobilization and producing dense hybrid composites. Arab J Sci Eng 46, 6333–6348 (2021). https://doi.org/10.1007/s13369-020-05065-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13369-020-05065-6