Issue 1, 2021
From the journal:

CrystEngComm

Unusual porous crystals via catenation of 1D ladders: unprecedented mixture effects on the adsorption of xylene isomers in a SCSC mode†

Soojin Lee,a   Dongwon Kim,a   In-Hyeok Park ORCID logo a  and  Ok-Sang Jung ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Pusan National University, Busan 46241, Republic of Korea
E-mail: oksjung@pusan.ac.kr
Fax: (+82) 51 5163522
Tel: (+82) 51 5103240

Abstract

Self-assembly of silver(I) perchlorate with a C3-symmetric tridentate N-donor ligand produces stable crystals with open channels via catenation of 1D ladder-type coordination polymers. The open-channel crystal shows both unprecedented mixture and temperature effects on the adsorption and separation of o-, m-, and p-xylene isomers in a single-crystal-to-single-crystal (SCSC) mode. o-Xylene is not adsorbed into the channel at 5 °C, but is inserted into the channel at room temperature. In particular, the 1 : 1 mixture of o- and m-xylene was adsorbed into the channel in the 1 : 1 mole ratio via intermolecular weak interactions at 5 °C. In addition, the porous crystals are a practical template for structural determination of small liquid hydrocarbons in the SCSC state.

Graphical abstract: Unusual porous crystals via catenation of 1D ladders: unprecedented mixture effects on the adsorption of xylene isomers in a SCSC mode

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CE01458C
Article type
Paper
Submitted
05 Oct 2020
Accepted
20 Oct 2020
First published
21 Oct 2020

CrystEngComm, 2021,23, 40-46

Permissions

Request permissions

Unusual porous crystals via catenation of 1D ladders: unprecedented mixture effects on the adsorption of xylene isomers in a SCSC mode

S. Lee, D. Kim, I. Park and O. Jung, CrystEngComm, 2021, 23, 40 DOI: 10.1039/D0CE01458C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements