Abstract
An innovative two-step noncatalytic esterification technique was proposed to synthesize alkyl esters from free fatty acids simulated in waste cooking oil, as a pretreatment process for biodiesel production, without adding any catalyst under normal conditions of pressure and temperature. The effect of methanol:oil molar ratio, reaction time, mixing rate, and reaction temperature were investigated. The results confirmed that the conversion of the reaction was increased when increasing the methanol molar ratio and decreased in prolonged reaction temperature. High conversion (94.545%) was successfully achieved at optimized conditions of 115:1, 65:1 methanol:oil molar ratio in the first step and second step, respectively, other conditions in both steps were found to be 9 s reaction time, 450 rpm mixing rate, and 62 °C reaction temperature by response surface methodology central composite design. Noncatalytic esterification, which eliminates the complications corresponding with catalyst utilization such as additional cost, time-wasting, and separation requirements, could be considered as a promising pretreatment technique to reduce the high acidity of waste cooking oil to the acceptable limit of 1 mg KOH/g oil or less in two steps, for biodiesel synthesize.
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References
Silva SP, Sales DCS, de Abreu CAP, Schuler ARP, de Abreu CAM (2017) Kinetics of the biphasic liquid–liquid transesterification of vegetable oils into biodiesel. Reac Kinet Mech Cat 123:529–542. https://doi.org/10.1007/s11144-017-1322-8
Ajala EO, Ajala MA, Odetoye TE, Okunlola AT (2019) Synthesis of solid catalyst from dolomite for biodiesel production using palm kernel oil in an optimization process by definitive screening design. Braz J Chem Eng 36:979–994. https://doi.org/10.1590/0104-6632.20190362s20180516
Alismaeel ZT, Abbas AS, Albayati TM, Doyle AM (2018) Biodiesel from batch and continuous oleic acid esterification using zeolite catalysts. Fuel 234:170–176. https://doi.org/10.1016/j.fuel.2018.07.025
Chai M, Tu Q, Lu M, Yang YJ (2014) Esterification pretreatment of free fatty acid in biodiesel production, from laboratory to industry. Fuel Process Technol 125:106–113. https://doi.org/10.1016/j.fuproc.2014.03.025
Hassan F, Aljbory I, Kassim T (2013) An attempt to stimulate lipids for biodiesel production from locally isolated microalgae in Iraq. Baghdad Sci J 10:97–108
Zayed MA, Abd El-Kareem MSM, Zaky NHS (2017) Gas Chromatography-Mass Spectrometry studies of waste vegetable mixed and pure used oils and its biodiesel products. J Pharm Appl Chem 3:109–116. https://doi.org/10.18576/jpac/030204
Afsharizadeh M, Mohsennia M (2019) Catalytic synthesis of biodiesel from waste cooking oil and corn oil over zirconia-based metal oxide nanocatalysts. Reac Kinet Mech Cat 128:443–459. https://doi.org/10.1007/s11144-019-01622-9
Aboelazayem O, Gadalla M, Saha B (2019) Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil. Renew Energy 143:77–90. https://doi.org/10.1016/j.renene.2019.04.106
Sahar SS, Iqbal J, Ullah I, Bhatti HN, Nouren S, Habib-ur-Rehman JN, Iqbal M (2018) Biodiesel production from waste cooking oil: an efficient technique to convert waste into biodiesel. Sustain Cities Soc 41:220–226. https://doi.org/10.1016/j.scs.2018.05.037
Carlini M, Castellucci S, Cocchi S (2014) A pilot-scale study of waste vegetable oil transesterification with alkaline and acidic catalysts. Energy Procedia 45:198–206
Navajas A, Reyero I, Jiménez-Barrera E, Romero-Sarria F, Llorca J, Gandía LM (2020) Catalytic performance of bulk and Al2O3-supported molybdenum oxide for the production of biodiesel from oil with high free fatty acids content. Catalysts 10:1–14
Suresh R, Antony JV, Vengalil R, Kochimoolayil GE, Joseph R (2017) Esterification of free fatty acids in non-edible oils using partially sulfonated polystyrene for biodiesel feedstock. Ind Crops Prod 95:66–74. https://doi.org/10.1016/j.indcrop.2016.09.060
Gaurav A, Dumas S, Mai CTQ, Ng FTT (2019) A kinetic model for a single step biodiesel production from a high free fatty acid (FFA) biodiesel feedstock over a solid heteropolyacid catalyst. Green Energy Environ 4:328–341. https://doi.org/10.1016/j.gee.2019.03.004
Sharma YC, Singh B, Upadhyay SN (2008) Advancements in development and characterization of biodiesel: a review. Fuel 87:2355–2373
Takagaki A, Toda M, Okamura M, Kondo JN, Hayashi S, Domen K, Hara M (2006) Esterification of higher fatty acids by a novel strong solid acid. Catal Today 116:157–161
Ataya F, Dubé MA, Ternan M (2007) Acid-catalyzed transesterification of canola oil to biodiesel under single- and two-phase reaction conditions. Energy Fuels 21:2450–2459
Birla A, Singh B, Upadhyay SN, Sharma YC (2012) Kinetics studies of synthesis of biodiesel from waste frying oil using a heterogeneous catalyst derived from snail shell. Bioresour Technol 106:95–100
Changi S, Pinnarat T, Savage PE (2011) Mechanistic modeling of hydrolysis and esterification for biofuel processes. Ind Eng Chem Res 50:12471–12478
Canoira L, Rodríguez-Gamero M, Querol E, Alcántara R, Lapuerta M, Oliva F (2008) Biodiesel from low-grade animal fat: production process assessment and biodiesel properties characterization. Ind Eng Chem Res 47:7997–8004
Zheng S, Kates M, Dubé MA, McLean DD (2006) Acid-catalyzed production of biodiesel from waste frying oil. Biomass Bioenerg 30:267–272
Budhwani AAA, Maqbool A, Hussain T, Syed MN (2019) Production of biodiesel by enzymatic transesterification of non-edible Salvadora persica (Pilu) oil and crude coconut oil in a solvent-free system. Bioresour Bioprocess. https://doi.org/10.1186/s40643-019-0275-3
Rani KNP, Neeharika TSVR, Vardhan GH, Kumar TP, Devi BLAP (2020) The kinetics of the esterification of free fatty acids in jatropha oil using glycerol based solid acid catalyst. Eur J Sustain Dev Res 4:1–11. https://doi.org/10.29333/ejosdr/7594
Ghadge SV, Raheman H (2006) Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology. Bioresour Technol 97:379–384
Soufi MD, Ghobadian B, Najafi G, Mousavi SM (2017) Optimization of methyl ester production from waste cooking oil in a batch tri-orifice oscillatory baffled reactor. Fuel Process Technol 167:641–647
Ghadge SV, Raheman H (2005) Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids. Biomass Bioenerg 28:601–605
Encinar JM, Sánchez N, Martínez G, García L (2011) Study of biodiesel production from animal fats with high free fatty acid content. Bioresour Technol 102:10907–10914
Canakci M, Van Gerpen J (2001) Biodiesel production from oils and fats with high free fatty acids. Am Soc Agric Eng 44:1429–1436
Liu Y, Lotero E, Goodwin JG (2006) Effect of water on sulfuric acid catalyzed esterification. J Mol Catal A 245:132–140
Doyle AM, Albayati TM, Abbas AS, Alismaeel ZT (2016) Biodiesel production by esterification of oleic acid over zeolite Y prepared from kaolin. Renew Energy 97:19–23. https://doi.org/10.1016/j.renene.2016.05.067
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Special gratitude to the University of Baghdad AL Khwarizmi College of Engineering for the offered assistance in carrying out this investigation.
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Alkhafaje, Z.A., Mohammed, A.K. & Rashid, I.M. Development of two-step noncatalytic esterification of waste cooking oil for biodiesel preparation. Reac Kinet Mech Cat 131, 645–659 (2020). https://doi.org/10.1007/s11144-020-01873-x
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DOI: https://doi.org/10.1007/s11144-020-01873-x