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Impedance analysis of zirconium-doped lithium manganese oxide

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Abstract

In recent days, portable electronic devices are indispensable to improve the standard of living, which led to the demand for energy storage devices with good performance. Among the storage devices, rechargeable lithium ion batteries play a vital role due to the good electrical conductivity. In this study, impedance and electrical performance were studied for zirconium-doped Li4Mn5O12 at different concentrations (0.1, 0.2, 0.3 and 0.4 mol). The structural and morphological properties of the material were studied by powder X-ray diffractometer spectra and scanning electron microscopy analysis. Morphological properties exhibit the combination of polyhedral and needle-shaped particles, which were in micron size. The Nyquist plot indicates the absence of grain boundary effect and explained the bulk property, i.e., the negative temperature co-efficient of resistance property of the material. Zirconium-doped lithium manganese oxide (0.2 mol) exhibits good electrical property than other concentrations. Maximum conductivity was (1.4 × 10−5 S cm−1) observed at 160°C for the same. These results suggested that 0.2 mol of zirconium will enhance the electrical property of lithium manganese oxide (Li4Mn5O12).

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Authors and Affiliations

  1. Department of Physics, Karpagam Academy of Higher Education, Coimbatore, 641021, India

    Sam Manova Vedhanayagam, Sharmila Saminathan & B Janarthanan

  2. Department of Physics, Sri Ramakrishna Mission Vidhyalaya College of Arts and Science, Coimbatore, 641020, India

    J Chandrasekaran

Authors
  1. Sam Manova Vedhanayagam
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  2. Sharmila Saminathan
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  3. B Janarthanan
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  4. J Chandrasekaran
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Correspondence to Sharmila Saminathan.

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Vedhanayagam, S.M., Saminathan, S., Janarthanan, B. et al. Impedance analysis of zirconium-doped lithium manganese oxide. Bull Mater Sci 43, 294 (2020). https://doi.org/10.1007/s12034-020-02257-6

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  • DOI: https://doi.org/10.1007/s12034-020-02257-6

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