Abstract
1,2-trans-diiodo-ethene (C2H2I2) – is an overlooked halogen bond donor, which demonstrate the distinct similarity of the geometry and directionality of I···I halogen bonds around the iodine atoms in its native and CpMn(CO)2(C2H2I2) π-complex crystals. Distortion of the planar geometry of C2H2I2 upon the π-coordination result the distortion of the native planar layered geometry of C2H2I2, so that [CpMn(CO)2](π-C2H2I2) features more complex I···I XB assisted 3D network. Unusual structural parallels between the native C2H2I2 crystals and solid iodine are discussed.
Funding source: Russian Scientific Foundation
Award Identifier / Grant number: project № 19-13-00338
Acknowledgments
XRD experiments were performed using the equipment of shared experimental facilities supported by Kurnakov Institute of General and Inorganic Chemistry RAS.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This work is supported by Russian Scientific Foundation (grant No 19-13-00338).
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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