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Multiblock Copoly(urethane–imide)s with the Properties of Thermoplastic Elastomers

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Abstract

A review of the works performed at the Institute of Macromolecular Compounds, Russian Academy of Sciences in the field of multiblock copoly(urethane–imide)s, a relatively new subclass of thermally stable polymers, is presented. The synthesis of the representative family of copoly(urethane–imide)s different in the chemical structure and ratio of flexible polyester/polyether and rigid urethane–imide blocks is performed. Mixed compounds composed of synthesized copoly(urethane–imide)s and thermoplastic polyimides are obtained. The effect of the chemical structure of the flexible and rigid blocks and their ratio on the glass and melting transitions of the studied polymer systems is investigated. Polymer systems that form stable melts and are suitable for processing to thick-wall products, thermoplastic elastomers, are proposed.

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REFERENCES

  1. X. Sang, R. Wang, X. Chen, L. Zhang, A. N. Man, and Yi. Shen, Adv. Mater. Res. 284–286, 1746 (2011).

    Article  Google Scholar 

  2. X. Solimando, J. Babin, C. Arnal-Herault, M. Wang, D. Barth, D. Roizard, J.-R. Doillon-Halmenschlager, M. Poncot, I. Royaud, P. Alcouffe, L. David, and A. Jonquires, Polymer 31, 56 (2017).

    Article  Google Scholar 

  3. T. Ueda and S.-I. Inoue, Open J. Polym. Mater. 8, 1 (2018).

    Article  Google Scholar 

  4. P. Wright and A.P. C. Cumming, Solid Polyurethane Elastomers (Gordon and Breach, New York, 1969).

    Google Scholar 

  5. M. I. Bessonov, M. M. Koton, V. V. Kudryavtsev, and L. A. Laius, Polyimides: A Class of Thermally Stable Polymers (Nauka, Moscow, 1983) [in Russian].

    Google Scholar 

  6. T. Ueda and S.-I. Inoue, Open J. Polym. Mater. 8, 11 (2018).

    CAS  Google Scholar 

  7. T. Ueda, T. Nishio, and S. Inoue, Open J. Org. Polym. Mater. 7, 47 (2017).

    Article  CAS  Google Scholar 

  8. A. C. de Visser, D. E. Gregonis, and A. A. Driessen, Makromol. Chem. 179, 1855 (1978).

    Article  CAS  Google Scholar 

  9. KhiMiK.ru—THERMOELASTOPLASTS—Chemical Encyclopedia. http://www.xumuk.ru/encyklopedia/2/4389.html. Cited 2020.

  10. A. Jonquieres, R. Clement, and P. Lochon, Prog. Polym. Sci. 27, 1803 (2002).

    Article  CAS  Google Scholar 

  11. X. Solimando, J. Babin, C. Arnal-Herault, M. Wang, D. Barth, D. Roizard, J.-R. Doillon-Halmenschlager, M. Poncot, I. Royaud, P. Alcouffe, L. David, and A. Jonquieres, Polymer 131, 56 (2017).

    Article  CAS  Google Scholar 

  12. H. Yeganeh and M. A. Shamekhi, Polymer 45, 359 (2004).

    Article  CAS  Google Scholar 

  13. R. M. Gerkin and B. L. Hilker, in Encyclopedia of Materials: Science and Technology (Springer, Heidelberg, 2008), p. 730.

    Google Scholar 

  14. B. Masiluanis, J. Hroutz, J. Baldrian, and M. Ilavsky, J. Appl. Polym. Sci. 34, 1941 (1987).

    Article  Google Scholar 

  15. B. A. Koenitzer, US Patent No. 4929358 (1990).

  16. A. L. Didenko, V. E. Smirnova, G. V. Vaganov, E. N. Popova, V. Yu. Elokhovskii, O. V. Toloshko, E. S. Vasilyeva, V. M. Svetlichnyi, V. E. Yudin, and V. V. Kudryavtsev, J. Int. Sci. Publ.: Mater., Meth. Technol. 12, 144 (2018).

    Google Scholar 

  17. A. L. Didenko, V. E. Smirnova, G. V. Vaganov, E. N. Popova, O. V. Toloshko, E. S. Vasilyeva, V. M. Svetlichnyi, V. E. Yudin, and V. V. Kudryavtsev, Russ. Chem. Bull. 68, 1603 (2019).

    Article  CAS  Google Scholar 

  18. A. L. Didenko, V. E. Smirnova, G. V. Vaganov, E. N. Popova, O. V. Toloshko, E. S. Vasilyeva, V. Yu. Elokhovskii, A. G. Ivanov, V. M. Svetlichnyi, V. E. Yudin, and V. V. Kudryavtsev, Russ. J. Appl. Chem. 93, 54 (2020).

    Article  Google Scholar 

  19. A. L. Didenko, D. A. Kuznetsov, V. E. Smirnova, E. N. Popova, G. V. Vaganov, A. G. Ivanov, V. E. Yudin, V. M. Svetlichnyi, V. V. Kudryavtsev, Russ. Chem. Bull. 69, 369 (2020).

    Article  CAS  Google Scholar 

  20. A. L. Didenko, V. M. Svetlichnyi, V. E. Smirnova, E. N. Popova, G. V. Vaganov, V. E. Yudin, and V. V. Kudryavtsev, Polym. Sci., Ser. A 61, 142 (2019).

    Article  Google Scholar 

  21. D. A. Kuznetsov, V. M. Svetlichnyi, A. L. Didenko, G. V. Vaganov, V. Yu. Elokhovskii, V. V. Kudryavtsev, and V. E. Yudin, Russ. J. Appl. Chem. (2020) (in press).

  22. RF Patent No. 2279452 (2004).

  23. V. M. Svetlichnyi and V. V. Kudryavtsev, Polym. Sci., Ser. B 45, 140 (2003).

    Google Scholar 

  24. D. B. Klinedinst, I. Yilgor, E. Yilgor, M. Zhang, and G. L. Wilkes, Polymer 53, 5358 (2012).

    Article  CAS  Google Scholar 

  25. K. N. Raftopoulos, M. Jancia, D. Aravopoulou, E. Hebda, K. Pielichowski, and P. Pissis, Macromolecules 46, 7378 (2013).

    Article  CAS  Google Scholar 

  26. P. T. Knight, K. M. Lee, H. Qin, and P. T. Mather, Biomacromolecules 9, 2458 (2008).

    Article  CAS  PubMed  Google Scholar 

  27. I. A. Kobykhno, A. L. Didenko, V. E. Smirnova, G. V. Vaganov, A. G. Ivanov, E. N. Popova, L. S. Litvinova, V. M. Svetlichnyi, E. S. Vasilyeva, O. V. Tolochko, V. E. Yudin, and V. V. Kudryavtsev, Mater. Phys. Mech. 40, 221 (2018).

    CAS  Google Scholar 

  28. I. Kobuchno, A. Didenko, D. Honcharenko, E. Vasilieva, V. Kudryavtsev, and O. Tolocko, Mater. Today: Proc. (2020) (in press).

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Correspondence to A. L. Didenko.

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Translated by E. Boltukhina

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Didenko, A.L., Kuznetsov, D.A., Vaganov, G.V. et al. Multiblock Copoly(urethane–imide)s with the Properties of Thermoplastic Elastomers. Polym. Sci. Ser. C 62, 90–110 (2020). https://doi.org/10.1134/S1811238220020046

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  • DOI: https://doi.org/10.1134/S1811238220020046

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