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Sulfonated Polyphenylquinoxalines: Synthesis, Thermal Stability, and Proton Conductivity

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Abstract

A brief analysis of the publications on the synthesis of polyphenylquinoxalines, their sulfonation, and the study of their thermal stability and proton conductivity is presented. Polyphenylquinoxaline is synthesized based on 3,3',4,4'-tetraaminodiphenyl oxide and 1,4-bis(phenylglyoxalyl) benzene and sulfonated. Films of sulfonated polyphenylquinoxaline with sulfur contents of 0.6, 1.7, 6.0, and 8.0% are obtained, and their thermal stability, proton conductivity, and testing as a proton-conducting membrane in a membrane electrode block of a fuel cell are investigated.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (the synthesis of polyphenylquinoxalines and sulfonated polyphenylquinoxalines with various compositions) as well as a state task, state registration no. № AAAA-A19-119061890019-5 (the study of thermal stability and proton conductivity), and was supported by the Russian Science Foundation, project no. 17-79-30054 (the testing of the membrane electrode block of fuel cells).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    N. M. Belomoina & E. G. Bulycheva

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    R. V. Pisarev, E. V. Gerasimova, A. V. Pisareva & Yu. A. Dobrovolsky

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  1. N. M. Belomoina
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  2. E. G. Bulycheva
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  3. R. V. Pisarev
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  4. E. V. Gerasimova
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  5. A. V. Pisareva
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  6. Yu. A. Dobrovolsky
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Correspondence to E. G. Bulycheva.

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Translated by E. Boltukhina

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Belomoina, N.M., Bulycheva, E.G., Pisarev, R.V. et al. Sulfonated Polyphenylquinoxalines: Synthesis, Thermal Stability, and Proton Conductivity. Polym. Sci. Ser. C 62, 222–230 (2020). https://doi.org/10.1134/S1811238220020022

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  • DOI: https://doi.org/10.1134/S1811238220020022

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