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Synlett 2021; 32(10): 962-970
DOI: 10.1055/a-1286-5934
DOI: 10.1055/a-1286-5934
account
Rare-Earth-Catalyzed Hydrosilylation and Dehydrogenative Coupling of Hydrosilanes
We are grateful to the National Natural Science Foundation of China (Grant Numbers 21890722, 22071123, 21632006) for financial support.
Abstract
Activation of Si–H bonds with rare-earth complexes could generate the highly reactive rare-earth hydrides or silyl complexes, which are key intermediates for hydrosilylation and cross-coupling reactions. This Account summarizes the recent advances in the rare-earth-catalyzed hydrosilylation of unsaturated substrates and dehydrogenative coupling of hydrosilanes with amines in our laboratory. The results demonstrated that rare-earth catalysts are unique in their reactivity and selectivity, enabling some unprecedented reactions.
1 Introduction
2 Dehydrogenative Coupling of Hydrosilanes with Amines
3 Catalytic Dehydrogenative Coupling of Hydrosilanes with Amines
4 Catalytic Hydrosilylation of Terminal Alkenes and Polymerization of Styrene
5 Catalytic Hydrosilylation of Internal Alkenes
6 Catalytic Dihydrosilylation of Internal Alkynes
7 Conclusions and Outlook
Publication History
Received: 19 September 2020
Accepted after revision: 08 October 2020
Accepted Manuscript online:
08 October 2020
Article published online:
05 November 2020
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