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Investigation of NLO Properties of Eriochrome Black T Colloidal Solution: Role of Surfactant and Reverse Micelles

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Abstract

The photophysical and nonlinear optical properties of Eriochrome Black T (EBT) in micelles, with two charge types of surfactant and reverse micelles (RMs) in a wide range of sizes, were investigated via ultraviolet–visible absorption, fluorescence spectroscopy, and a Z-scan technique. Accordingly, a significant redshift in absorbance and fluorescence quenching of the EBT was observed with an increase in cetyltrimethylammonium bromide (CTAB) concentration. Comparably, the nonlinear absorption coefficient (β) of the EBT decreased following an increase in cationic CTAB concentration, due to an increasing trend in the CTAB:EBT complex in the solution, and it decreased following an increase in anionic aerosol OT concentration. The same behavior was further detected for the nonlinear index of refraction (n2). The β value of the EBT also decreased with an increase in the size and concentration of the RMs, while the n2 was enhanced.

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Funding

This study was funded by Grant Number 2/51979.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran

    Narges Torabi, Farhad Asadullah Zarif & Afshin Azarpour

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  1. Narges Torabi
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  2. Farhad Asadullah Zarif
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  3. Afshin Azarpour
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Correspondence to Narges Torabi.

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Narges Torabi has received research grants from Ferdowsi University of Mashhad.

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Torabi, N., Zarif, F.A. & Azarpour, A. Investigation of NLO Properties of Eriochrome Black T Colloidal Solution: Role of Surfactant and Reverse Micelles. J. Electron. Mater. 50, 640–648 (2021). https://doi.org/10.1007/s11664-020-08564-2

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  • DOI: https://doi.org/10.1007/s11664-020-08564-2

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