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Oxygen absorption by the ternary system styrene oxide—copper(II) chloride—α-naphtol in alcoholic media

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Abstract

The fast absorption of molecular oxygen by a system including styrene oxide, copper(II) chloride, and α-naphthol (strong inhibitor of oxidation) was found and studied by the volumetric method. A low value of the activation energy of oxidation and a complicated concentration dependence of the reaction rate indicate that the oxidation proceeds via the formation of a ternary system, possibly, via a complex of three reactants. The thermolabile activity of the copper catalyst of oxidation was found for the oxidation of this system in a 85 vol.% ButOH + + 15 vol.% H2O solution.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    L. V. Petrov & V. M. Solyanikov

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  1. L. V. Petrov
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  2. V. M. Solyanikov
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Correspondence to L. V. Petrov.

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This work was carried out in terms of the state assignment (State Registration No. 01201361859).

Russian Chemical Bulletin, International Edition, Vol. 69, No. 10, pp. 1869–1872, October, 2020

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1869–1872, October, 2020.

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Petrov, L.V., Solyanikov, V.M. Oxygen absorption by the ternary system styrene oxide—copper(II) chloride—α-naphtol in alcoholic media. Russ Chem Bull 69, 1869–1872 (2020). https://doi.org/10.1007/s11172-020-2972-7

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  • DOI: https://doi.org/10.1007/s11172-020-2972-7

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