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Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates

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Abstract

The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction.

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Authors and Affiliations

  1. Baku State University, 23 Z. Khalilov str., AZ1148, Baku, Azerbaijan

    A. I. Ismiyev & A. M. Magerramov

  2. Kuban State University, 149 Stavropolskaya ul., 350040, Krasnodar, Russian Federation

    V. V. Dotsenko

  3. North-Caucasus Federal University, 1a ul. Pushkina, 355009, Stavropol, Russian Federation

    V. V. Dotsenko, N. A. Aksenov & I. V. Aksenova

Authors
  1. A. I. Ismiyev
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  2. V. V. Dotsenko
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  3. N. A. Aksenov
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  4. I. V. Aksenova
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  5. A. M. Magerramov
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Corresponding authors

Correspondence to A. I. Ismiyev or V. V. Dotsenko.

Additional information

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (theme 0795-2020-0031; project executors V. V. Dotsenko, N. A. Aksenov, and I. V. Aksenova).

Russian Chemical Bulletin, International Edition, Vol. 69, No. 10, pp. 1938–1943, October, 2020

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1938–1943, October, 2020.

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Ismiyev, A.I., Dotsenko, V.V., Aksenov, N.A. et al. Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates. Russ Chem Bull 69, 1938–1943 (2020). https://doi.org/10.1007/s11172-020-2982-5

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  • DOI: https://doi.org/10.1007/s11172-020-2982-5

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