Skip to main content
Log in

Parameterization of the structures arising in the deformation of elastomers

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The phase structure of synthetic isoprene rubber samples subjected to stretching was studied by transmission electron microscopy. A procedure for determining the fractal dimension of extended one-dimensional structures arising during deformation was proposed. Image parametrization, being the extraction of substantial acting parameters, their description, and quantitative estimation of the obtained parameters, made it possible to characterize each stage of the deformation. A combination of standard methods of studying electron microscopic images using the fractal theory to describe the supramolecular and phase structures of elastomers allows one to understand the mechanism of the deformation process and the nature of the structures arising in structure rearrangement.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. O. V. Gorshkova, A. E. Chalykh, V. K. Gerasimov, V. V. Matveev, Prot. Met., 2008, 44, 624.

    Article  CAS  Google Scholar 

  2. A. E. Chalykh, O. V. Gorshkova, V. K. Gerasimov, V. V. Matveev, Int. Polym. Sci. Technol., 2018, 45, 138.

    Google Scholar 

  3. A. E. Chalykh, O. V. Gorshkova, V. K. Gerasimov, V. V. Matveev, Int. Polym. Sci. Technol., 2018, 45, 144.

    Google Scholar 

  4. O. V. Gorshkova, A. E. Chalykh, V. K. Gerasimov, V. V. Matveev, Nelineinyi mir [Nonlinear World], 2009, 7, 772 (in Russian).

    Google Scholar 

  5. V. I. Roldugin, in Sovremennye problemy fizicheskoi khimii [Modern Problems of Physical Chemistry], Granitsa, Moscow, 2005, p. 137 (in Russian).

    Google Scholar 

  6. V. I. Roldugin, Fizikokhimiya poverkhnosti [Physicochemistry of Surface], Intellekt, Dolgoprudnyi, 2008, 568 pp. (in Russian).

    Google Scholar 

  7. Ph. H. Geil, Polymer Single Crystals, Wiley, New York, 1963, 560 pp.

    Google Scholar 

  8. M. F. Bukhina, Tekhnicheskaya fizika elastomerov [Technical Physics of Elastomers], Khimiya, Moscow, 1984, 224 pp. (in Russian).

    Google Scholar 

  9. G. M. Bartenev, A. G. Barteneva, Relaksatsionnye svoistva polimerov [Relaxation Properties of Polymers], Khimiya, Moscow, 1992, 384 pp. (in Russian).

    Google Scholar 

  10. M. A. Martynov, K. A. Velegzhanina, Rentgenografiya polimerov [Radiography of Polymers], Khimiya, Leningrad, 1972, 93 pp. (in Russian).

    Google Scholar 

  11. GOST R 568000-2015 “Komposity polimernye. Opredelenie mekhanicheskikh svoistv pri rastyazhenii nearmirovannykh i armirovannykh materialov” [Standards R 568000-2015 “Polymeric Composites. Determination of Mechanical Properties on Stretching of Non-reinforced and Reinforced Materials’] (in Russian).

  12. G. Schimmel, Elektronenmikroskopisch e Metodik [Procedures of Electron Microscopy], Springer, Berlin, 1969 (in German).

    Google Scholar 

  13. V. E. Gul’, V. N. Kuleznev, Struktura i mekhanicheskie svoistva polimerov [Structure and Mechanical Properties of Polymers], Labirint, Moscow, 1994, 367 pp. (in Russian).

    Google Scholar 

  14. S. M. Aharoni, Polymer, 1978, 19, 401.

    CAS  Google Scholar 

  15. V. A. Marikhin, L. P. Myasnikova, Nadmolekulyarnaya struktura polimerov [Supramolecular Structure of Polymers], Khimiya, Leningrad, 1977, 240 pp. (in Russian).

    Google Scholar 

  16. A. L. Volynskii, N. F. Bakeev, Rol’poverkhnostnykh yavlenii v strukturno-mekhanicheskom povedenii tverdykh polimerov [The Role of Surface Phenomena in the Structural Mechanical Behavior of Solid Polymers], Fizmatlit, Moscow, 2014, p. 336 (in Russian).

    Google Scholar 

  17. B. Wunderlich, Macromolecular Physics. Crystal Nucliation. Grouth. Annealing, Academic Press, New York, 1976, 573 pp.

    Google Scholar 

  18. S. A. Saltykov, Stereometricheskaya metallografiya [Stereometric Metallography], Metallurgiya, Moscow, 1976, 270 pp. (in Russian).

    Google Scholar 

  19. B. B. Mandelbrot, Fractal: Form, Chance, and Dimension, Freeman, San Francisco, 1977, 365 pp.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. F. Petrova.

Additional information

The study was carried out using the equipment of the Center for Collective Use at the A. N. Frumkin Institute of Physical Chemistry and Electrochemistry (Russian Academy of Sciences).

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-03-00722).

Russian Chemical Bulletin, International Edition, Vol. 69, No. 10, pp. 1859–1864, October, 2020

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1859–1864, October, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chalykh, A.E., Petrova, T.F., Gerasimov, V.K. et al. Parameterization of the structures arising in the deformation of elastomers. Russ Chem Bull 69, 1859–1864 (2020). https://doi.org/10.1007/s11172-020-2970-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-020-2970-9

Key words

Navigation