Abstract
This study aims at synthesizing alkyd resins from rubber seed oil (RSO), soybean oil (SBO), and their blends via the monoglyceride route. Oil extracted from rubber seeds was blended with soybean oil at various blending ratios (80:20, 70:30, 50:50, 30:70, and 10:90). Thereafter, the blends were employed in the synthesis of polyesters (alkyd resins) via alcoholysis technique. The alkyd samples synthesized from the RSO, SBO, and their respective blends were characterized for comparative purpose. The RSO-/SBO-based alkyds and aforementioned blends have iodine values of 157.90/142.00, 152.44, 149.90, 143.16, 142.26, and 142.41 gI2/100 g and saponification values of 216.21/228.61, 203.67, 171.04, 161.97, 142.89, and 135.62 mgKOH/g, respectively. The drying property (set-to-touch time and the tack free) of the 100% RSO-based alkyd resin did not experience any significant improvement as the blending proportion of SBO in RSO increases. The tack-free and dry-through times for the blends were estimated to be around 129–133 and 236–243 min, respectively. Huggins and Kraemer viscosity relationship was used to extrapolate the intrinsic viscosities of the RSO- and SBO-based alkyds and their corresponding blends. The blends showed resistance to brine, water, and acid. However, only some exhibited fair resistance to alkali. The results from the investigation revealed that the alkyds prepared using a blend of RSO/SBO oil possess coating properties whose values are comparable to those of commercial polyesters. However, the studied SBO cannot be considered as good blending oil with RSO for the preparation of alkyd for the improvement of drying properties.
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References
“Alkyd resins.” Kirk‐othmer Encyclopedia of Chemical Technology
Otabor, GO, Ifijen, IH, Mohammed, FU, Aigbodion, AI, Ikhuoria, EU, “Alkyd resin from rubber seed oil/linseed oil blend: A comparative study of the physiochemical properties.” Heliyon, 5 (5) e01621 (2019)
Uzoh, CF, Obele, MC, Umennabuife, UM, Onukwuli, OD, “Synthesis of rubber seed oil waterborne alkyd resin from glucitol.” Journal of Coatings Technology and Research, 16 (6) 1727–1735 (2019)
Uzoh, CF, Obodo, NJ, Onukwuli, OD, “Exploring the effect of styrene and anhydride ratio on the coating properties of non-drying vegetable oil based alkyd resin.” Journal of King Saud University - Engineering Sciences, 30 (1) 12–21 (2018)
Abd El-Ghaffar, MA, Abdelwahab, NA, Fekry, AM, Sanad, MA, Sabaa, MW, Soliman, SMA, “Polyester-epoxy resin/conducting polymer/barium sulfate hybrid composite as a smart eco-friendly anti-corrosive powder coating.” Progress in Organic Coatings, 144 105664 (2020)
Alam, M, Akram, D, Sharmin, E, Zafar, F, Ahmad, S, “Vegetable oil based eco-friendly coating materials: A review article.” Arabian Journal of Chemistry, 7 (4) 469–479 (2014)
Liang, D, Zhang, Q, Zhang, W, Liu, L, Liang, H, Quirino, RL, Chen, J, Liu, M, Lu, Q, Zhang, C, “Tunable thermo-physical performance of castor oil-based polyurethanes with tailored release of coated fertilizers.” Journal of Cleaner Production, 210 1207–1215 (2019)
Lligadas, G, Ronda, JC, Galià, M, Cádiz, V, “Renewable polymeric materials from vegetable oils: A perspective.” Materials Today, 16 (9) 337–343 (2013)
Selim, MS, Shenashen, MA, Hashem, AI, El-Safty, SA, “Linseed oil-based alkyd/Cu2O nanocomposite coatings for surface applications.” New Journal of Chemistry, 42 (12) 10048–10058 (2018)
Su, YLH, Zhang, S, Yang, Z, Yuan, T, “One-step synthesis of novel renewable vegetable oil-based acrylate prepolymers and their application in UV-curable coatings.” Polymers, 12 1165 (2020)
Gogoi, P, Boruah, M, Sharma, S, Dolui, SK, “Blends of epoxidized alkyd resins based on jatropha oil and the epoxidized oil cured with aqueous citric acid solution: A green technology approach.” ACS Sustainable Chemistry & Engineering, 3 (2) 261–268 (2015)
Sivaphol, P, Onusa, S, Pitt, S, “Alkyd printing inks from waste frying oil.” Walailak Journal of Science and Technology (WJST), 18 (0) (2019)
Maliki, M, Ifijen, IH, “Extraction and characterization of rubber seed oil.” International Journal of Scientific Engineering and Science, 4 (6) 24–27 (2020)
Zhang, CGT, Madbouly, SA, Kessler, MR, “Recent advances in vegetable oil-based polymers and their composites.” Progress in Polymer Science, 71 91–143 (2017)
George, K, Reghu, C, Nehru, C, “By products and ancillary source of income.” In: Natural Rubber Agromanagement and Crop Processing. Rubber Research Institute of India, Kottayam, 509–520 (2000)
Iyayi, AF, Akpaka, PO, Ukpeoyibo, U, “Rubber seed processing for value-added latex production in Nigeria.” African Journal of Agricultural Research, 3 (7) 505–509 (2008)
Das, P, Sharma, N, Puzari, A, Kakati, DK, Devi, N, “Synthesis and characterization of neem (Azadirachta indica) seed oil-based alkyd resins for efficient anticorrosive coating application.” Polymer Bulletin (2020)
Aigbodion, AI, Pillai, CKS, “Preparation, analysis and applications of rubber seed oil and its derivatives in surface coatings.” Progress in Organic Coatings, 38 (3) 187–192 (2000)
Aigbodion, AI, Pillai, CKS, “Synthesis and molecular weight characterization of rubber seed oil-modified alkyd resins.” Journal of Applied Polymer Science, 79 (13) 2431–2438 (2001)
Malik, M, Ikhuoria, EU, Ifijen, IH, “Extraction and physiochemical characterization of oils obtained from selected under-utilized oil-bearing seeds in Nigeria, Publication of Chemical Society of Nigeria, Kano Chapter.” ChemSearch Journal 11 (1) 110–117 (2020)
Arminger, B, Jaxel, J, Bacher, M, Gindl-Altmutter, W, Hansmann, C, “On the drying behavior of natural oils used for solid wood finishing.” Progress in Organic Coatings, 148 (105831) (2020)
Chiplunkar, PP, Shinde, VV, Pratap, AP, “Synthesis and application of palm fatty acid distillate based alkyd resin in liquid detergent.” Journal of Surfactants and Detergents, 20 (1) 137–149 (2017)
Uzoh, CF, Onukwuli, OD, “Optimal prediction of PKS: RSO modified alkyd resin polycondensation process using discrete-delayed observations, ANN and RSM-GA techniques.” Journal of Coatings Technology and Research, 14 (3) 607–620 (2017)
Hulsbosch, J, Claes, L, Jonckheere, D, Mestach, D, De Vos, DE, “Synthesis and characterisation of alkyd resins with glutamic acid-based monomers.” Royal Society of Chemistry Advances, 8 (15) 8220–8227 (2018)
Mutar, MA, Hassan, NMA, “Synthesis and characterization of new alkyd resins (short, medium and long) based on sunflower oil and linoleic acid as binder for paints.” International Journal of Chemical and Petrochemical Technology, 7 (1) 1–16 (2017)
Isaac, IO, Nsi, EW, “Influence of polybasic acid type on the physicochemical and viscosity properties of cottonseed oil alkyd resins.” International Journal of Engineering and Science, 2 (5) 1–14 (2013)
Mizutani, T, Arai, K, Miyamoto, M, Kimura, Y, “Application of silica-containing nano-composite emulsion to wall paint: A new environmentally safe paint of high performance.” Progress in Organic Coatings, 55 (3) 276–283 (2006)
Nkwor, AN, Ukoha, PO, “Evaluation of the leather fatliquoring potential of sulphonated Afzelia africana aril cap oil.” Heliyon, 6 (1) e03009 (2020)
Nkwor, AN, Ukoha, PO, Wise, WR, Nwaji, NN, Flowers, K, “Fatty acid profile and production of fatliquor from Canarium schweinfurthii mesocarp oil.” Pertanika Journal of Science and Technology, 27 (4) 2221–2243 (2019)
Ma, Y, Lei, R, Jiang, Y, “Synthesis and characteristics of Zanthoxylum bungeanum seed oil-based alkyd resin modified by epoxy resin and their blends with HMMM.” Polymer Bulletin 77 4697–4711 (2019)
Ikhuoria, EU, Maliki, M, Okieimen, FE, Aigbodion, AI, Obaze, EO, Bakare, IO, “Synthesis and characterisation of chlorinated rubber seed oil alkyd resins.” Progress in Organic Coatings, 59 (2) 134–137 (2007)
Ikhuoria, EU, Aigbodion, AI, “Determination of solution viscosity characteristics of rubber seed oil based alkyds resins.” Journal of Applied Polymer Science, 101 (3073–3075) (2006)
Hudson, K, “Soybean oil-quality variants identified by large-scale mutagenesis.” International Journal of Agronomy, 2012 (569817) (2012)
Anang, MA, Oteng-Peprah, M, Opoku-Boadu, K, “Extraction and characterisation of african star apple (Chrysophyllum albidum) seed oil and the adsorptive properties of the fruit shell in Ghana.” (2019) http://europepmc.org/abstract/MED/31058182
Milovanović, M, Pićurić-Jovanović, K, “Characteristics and composition of melon seed oil.” Journal of Agricultural Sciences, 50 (1) 41–47 (2005)
Zahir, E, Saeed, R, Hameed, MA, Yousuf, A, “Study of physicochemical properties of edible oil and evaluation of frying oil quality by fourier transform-infrared (FT-IR) spectroscopy.” Arabian Journal of Chemistry, 10 S3870–S3876 (2017)
Atasie, VN, Akinhanmi, TF, “Extraction, compositional studies and physico-chemical characteristics of palm kernel oil.” Pakistan Journal of Nutrition, 8 800–803 (2009)
Ghani, NAA, Channip, A-A, Chok HHP, Ja’afar F, Yasin HM, Usman A, “Physicochemical properties, antioxidant capacities, and metal contents of virgin coconut oil produced by wet and dry processes.” Food. Sci. Nutr., 6 (5) 1298–1306 (2018)
Ibeto, CN, Okoye, COB, Ofoefule, AU, “Comparative study of the physicochemical characterization of some oils as potential feedstock for biodiesel production.” ISRN Renewable Energy, 2012 (621518) (2012)
Singh, G, Jeyaseelan, C, Bandyopadhyay, KK, Paul, D, “Comparative analysis of biodiesel produced by acidic transesterification of lipid extracted from oleaginous yeast Rhodosporidium toruloides.” 3 Biotech 8 (10) 434 (2018)
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Ifijen, I.H., Odi, H.D., Maliki, M. et al. Correlative studies on the properties of rubber seed and soybean oil-based alkyd resins and their blends. J Coat Technol Res 18, 459–467 (2021). https://doi.org/10.1007/s11998-020-00416-2
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DOI: https://doi.org/10.1007/s11998-020-00416-2