Skip to main content
Log in

Hydrogels Based on Cross-Linked Cationic Cellulose Derivatives

  • Published:
Chemistry of Natural Compounds Aims and scope

Cationization of wood and cotton celluloses using 3-chloro-2-hydroxypropyltrimethylammonium chloride in aqueous suspensions in the presence of various amounts of NaOH followed by cross-linking with epichlorohydrin was studied in detail. The compositions of the cationic cellulose ethers and the reaction efficiency depended strongly on the ratio of the alkylating mixture components. The physicochemical properties of the synthesized samples were studied using chemical analysis, IR spectroscopy, X-ray structure analysis, and centrifugation to determine water absorption. The content of cationic groups and concentration of cationic cellulose in the epichlorohydrin cross-linking stage had decisive effects on the degree of swelling in water and aqueous NaCl solution of the cross-linked cationic cotton and wood celluloses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

References

  1. S. M. Butrim, T. D. Bil’dukevich, N. S. Butrim, and T. L. Yurkshtovich, Chem. Nat. Compd., 47, 185 (2011).

    Article  CAS  Google Scholar 

  2. S. M. Butrim, T. D. Bil’dukevich, N. S. Butrim, and T. L. Yurkshtovich, Chem. Nat. Compd., 43, 302 (2007).

    Article  CAS  Google Scholar 

  3. D. M. Suflet, I. Popescu, and I. M. Pelin, Cellul. Chem. Technol., 51, 23 (2017).

    CAS  Google Scholar 

  4. X. Shen, J. L. Shamshina, P. Berton, G. Gurau, and R. D. Rogers, Green Chem., 18, 53 (2016).

    Article  Google Scholar 

  5. H. Kono and S. Fujita, Carbohydr. Polym., 87, 2582 (2012).

    Article  CAS  Google Scholar 

  6. S. M. Butrim, T. D. Bil’dukevich, N. S. Butrim, and T. L. Yurkshtovich, Colloid J., 78, 310 (2016).

    Article  CAS  Google Scholar 

  7. D. B. Solarek, in: Modified Starches: Properties and Uses, O. B. Wurzburg (ed.), CRC Press, Inc., Boca Raton, Florida, 1986, p. 113.

  8. L. Yan, Q. Shuai, X. Gong, Q. Gu, and H. Yu, Clean: Soil, Air, Water, 37, 392 (2009).

    CAS  Google Scholar 

  9. J. Houben and T. Weyl, Methoden der organische Chemie, G. Thieme Verlag, Stuttgart [Russian translation, Khimiya, Moscow, 1967, 1032 pp].

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. M. Butrim.

Additional information

Translated from Khimiya Prirodnykh Soedinenii, No. 6, November–December, 2020, pp. 949–952.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Butrim, S.M., Bil’dyukevich, T.D., Butrim, N.S. et al. Hydrogels Based on Cross-Linked Cationic Cellulose Derivatives. Chem Nat Compd 56, 1106–1110 (2020). https://doi.org/10.1007/s10600-020-03237-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10600-020-03237-2

Keywords

Navigation