Abstract
The use of electric arc furnaces is important in steelmaking, notably to recycle scrap steel, yet arc furnace is an unintentional source of persistent organic pollutants (POPs) such as chlorinated dioxins and furans (PCDD/Fs), dioxin-like polychlorinated biphenyls (dl-PCBs) and brominated dioxins and furans (PBDD/Fs). Here, we review the level, profiles, influencing factors and formation mechanisms of such pollutants from arc furnaces of steelmaking plants. Comparison of various industrial sources shows that pollutant concentrations in the stack gas from the arc furnace in steelmaking plants are lower than that in the fly ash of all industrial sources. Preheating the scrap steel could increase the formation and emission of pollutants. The composition of raw materials is suggested to be an important influencing factor in pollutant formation. Air pollution control devices significantly reduce emissions of pollutants.
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References
Ali H, Khan E (2016) Environmental chemistry in the twenty-first century. Environ Chem Lett 15:329–346. https://doi.org/10.1007/s10311-016-0601-3
Antunes P, Viana P, Vinhas T, Rivera J, Gaspar EMSM (2012) Emission profiles of polychlorinated dibenzodioxins, polychlorinated dibenzofurans (PCDD/Fs), dioxin-like PCBs and hexachlorobenzene (HCB) from secondary metallurgy industries in Portugal. Chemosphere 88:1332–1339. https://doi.org/10.1016/j.chemosphere.2012.05.032
Aresta M, Dibenedetto A, Fragale C, Pastore T (2004) High-energy milling to decontaminate soils polluted by polychlorobiphenyls and atrazine. Environ Chem Lett 2:1–4. https://doi.org/10.1007/s10311-003-0057-0
Aries E, Anderson DR, Fisher R (2008) Exposure assessment of workers to airborne PCDD/Fs, PCBs and PAHs at an electric arc furnace steelmaking plant in the UK. Ann Occup Hyg 52:213–225. https://doi.org/10.1093/annhyg/men011
Arion A, Flormond P, Berho F, Marliere E, Louer LP (2002) Investigation of dioxin formation mechanisms under sintering conditions by use of pilot plant. Organohalogen Compd 56:127–130
Association W (2017). World steel in figures 2016, https://www.worldsteel.org.
Association W (2019). World steel in figures 2018, https://www.worldsteel.org.
Association W (2020). World steel in figures 2019, https://www.worldsteel.org.
Birat JP, Arion A, Faral M, Baronnet F, Marquaire PM, Rambaud P (2001) Réduction des émissions de produits organiques dans les fumées de four électrique à arc Revue de Metallurgie. Cahiers D’Informations Tech 98:839–854. https://doi.org/10.1051/metal:2001132
Björklund J, Tollbäck P, HiäRne C, Dyremark E, Stman C (2004) Influence of the injection technique and the column system on gas chromatographic determination of polybrominated diphenyl ethers. J Chromatogr A 1041:201–210. https://doi.org/10.1016/j.chroma.2004.04.025
Buekens A, Stieglitz L, Hell K, Huang H, Segers P (2001) Dioxins from thermal and metallurgical processes: Recent studies for the iron and steel industry. Chemosphere 42:729–735. https://doi.org/10.1016/S0045-6535(00)00247-2
Caserini S, Monguzzi AM (2002) PCDD/Fs emissions inventory in the Lombardy region: results and uncertainties. Chemosphere 48:779–786. https://doi.org/10.1016/S0045-6535(02)00127-3
Chang MB, Huang HC, Tsai SS, Chi KH, Chang-Chien GP (2006) Evaluation of the emission characteristics of PCDD/Fs from electric arc furnaces. Chemosphere 62:1761–1773. https://doi.org/10.1016/j.chemosphere.2005.07.054
Chang MB, Lin JJ, Chang SH (2002) Characterization of dioxin emissions from two municipal solid waste incinerators in Taiwan. Atmos Environ 36:279–286
Chiu JC, Shen YH, Li HW, Lin LF, Wang LC, Chang-Chien GP (2011) Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from an electric arc furnace, secondary aluminum smelter, crematory and joss paper incinerators. Aerosol Air Qual Res 11:13–20. https://doi.org/10.4209/aaqr.2010.06.0051
Du B, Zheng M, Tian H, Liu A, Huang Y, Li L, Ba T, Li N, Ren Y, Li Y, Dong S, Su G (2010) Occurrence and characteristics of polybrominated dibenzo-p-dioxins and dibenzofurans in stack gas emissions from industrial thermal processes. Chemosphere 80:1227–1233. https://doi.org/10.1016/j.chemosphere.2010.05.044
Everaert K, Baeyens J (2002) The formation and emission of dioxins in large scale thermal processes. Chemosphere 46:439–448. https://doi.org/10.1016/S0045-6535(01)00143-6
Fisher R, Anderson D, Wilson DT, Aries E, Hemfrey D, Fray TAT (2004) Effect of chloride on the formation of PCDD/Fs and WHO-12 PCBs in iron ore sintering. Organohalogen Compd 66:1116–1122
Fostinelli J, Catalani S, Gaia A, DePalma G, Apostoli P (2017) Assessment of residual exposure to PCBs in metallurgy. Med Lav. https://doi.org/10.23749/mdl.v108i3.5907
Friedacher A, Lehner J, Gould L, Fingerhut W (2006) Reduction of dioxin/furan emissions in the waste gas from electric arc furnaces. BHM Bergund Hüttenmännische Monatshefte 151:131–136. https://doi.org/10.1007/BF03165187
Halek F, Kianpour-rad M, Kavousi A (2008) Characterization and source apportionment of polycyclic aromatic hydrocarbons in the ambient air (Tehran, Iran). Environ Chem Lett 8:39–44. https://doi.org/10.1007/s10311-008-0188-4
Hanari N, Kannan K, Miyake Y, Okazawa T, Kodavanti PRS, Aldous KM, Yamashita N (2006) Occurrence of polybrominated biphenyls, polybrominated dibenzo-p-dioxins, and polybrominated dibenzofurans as impurities in commercial polybrominated diphenyl ether mixtures. Environ Sci Technol 40:4400–4405. https://doi.org/10.1021/es060559k
Huang H, Buekens A (1995) On the mechanisms of dioxin formation in combustion processes. Chemosphere 31:4099–4117. https://doi.org/10.1016/0045-6535(95)80011-9
Iino F, Imagawa T, Takeuchi M, Sadakata M (1999) De novo synthesis mechanism of polychlorinated dibenzofurans from polycyclic aromatic hydrocarbons and the characteristic isomers of polychlorinated naphthalenes. Environ Sci Technol 33:1038–1043. https://doi.org/10.1021/es980857k
IPPC 2001 Best available techniques reference document on the production of iron and steel Seville, Spain European Commission, Integrated Pollution Prevention and Control (IPPC)
IPPC, 2010. European Commission, Integrated Pollution Prevention and Control (IPPC), Best available techniques reference document for production of iron and steel
Kanan S, Samara F (2018) Dioxins and furans: A review from chemical and environmental perspectives. Trends Environ Anal Chem 17:1–13. https://doi.org/10.1016/j.teac.2017.12.001
Krishnaraj R (2015) Control of pollution emitted by foundries. Environ Chem Lett 13:149–156. https://doi.org/10.1007/s10311-015-0500-z
Kulkarni PS, Crespo JG, Afonso CAM (2008) Dioxins sources and current remediation technologies - A review. Environ Int 34:139–153. https://doi.org/10.1016/j.envint.2007.07.009
Lee CC, Shih TS, Chen HL (2009) Distribution of air and serum PCDD/F levels of electric arc furnaces and secondary aluminum and copper smelters. J Hazard Mater 172:1351–1356. https://doi.org/10.1016/j.jhazmat.2009.07.148
Lee WS, Chang-Chien GP, Wang LC, Lee WJ, Tsai PJ, Wu KY, Lin C (2004) Source identification of PCDD/Fs for various atmospheric environments in a highly industrialized city. Environ Sci Technol 38:4937–4944. https://doi.org/10.1021/es0499795
Lee WS, Chang-Chien GP, Wang LC, Lee WJ, Wu KY, Tsai PJ (2005) Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from stack gases of electric arc furnaces and secondary aluminum smelters. J Air Waste Manage Assoc 55:219–226. https://doi.org/10.1080/10473289.2005.10464613
Li HW, Lee WJ, Tsai PJ, Mou JL, Chang-Chien GP, Yang KT (2008) A novel method to enhance polychlorinated dibenzo-p-dioxins and dibenzofurans removal by adding bio-solution in EAF dust treatment plant. J Hazard Mater 150:83–91. https://doi.org/10.1016/j.jhazmat.2007.04.077
Li HW, Wu YL, Lee WJ, Chang-Chien GP (2007) Fate of polychlorinated dibenzo-p-dioxins and dibenzofurans in a fly ash treatment plant. J Air Waste Manag Assoc 57:1024–1031. https://doi.org/10.3155/1047-3289.57.9.1024
Li S, Zheng M, Liu W, Liu G, Xiao K, Li C (2014) Estimation and characterization of unintentionally produced persistent organic pollutant emission from converter steelmaking processes. Environ Sci Pollut Res 21:7361–7368. https://doi.org/10.1007/s11356-014-2652-y
Li Y, Yang Y, Yu G, Huang J, Wang B, Deng S, Wang Y (2016) Emission of unintentionally produced persistent organic pollutants (UPOPs) from municipal waste incinerators in China. Chemosphere 158:17–23. https://doi.org/10.1016/j.chemosphere.2016.05.037
Liu G, Zheng M, Cai M, Nie Z, Zhang B, Liu W, Du B, Dong S, Hu J, Xiao K (2013) Atmospheric emission of polychlorinated biphenyls from multiple industrial thermal processes. Chemosphere 90:2453–2460. https://doi.org/10.1016/j.chemosphere.2012.11.008
Liu G, Zheng M, Du B, Nie Z, Zhang B, Hu J, Xiao K (2012) Identification and characterization of the atmospheric emission of polychlorinated naphthalenes from electric arc furnaces. Environ Sci Pollut Res 19:3645–3650. https://doi.org/10.1007/s11356-012-1038-2
Liu G, Zheng M, Liu W, Wang C, Zhang B, Gao L, Su G, Xiao KE, Lv P (2009) Atmospheric emission of PCDD/Fs, PCBs, hexachlorobenzene, and pentachlorobenzene from the coking industry. Environ Sci Technol 43:9196–9201. https://doi.org/10.1021/es902429m
Lv P, Zheng M, Liu G, Liu W, Xiao K (2011) Estimation and characterization of PCDD/Fs and dioxin-like PCBs from Chinese iron foundries. Chemosphere 82:759–763. https://doi.org/10.1016/j.chemosphere.2010.10.077
Tysklind M, Söderström G, Rappe C, Hägerstedt L-E, Burström E (1989) PCDD and PCDF emissions from scrap metal melting processes at a steel mill. Chemosphere 19:705–710. https://doi.org/10.1016/0045-6535(89)90394-9
Madias J (2016) Electric Arc Furnace. In Ironmaking and Steelmaking Processes, Springer, Cham
Murakami T, Shimura M, Kasai E (2008). Effect of temperature and atmosphere on emission behavior of hexachlorobenzene from electric arc furnace dust. Proceedings ICS 2008: The 4th international congress on the science and technology of steelmaking, Doi: https://doi.org/10.1021/es8011645
Nanda S, Berruti F (2020) Municipal solid waste management and landfilling technologies: a review. Environ Chem Lett. https://doi.org/10.1007/s10311-020-01100-y
Nguyen MIUE, Go S, Shin T, Tomohiko I, Pham TKT, Pham HV, Shinsuke T (2010) Evaluation of dioxin-like activities in settled house dust from Vietnamese e-waste recycling sites: relevance of Polychlorinated/Brominated Dibenzo-p-Dioxin/Furans and Dioxin-like PCRs. Environ Sci Technol 44:9195–9200. https://doi.org/10.1021/es102505j
Ni Y, Zhang H, Fan S, Zhang X, Zhang Q, Chen J (2009) Emissions of PCDD/Fs from municipal solid waste incinerators in China. Chemosphere 75:1153–1158. https://doi.org/10.1016/j.chemosphere.2009.02.051
Nie Z, Zheng M, Liu W, Zhang B, Liu G, Su G, Lv P, Xiao K (2011) Estimation and characterization of PCDD/Fs, dl-PCBs, Polychlorinated naphthalenes, Hexachlorobenzene and PeCBz emissions from magnesium metallurgy facilities in China. Chemosphere 85:1707–1712. https://doi.org/10.1016/j.chemosphere.2011.09.016
Noma Y, Yamamoto T, Sakai S-i (2004) Congener-specific composition of and Dibenzofurans in the Halowax Series. Environ Sci Technol 38:1675–1680. https://doi.org/10.1021/es035101m
Öberg T (2007) Low-temperature formation and degradation of chlorinated benzenes, PCDD and PCDF in dust from steel production. Sci Total Environ 382:153–158. https://doi.org/10.1016/j.scitotenv.2007.03.015
Odabasi M, Bayram A, Elbir T, Seyfioglu R, Dumanoglu Y, Bozlaker A, Demircioglu H, Altiok H, Yatkin S, Cetin B (2009) Electric arc furnaces for steel-making: Hot spots for persistent organic pollutants. Environ Sci Technol 43:5205–5211. https://doi.org/10.1021/es900863s
Odabasi M, Dumanoglu Y, Kara M, Altiok H, Elbir T, Bayram A (2017) Polychlorinated naphthalene (PCN) emissions from scrap processing steel plants with electric-arc furnaces. Sci Total Environ 574:1305–1312. https://doi.org/10.1016/j.scitotenv.2016.08.028
Onodera J, Ueda Y, Choi J-W, Hashimoto S, Suzuki N, Morita M, Sato H (2003) Study of thermal decomposition at a GC injector in an analysis of PBDDs/PBDFs by high-resolution GC/MS. Bunseki Kagaku 52:505–512. https://doi.org/10.2116/bunsekikagaku.52.505
Pandelova M, Lenoir D, Schramm KW (2006) Correlation between PCDD/F, PCB and PCBz in coal/waste combustion. Influ Var Inhib Chemosphere 62:1196–1205. https://doi.org/10.1016/j.chemosphere.2005.07.068
Pham MTN, Anh HQ, Nghiem XT, Tu BM, Dao TN, Nguyen MH (2019) Characterization of PCDD/Fs and dioxin-like PCBs in flue gas from thermal industrial processes in Vietnam: A comprehensive investigation on emission profiles and levels. Chemosphere 225:238–246. https://doi.org/10.1016/j.chemosphere.2019.03.024
Pham MTN, Hoang AQ, Nghiem XT, Tu BM, Dao TN, Vu DN (2019) Residue concentrations and profiles of PCDD/Fs in ash samples from multiple thermal industrial processes in Vietnam: Formation, emission levels, and risk assessment. Environ Sci Pollut Res 26:17719–17730. https://doi.org/10.1007/s11356-019-05015-2
Porzio GF, Colla V, Fornai B, Vannucci M, Larsson M, Stripple H (2016) Process integration analysis and some economic-environmental implications for an innovative environmentally friendly recovery and pre-treatment of steel scrap. Appl Energy 161:656–672. https://doi.org/10.1016/j.apenergy.2015.08.086
Quass U, Fermann M, Bröker G (2000). The European Dioxin Emission Inventory, Stage II. Ec.Europa.Eu 1: 55–55
Quiroz R, Popp P, Barra R (2008) Analysis of PCB levels in snow from the Aconcagua Mountain (Southern Andes) using the stir bar sorptive extraction. Environ Chem Lett 7:283–288. https://doi.org/10.1007/s10311-008-0164-z
Raccanelli S, Libralato S, Favotto M (2007) On the detoxification of benthic bivalves contaminated by POPs: insights from experimental and modelling approaches. Environ Chem Lett 6:251–258. https://doi.org/10.1007/s10311-007-0127-9
Roland W, Fukuya I, Takashi I (2001) Formation of PCDF, PCDD, PCB, and PCN in de novo synthesis from PAH: mechanistic aspects and correlation to fluidized bed incinerators. Chemosphere. https://doi.org/10.1016/S0045-6535(00)00508-7
Shukla V, Upreti DK, Patel DK, Yunus M (2012) Lichens reveal air PAH fractionation in the Himalaya. Environ Chem Lett 11:19–23. https://doi.org/10.1007/s10311-012-0372-4
Sofilić T, Jendričko J, Kovačevic Z, Ćosić M (2012) Measurement of polychlorinated dibenzo-p-dioxin and dibenzofuran emission from EAF steel making proces. Arch Metall Mater 57:811–821. https://doi.org/10.2478/V10172-012-0089-1
Srogi K (2007) Levels and congener distributions of PCDDs, PCDFs and dioxin-like PCBs in environmental and human samples: a review. Environ Chem Lett 6:1–28. https://doi.org/10.1007/s10311-007-0105-2
Standard CN (2014). Standards for pollution control on the municipal solid waste incineration
Takashi I, Chun Wai L (2001) Correlation of polychlorinated naphthalenes with polychlorinated dibenzofurans formed from waste incineration. Chemosphere. https://doi.org/10.1016/S0045-6535(00)00287-3
Turk M, Jakšić J, Vojinović Miloradov M, Klanova J (2007) Post-war levels of persistent organic pollutants (POPs) in air from Serbia determined by active and passive sampling methods. Environ Chem Lett 5:109–113. https://doi.org/10.1007/s10311-006-0091-9
UNEP (2001) United Nations Environment Programme. Thailand dioxin sampling and analysis program, Geneva
UNEP (2013) United Nations Environment Programme. Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs
Wang D, Xu X, Zheng M, Chiu CH (2002) Effect of copper chloride on the emissions of PCDD/Fs and PAHs from PVC combustion. Chemosphere 48:857–863. https://doi.org/10.1016/S0045-6535(02)00020-6
Wang JB, Hung CH, Hung CH, Chang-Chien GP (2009) Polychlorinated dibenzo-p-dioxin and dibenzofuran emissions from an industrial park clustered with metallurgical industries. J Hazard Mater 161:800–807. https://doi.org/10.1016/j.jhazmat.2008.04.026
Wang LC, Wang YF, Hsi HC, Chang-Chien GP (2010) Characterizing the emissions of polybrominated diphenyl ethers (Polybrominated diphenyl ethers) and polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) from metallurgical processes. Environ Sci Technol 44:1240–1246. https://doi.org/10.1021/es903128e
Watanabe K, Senthilkumar K, Masunaga S, Takasuga T, Iseki N, Morita M (2004) Brominated Organic Contaminants in the Liver and Egg of the Common Cormorants (Phalacrocorax carbo) from Japan. Environ Sci Technol 38:4071–4077. https://doi.org/10.1021/es0307221
Wu EMY, Wang LC, Lin SL, Chang-Chien GP (2014) Validation and characterization of persistent organic pollutant emissions from stack flue gases of an electric arc furnace by using a long-term sampling system (AMESA®). Aerosol Air Qual Res 14:185–196. https://doi.org/10.4209/aaqr.2013.09.0285
Yang GCC, Chuang TN, Huang CW (2017) Achieving zero waste of municipal incinerator fly ash by melting in electric arc furnaces while steelmaking. Waste Manag (Oxford) 62:160–168. https://doi.org/10.1016/j.wasman.2017.02.021
Yang HH, Lee WJ, Chen SJ, Lai SO (1998) PAH emission from various industrial stacks. J Hazard Mater 60:159–174. https://doi.org/10.1016/S0304-3894(98)00089-2
Yang Q, Yang L, Shen J, Yang Y, Wang M, Liu X, Shen X, Li C, Xu J, Li F, Li D, Liu G, Zheng M (2020) Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) emissions from electric arc furnaces for steelmaking. Emerg Contam 6:330–336. https://doi.org/10.1016/j.emcon.2020.08.005
Yu G, Zhang Q, Huang J, Cai Z, Sui Q (2007) Capacity estimation and preliminary strategy for reducing the release of dioxins in China. Front Environ Sci Engin China 1:13–17. https://doi.org/10.1007/s11783-007-0002-8
Zacco A, Borgese L, Gianoncelli A, Struis RPWJ, Depero LE, Bontempi E (2014) Review of fly ash inertisation treatments and recycling. Environ Chem Lett 12:153–175. https://doi.org/10.1007/s10311-014-0454-6
Zhang M, Buekens A, Li X (2016) Brominated flame retardants and the formation of dioxins and furans in fires and combustion. J Hazard Mater 304:26–39. https://doi.org/10.1016/j.jhazmat.2015.10.014
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grants 21936007, 91843301 and 21777172), CAS Interdisciplinary Innovation Team (Grant JCTD-2019-03) and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2016038).
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Yang, Q., Yang, L., Shen, X. et al. Organic pollutants from electric arc furnaces in steelmaking: a review. Environ Chem Lett 19, 1509–1523 (2021). https://doi.org/10.1007/s10311-020-01128-0
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DOI: https://doi.org/10.1007/s10311-020-01128-0