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Enhancement of Anticorrosion Properties of Epoxy Based Primer Coating by Bis[[3,4-Dihydroxyphenylmethylene] carbonothioicdihydrazide] on AA2024-T3 Alloy

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Abstract

A corrosion inhibitor bis[[3,4-dihydroxyphenylmethylene]carbonothioicdihydrazide] (DCT) was synthesized and used to improve the corrosion resistance of an epoxy based primer coating on AA2024-T3 alloy in NaCl solution. The ability of DCT to inhibit the corrosion was evaluated by electrochemical studies. The compound exhibited an inhibition efficiency of 99%. The surfaces of the corroded specimens were characterized by field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The anticorrosion nature of the substrate coated with a commercial epoxy-based primer doped with DCT was evaluated by electrochemical impedance spectroscopy and a salt spray test. The results established not only the ability of DCT to improve the anticorrosion property of the epoxy based primer coating on AA2024-T3 alloy but also a sustained corrosion protection (1000 h) of the alloy.

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Authors and Affiliations

  1. Department of Chemistry, National Institute of Technology Karnataka, Srinivasnagar, 575025, Surathkal, Karnataka, India

    B. G. Prakashaiah & A. Nityananda Shetty

  2. Surface Engineering Division, CSIR-National Aerospace Laboratories, Bengaluru, Karnataka, India

    B. G. Prakashaiah & B. E. Amitha Rani

Authors
  1. B. G. Prakashaiah
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  2. A. Nityananda Shetty
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Correspondence to A. Nityananda Shetty.

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Prakashaiah, B.G., Shetty, A.N. & Rani, B.E. Enhancement of Anticorrosion Properties of Epoxy Based Primer Coating by Bis[[3,4-Dihydroxyphenylmethylene] carbonothioicdihydrazide] on AA2024-T3 Alloy. Surf. Engin. Appl.Electrochem. 56, 610–623 (2020). https://doi.org/10.3103/S1068375520050129

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