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Describing the Reaction of the Hydrocarboxylation of 1-Hexene, Catalyzed by Co2(CO)8, in Marcelin–de Donde Kinetics

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

An equation is derived for calculating the rate coefficient of the 1-hexene hydrocarboxylation reaction in Marcelin–de Donde kinetics. The equation correctly describes experimental data in the range of concentrations of an unsaturated substrate, where the traditional Van’t Hoff–Arrhenius kinetics is of little use.

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REFERENCES

  1. J. Falbe, New Synthesis with Carbon Monoxide (Springer, Berlin, 1980).

    Book  Google Scholar 

  2. Yu. T. Vigranenko, S. Yu. Sukhov, and V. A. Rybakov, Russ. J. Appl. Chem. 72, 1957 (1999).

    Google Scholar 

  3. N. E. Vishnevskii, N. P. Glukhanov, and I. S. Kovalev, Machines and High-Pressure Washers with Hermetic Electric Drive (Mashinostroenie, Leningrad, 1977) [in Russian].

    Google Scholar 

  4. P. Szabo, L. Marko, and G. Bor, Chem. Rechn. 13, 549 (1961).

    CAS  Google Scholar 

  5. J. Fritz and G. Schenk, Quantitative Analytical Chemistry (Allyn and Bacon, Boston, 1974).

    Google Scholar 

  6. M. Feinberg, Arch. Rat. Met. Anal 46 (1), 1 (1972).

    Article  Google Scholar 

  7. V. I. Dimitrov, Simple Kinetics (Nauka, Novosibirsk, 1982) [in Russian].

    Google Scholar 

  8. M. Kh. Karapetyants, Chemical Thermodynamics (Khimiya, Moscow, 1975) [in Russian].

    Google Scholar 

  9. T. N. Tyvina, A. A. Kharchenko, and R. O. Pryanikova, Zh. Prikl. Khim. 50, 186 (1977).

    CAS  Google Scholar 

  10. S. M. Walas, Phase Equilibria in Chemical Technology (Butterworth-Heinemann, Boston, 1985).

    Google Scholar 

  11. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids (McGraw-Hill, New York, 1977).

    Google Scholar 

  12. S. Benson, Thermochemical Kinetics (Wiley, New York, 1968).

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State Forestry University, 194021, St. Petersburg, Russia

    Yu. T. Vigranenko, A. V. de Vekki & E. V. Koluzhnikova

  2. St. Petersburg State University of Aerospace Instrumentation, 190000, St. Petersburg, Russia

    T. E. Krylova

Authors
  1. Yu. T. Vigranenko
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  2. A. V. de Vekki
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  3. T. E. Krylova
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  4. E. V. Koluzhnikova
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Corresponding author

Correspondence to A. V. de Vekki.

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Vigranenko, Y.T., de Vekki, A.V., Krylova, T.E. et al. Describing the Reaction of the Hydrocarboxylation of 1-Hexene, Catalyzed by Co2(CO)8, in Marcelin–de Donde Kinetics. Russ. J. Phys. Chem. 94, 2209–2211 (2020). https://doi.org/10.1134/S0036024420110321

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  • DOI: https://doi.org/10.1134/S0036024420110321

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