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Synthesis and Crystal-Chemical, Thermal, and Spectrochemical Properties of the Zn2 – 2xNi2xSiO4 Solid Solution with a Willemite Structure

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

It has been found that the isomorphic capacity of the Zn2 – 2xNi2xSiO4 solid solution with a willemite structure is 15 mol % Ni. The unit cell parameters of Zn2 – 2xNi2xSiO4 samples in the homogeneity range of the solid solution are nearly independent of the content of dopant х and are close to those of undoped Zn2SiO4. It has been shown that the melting point of Zn2 – 2xNi2xSiO4 decreases with an increase in х from 1512°С for х = 0 to 1455°С for х = 0.15. The UV-Vis absorption spectrum and color coordinates of Zn2 – 2xNi2xSiO4 correspond to the blue range, and the color intensity of the pigment increases with increasing nickel content.

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Funding

The work was supported by the Russian Foundation for Basic Research, project no. 19-03-00189.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, 620990, Yekaterinburg, Russia

    I. V. Ivanova, N. A. Zaitseva, R. F. Samigullina, I. V. Baklanova & M. V. Rotermel

  2. Ural State Mining University, 620144, Yekaterinburg, Russia

    N. A. Zaitseva

Authors
  1. I. V. Ivanova
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  2. N. A. Zaitseva
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  3. R. F. Samigullina
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  4. I. V. Baklanova
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  5. M. V. Rotermel
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Corresponding author

Correspondence to N. A. Zaitseva.

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Translated by G. Kirakosyan

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Ivanova, I.V., Zaitseva, N.A., Samigullina, R.F. et al. Synthesis and Crystal-Chemical, Thermal, and Spectrochemical Properties of the Zn2 – 2xNi2xSiO4 Solid Solution with a Willemite Structure. Russ. J. Inorg. Chem. 65, 1535–1540 (2020). https://doi.org/10.1134/S0036023620100101

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