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Synthesis and Reactivity of Zirconium and Hafnium Dihydroxophthalocyaninates

  • CHEMISTRY OF MACROCYCLIC AND METALLOCYCLIC COMPOUNDS
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Abstract—

Two synthetic approaches for obtaining of zirconium and hafnium dihydroxophthalocyaninates (i.e. (a) that using the zirconium and hafnium alkoxides as the reactive precursors and (b) hydrolysis of zirconium and hafnium dichloridophthalocyaninates) were evaluated. Reactivity of zirconium and hafnium dihydroxophthalocyaninates in their exchange reactions with β-diketones and with decanoic acid was also studied; they were compared with those of zirconium and hafnium dichloridophthalocyaninates. The use of zirconium and hafnium dihydroxophthalocyaninates as the precursors in their reactions with acid-sensitive ligands, such as ketoesters, is found to be a more effective approach.

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Funding

This publication is based on work “Evaluation of phthalocyanine complexes as chaperone mimetics to prevent protein heat-induced fibrillization in the food industry“ supported by Award No. FSA3-19-65501-0 of the U.S. Civilian Research & Development Foundation (CRDF Global) and by the Ministry of Education and Science of Ukraine under Cooperative Agreement No. М/188-2019.

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Authors and Affiliations

  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kyiv, Ukraine

    V. Chernii, I. Tretyakova, R. Selin & N. Fedosova

  2. Institute of Molecular Biology and Genetics, National Academy of Sciences of Ukraine, 03143, Kyiv, Ukraine

    V. Kovalska

Authors
  1. V. Chernii
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  2. I. Tretyakova
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  3. R. Selin
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  4. N. Fedosova
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  5. V. Kovalska
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Correspondence to V. Chernii.

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Chernii, V., Tretyakova, I., Selin, R. et al. Synthesis and Reactivity of Zirconium and Hafnium Dihydroxophthalocyaninates. Russ. J. Inorg. Chem. 65, 1489–1493 (2020). https://doi.org/10.1134/S0036023620100046

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  • DOI: https://doi.org/10.1134/S0036023620100046

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