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Zinc(II) and Manganese(II) Oxalatopalladates as Precursors of Bimetallic Nanomaterials

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Abstract

The thermal properties of [{Zn(H2O)3(PdOx2)}2(μ-H2O)2] · 4H2O and {(μ-Ox)Pd(μ-Ox)Mn(H2O)3}n · nH2O have been studied in various atmospheres. Zinc forms the intermetallide ZnPd in inert (He) and reductive (H2) atmospheres and a ZnO–PdO oxide mixture in an oxidative (air) atmosphere. Manganese forms MnO–Pd mixtures in an inert atmosphere, experiences deeper oxidation to Mn3O4 in an oxidative atmosphere, and is partially reduced to form the intermetallide Mn3Pd5 in a reductive atmosphere. High catalytic activity in CO photooxidation has been discovered in the Zn-containing sample deposited onto a TiO2 substrate. The XAFS spectroscopy data for the model catalysts make it possible to assume the formation of nanosized palladium particles during the hydrogen reduction of supported precursors.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-2-00308a).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. A. Garkul’, A. V. Zadesenets, P. E. Plyusnin, E. Yu. Filatov, T. I. Asanova & S. V. Korenev

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    D. V. Kozlov

Authors
  1. I. A. Garkul’
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  2. A. V. Zadesenets
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  3. P. E. Plyusnin
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  4. E. Yu. Filatov
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  5. T. I. Asanova
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  6. D. V. Kozlov
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  7. S. V. Korenev
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Correspondence to I. A. Garkul’.

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The authors declare no conflict of interest.

ADDITIONAL INFORMATION

This paper is based on the results of the XXII International Chernyaev Conference on the Chemistry, Analysis, and Technology of Platinum Metals (Moscow, 2019, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Russian Technological University).

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Translated by E. Glushachenkova

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Garkul’, I.A., Zadesenets, A.V., Plyusnin, P.E. et al. Zinc(II) and Manganese(II) Oxalatopalladates as Precursors of Bimetallic Nanomaterials. Russ. J. Inorg. Chem. 65, 1571–1576 (2020). https://doi.org/10.1134/S003602362010006X

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