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Polyelectrolytic Gels for Stabilizing Sand Soil against Wind Erosion

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Abstract

Interpolyelectrolyte complexes of a linear cationic polymer poly(diallyldimethylammonium chloride) and anionic microgel particles with carboxyl groups in a pH 6 buffer solution are presented. Dispersions of the microgel and its complexes—negatively charged with a 3-fold molar excess of the anionic groups of the microgel and positively charged with a 3-fold molar excess of the cationic groups of the polycation—retain aggregative stability for six months. When applying 1 wt % dispersions of the microgel and complex on the surface of the soil with a high sand content, polymer-soil coatings with a mechanical strength of 19 to 61 kg/m2 depending on the composition of the dispersion are formed. These indicators significantly exceed those for coatings obtained by applying a 1 wt % solution of a linear anionic polymer, poly(acrylic acid), on the soil surface. Coatings involving microgel and its complexes remain stable at an air flow rate of 190 km/h.

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ACKNOWLEDGMENTS

We are grateful to the University of Tsukuba and Professor Usuyama Toshinob for financial support in the form of the JASSO exchange scholarship.

Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-29-05036) and the JSPS KAKENHI program (project 16H06382).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    I. G. Panova, L. O. Ilyasov & A. A. Yaroslavov

  2. Faculty of Soil Science, Moscow State University, 119991, Moscow, Russia

    D. D. Khaidapova

  3. Faculty of Life and Environmental Sciences, University of Tsukuba, 1-1-1, 305-8572, Tennodai, Tsukuba, Ibaraki, Japan

    K. Ogawa & Y. Adachi

Authors
  1. I. G. Panova
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  2. L. O. Ilyasov
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  3. D. D. Khaidapova
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  4. K. Ogawa
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  5. Y. Adachi
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  6. A. A. Yaroslavov
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Correspondence to I. G. Panova.

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Panova, I.G., Ilyasov, L.O., Khaidapova, D.D. et al. Polyelectrolytic Gels for Stabilizing Sand Soil against Wind Erosion. Polym. Sci. Ser. B 62, 491–498 (2020). https://doi.org/10.1134/S1560090420050103

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  • DOI: https://doi.org/10.1134/S1560090420050103

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