Abstract
In this work, Zn2W hexaferrite was prepared by sol–gel (SG) and solid-state reaction (SSR) methods. The dependency of the microstructure, magnetic, and electromagnetic properties of the obtained Zn2W hexaferrite on the two different preparation methods and the sintering temperature was investigated. First, single-phase Zn2W hexaferrite was obtained by the SG method at sintering temperatures higher than 1250 °C, but this was not the case with the SSR method. Second, the Zn2W hexaferrite prepared by the SG method had a larger grain size than those prepared by the SSR method under the same sintering conditions due to the higher activity of the obtained nanosized precursor powder. Third, the saturation magnetization obtained the highest value herein of 77.48 emu/g from the Zn2W hexaferrite prepared by the SG method sintered at 1250 °C, which is higher than the value of 72.49 emu/g from the Zn2W hexaferrite prepared by the SSR method sintered at 1300 °C. Finally, the values of reflection losses reached a maximum of 22.4 dB at 17.0 GHz with the bandwidth of 0.87 GHz over 10 and 29.5 dB at 17.9 GHz with around the bandwidth of 1.38 GHz for the hexaferrite prepared by the SG method and SSR methods, respectively, which meets the absorption requirement for high-frequency microwave applications.
Highlights
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The excellent microwave material Zn2W(BaZn2Fe16O27) with single phase are obtained successfully.
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Comparison of microstructure, phase purity and magnetic properties of samples prepared by sol-gel and solid-state reaction methods.
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The obatained samples has important applications in high frequency with excellent electromagnetic and absorbing properties.
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References
Waqar M, Rafiq MA, Mirza TA, Khalid FA et al. (2018) Synthesis and properties of nickel-doped nanocrystalline barium hexaferrite ceramic materials. Appl Phys A-Mater 124:286
Kimura T (2012) Magnetoelectric Hexaferrites. Annu Rev Condens Matter Phys 3:93–110
Sun R, Li X, Xia A, Su S (2018) Hexagonal SrFe12O19 ferrite with high saturation magnetization. Ceram Int 44:13551–13555
Yang P, Zhao WH, Wang GY, Feng YB (2018) Investigation of microstructure and electromagnetism of plate-like Co2W ferrites synthesized by the molten salt/co-precipitation method. J Mater Sci-Mater Electron 30:892–901
Lee W, Hong YK, Choi M, Won H et al. (2018) Figure of Merit of X-type Hexaferrite (Ba2Co2Fe28O46) for Mobile Antenna Applications. Micro Opt Technol Lett 60:795–799
Daigle A, Dupre E, Geiler A, Chen YJ, Parimi PV et al. (2010) Preparation and characterization of pure-phase Co2Y ferrite powders via a scalable aqueous coprecipitation method. J Am Ceram Soc 93:2994–2997
Gang X, Wei GB, Yang XJ, Lu LD, Wang X (2000) Characterization and size-dependent magnetic properties of Ba3Co2Fe24O41 nanocrystals synthesized through a sol-gel method. J Mater Sci 35:931–936
Ahmad M, Grössinger R, Kriegisch M, Kubel F, Rana MU (2012) Magnetic and microwave attenuation behavior of Al-substituted Co2W hexaferrites synthesized by sol-gel autocombustion process. Curr Appl Phys 12:1413–1420
Zhang J, Wang LX, Huang XG (2014) Electromagnetic properties of BaZn2Fe16O27/antimony-doped tin oxide composite absorbing materials by co-precipitation method. Rare Met 33:697–702
Zeyde KM, Gudkova SA, Vinnik DA (2017) Investigation of barium hexaferrite BaFe12O19 electro physical parameters using open-ended coaxial probe method. Solid State Phenom 265:834–838
Lim ES, Mun KR, Kang YM (2018) Effect of Bi2O3, MnCO3 additives on the structure and magnetic roperties of M-type Sr-hexaferrites. J Magn Magn Mater 464:26–30
Liu JJ, Zhang P, Zhang XK, Xie QQ, Pan DJ, Zhang J, Zhang M (2015) Synthesis and microwave absorbing properties of La-doped Sr-hexaferrite nanopowders via sol–gel auto-combustion method. Rare Met 36:704–710
Rahul S, Agarwala RC, Agarwala V (2007) A study on the heat-treatments of nanocrystalline nickel substituted BaW hexaferrite produced by low combustion synthesis method. J Magn Magn Mater 312:117–125
Ghasemi A (2015) Stoner-Wohlfarth rotation or domain wall motion mechanism in W-type magnetic hexaferrite nanoparticles. Ceram Int 42:4143–4149
Rana K, Thakur P, Tomar M, Gupta V, Thakur A (2018) Investigation of cobalt substituted M-type barium ferrite synthesized via co-precipitation method for radar absorbing material in Ku-band (12–18GHz). Ceram Int 44:6370–6375
Drofenik M, Kristl M, Žistlnik A, Hanžel D, Lisjak D (2007) Hydrothermal synthesis of Ba-hexaferrite nanoparticles. J Am Ceram Soc 90:2057–2061
Yang L, Xia A, Jin C (2016) Synthesis, structure and magnetic properties of hexagonal BaFe12O19 ferrite obtained via a hydrothermal method. J Mater Sci: Mater Electron 27:10864–10868
Hooda A, Sanghi S, Agarwal A, Dahiya R (2014) Structural, dielectric and magnetic properties of Cd/Pb doped W-type hexaferrites. J Magn Magn Mater 349:121–127
Abo EAAM, El Nimr MK, El Kony D et al. (1999) Dielectric and magnetic permeability behavior of BaCo2-xNixFe16O27 W-type hexaferrites. J Magn Magn Mater 204:36–44
Ahmad M, Ali I, Aen F, Islam MU, Ashiq MN, Atiq S, Ahmad W, Rnan MU (2012) Effect of sintering temperature on magnetic and electrical properties of nanosized Co2W hexaferrites. Ceram Int 38:1267–1273
Aen F, Wasiq MF, Rana MU, Khan HM, Khan MA (2016) Structural and electrical behavior evaluation of Ho-substituted Co2W hexagonal ferrites. Ceram Int 42:16077–16083
Wang GY, Feng YB, Qiu T, Xu JF, Chen SN (2015) Structural, magnetic and electromagnetic properties of plate-like Zn2W barium hexagonal ferrites prepared by co-precipitation/molten salt method. Ceram Int 41:14087–14093
Yang XF, Jin Q, Chen ZP, Li QL, Liu B (2014) Fabrication and microwave absorbent properties of Cobate zinc substituted W-type BaCoZnFe16O27. J Magn Magn Mater 367:64–68
Cao XH, Guo X, Meng J (2018) Investigation of synthesis and magnetic properties of plate-shaped Zn2W ferrites prepared via chemical co-precipitation and sol–gel auto-combustion. J Sol-Gel Sci Technol 85:149–157
Pullar RC (2012) Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog Mater 57:1191–1334
Zhou E, Zheng H, Zheng L et al. (2018) Synthesis of dense, fine grained hexagonal barium ferrite ceramics by two step sintering process. Int J Appl Ceram Technol 15:1023
Dong CS, Wang X, Zhou PH et al. (2014) Microwave magnetic and absorption properties of M-type ferrite BaCoxTixFe12-2x O19 in the Ka band. J Magn Magn Mater 354:340–344
Lim JT, Kim CS (2013) Investigation of magnetic properties of Zn Doped Y-type barium ferrite. IEEE Trans Magn 49(7):4192–4195
Sözeri H, Mehmedia Z, Kavasc H, Baykald A (2015) Magnetic and microwave properties of BaFe12O19 substituted with magnetic, nonmagnetic and dielectric ions. Ceram Int 41:9602–9609
Liu CY, Zhang YJ, Tang Y, Wang ZR, Ma N, Du PY (2017) The tunable magnetic and microwave absorption properties of the Nb5+–Ni2+ co-doped M-type barium ferrite. J Mater Chem C 5:3461–3472
Nikmanesh H, Moradi M, Bordbar GH, Alam RS (2017) Effect of multi dopant barium hexaferrite nanoparticles on the structural, magnetic, and X-Ku bands microwave absorption properties. J Alloy Compd 708:99–107
Liu CY, Chen YJ, Yue YY, Tang Y, Wang ZR, Ma N, Du PY (2017) Formation of BaFe12-xNbxO19 and its high electromagnetic wave absorption properties in millimeter wave frequency range. J Am Ceram Soc 100:3999–4010
Azizi P, Masoudpanah SM, Alamolhoda S (2019) Magnetic and microwave absorption properties of SrZnCoFe16O27/CoFe2O4 and SrZnCoFe16O27/SrFe12O19 composite powders. Appl Phys A 125:686
Jia JG, Liu CY, Ma N, Han GR, Wen WJ, Du PY (2013) Exchange coupling controlled ferrite with dual magnetic resonance and broad frequency bandwidth in microwave absorption. Sci Technol Adv Mater 14:045002
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This work is funded by the National Natural Science Foundation of China (Grant No. 51702075 and 51771176) and National Key Research and Development Project (Grant No. 2019YFF0217205).
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Fan, L., Zheng, H., Zhou, X. et al. A comparative study of microstructure, magnetic, and electromagnetic properties of Zn2W hexaferrite prepared by sol–gel and solid-state reaction methods. J Sol-Gel Sci Technol 96, 604–613 (2020). https://doi.org/10.1007/s10971-020-05364-2
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DOI: https://doi.org/10.1007/s10971-020-05364-2