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Mechanism of Thermochemical Interaction between Old Copper Ore Flotation Tailings and Chlorammonium Reagents

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Abstract

The article addresses processability of old copper–zinc ore flotation tailings. Potential reserves and processability of mining waste are considered in terms of Uchaly Mining and Processing Plant. The mineral composition and chemistry of old tailings are determined. The analysis of modes of interaction between gold and tailings minerals reveals inefficiency of conventional technologies in extraction of valuable components. The authors validate thermochemical processing technology for old tailings with gold and silver recovery using chlorammonium reagents. The thermal study determines the mode of thermochemical interaction of old flotation tailings with NH4Cl and NH4Cl–NH4NO3 mixture, efficient sequence of tailings processing with chlorammonium reagents and the optimum temperature ranges.

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References

  1. Afanasenko, S.I., Gold Vein of Man-Made Dumps. Problems of the Development of Manmade Gold Deposits, Proc. of Interregional Conf., Magadan: SVKNII DVO RAN, 2010.

    Google Scholar 

  2. Benevolsky, B.I., Krivtsov, A.I., Romanchuk, A.I., and Mikhailov, B.K., Two Aspects of the Problem of Recycling Mining and Industrial Waste, Mineral’ye resursy Rossii. Ekonomika i upravlenie, 2011, no, 1, pp. 37–42.

    Google Scholar 

  3. Medyanik, N.L., Mishurina, O.A., Mullina, E.R., Smirnova, A.V., and Zaitseva, E.V., Technology of Comprehensive Processing of Manmade Hydraulic Fills at Copper-Sulfide Mines, Vestn. MGTU, 2019, vol. 17, no. 4, pp. 10–17.

    Google Scholar 

  4. Vikent’ev I.V., Moloshag, V.P., and Yudovskaya, M.A., Occurrence Forms and Concentrating Conditions of Noble Metals in the Ural Sulfide Ores, Geolog. Rudn. Mestorozhd., 2006, vol. 48, no. 2, pp. 91–125.

    Google Scholar 

  5. Chanturia, V.A. and Shadrunova, I.V. (eds.), Tekhnologii obogashcheniya mednykh i medno-tsinkovykh rud Urala (Beneficiation Technologies for the Ural Copper and Copper-Zinc Ores), Moscow: Nauka, 2016.

    Google Scholar 

  6. Shemyakin, V.S., Skopov, S.V., Tsypin, E.V., and Shemyakin, A.V., X-Ray Radiometric Separation of Minerals and Man-Made Formations of the Ural Region, Izv. vuzov. Gorn. Zh., 2011, no. 4, pp. 29–33.

    Google Scholar 

  7. Zelenov, V.I., Metodika issledovaniya zoloto- i serebrosoderzhashchikh rud (Procedure for Studying Gold and Silver-Bearing Ores), Moscow: Nedra, 1989.

    Google Scholar 

  8. Chepushtanova, T.A. and Lugunov, V.A., Kinetic Model of Thermal Decomposition, Dokl. NAN Resp. Kazakhstan, 2007, no. 5, pp. 76–80.

    Google Scholar 

  9. Borisov, V.A. and Kraydenko, R.I., Processing of Zinc-Containing Ores by the Chlorammonium Method, URL: http://portal.tpu.ru/SHARED/b/BORISOV/Tab2/Binder1.pdf.

  10. Borisov, V.A., Kraydenko, R.I., and Chegrintsev, S.N., Interaction of Iron (II) Sulfide and Iron (III) Oxide with Ammonium Chloride and Identification of Reaction Products, Izv. Vuzov. Khimiya i khim. tekhnologiya, 2010, vol. 53, no. 9, pp. 25–27.

    Google Scholar 

  11. Borisov, V.A., Study of Zinc Sulfide and Oxide Hydrochlorination by Ammonium Chloride, Proc. of Lomonosov 16th Int. Conf. of Students, Post-Graduates and Young Scientists, Moscow, 2009. URL: http://www.lomonosov-msu.ru/archive/Lomonosov_2009/28_7.pdf.

  12. Borisov, V.A., Dyachenko, A.N., and Kraydenko, R.I., Interaction of Ammonium Chloride with Copper (II) Sulfide and Oxide and Identification of Reaction Products, Zhurn. Obshch. Khim., 2011, vol. 81, no. 7, pp. 1080–1082.

    Google Scholar 

  13. Ivashentsev, Ya.I. and Timonova, R.I., Chlorination of Silver and Gold and Thermochemical Transformations of their Chlorides, Zhurn. Neorgan. Khimii, 1967, vol. 12, no. 8, pp. 2013–2016.

    Google Scholar 

  14. Zyryanov, M.N. and Leonov, S.B., Khloridnaya metallurgiya zolota (Chloride Metallurgy of Gold), Moscow: SP Intermet-Engineering, 1997.

    Google Scholar 

  15. Medyanik, N.L., Leont’eva, E.V., Mullina, E.R., and Shadrunova, I.V., Determination of Optimal Parameters of Thermochemical Processing of Old Flotation Tailings of Copper-Zinc Ores by Chlorammonium Reagents, Tsvet. Metally, 2018, no. 6, pp. 7–13.

    Article  Google Scholar 

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Correspondence to N. L. Medyanik.

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Russian Text © The Author(s), 2020, published in Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, 2020, No. 3, pp. 144–151.

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Medyanik, N.L., Leont’eva, E.V., Mullina, E.R. et al. Mechanism of Thermochemical Interaction between Old Copper Ore Flotation Tailings and Chlorammonium Reagents. J Min Sci 56, 457–463 (2020). https://doi.org/10.1134/S106273912003674X

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  • DOI: https://doi.org/10.1134/S106273912003674X

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